Abstract
An innovative methodological approach based on XRF measurements using a polychromatic X-ray beam combined with simulation tests based on an ultra-fast custom-made Monte Carlo code has been used to characterize the bulk chemical composition of restored (i.e., cleaned) and unrestored multilayered Peruvian metallic artifacts belonging to the twelfth- and thirteenth-century AD funerary complex of Chornancap–Chotuna in northern Peru. The multilayered structure was represented by a metal substrate covered by surface corrosion patinas and/or a layer from past protective treatments. The aim of the study was to assess whether this new approach could be used to overcome some of the limitations highlighted in previous research performed using monochromatic X-ray beam on patina-free and protective treatment-free metal artifacts in obtaining reliable data both on the composition on the bulk metals and on surface layers thickness. Results from the analytical campaign have led to a reformulation of previous hypotheses about the structure and composition of the metal used to create the Peruvian artifacts under investigation.
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R. Cesareo, A. Castellano, G. Buccolieri, S. Quarta, M. Marabelli, P. Santopadre, M. Leole, A. Brunetti, Portable equipment for energy dispersive X-ray fluorescence analysis of Giotto’s frescoes in the Chapel of the Scrovegni. Nucl. Instrum. Methods Phys. Res. Sect. B 213, 703–706 (2004)
A. Guilherme, M. Manso, S. Pessanha, A. Zegzouti, M. Elaatmani, R. Bendaoud, J. Coroado, J.M.F. dos Santos, M.L. Carvalho, Micro-XRF for characterization of Moroccan glazed ceramics and Portuguese tiles. J Instrum 8, C02055 (2013)
R. Cesareo, C. Calza, M. Dos Anjos, R.T. Lopes, A. Bustamante, S.J. Fabian, W. Alva, Z.L.R. Chero, Pre-Columbian alloys from the royal tombs of Sipan; energy dispersive X-ray fluorescence analysis with a portable equipment. Appl. Radiat. Isot. 68, 525–528 (2010)
R. Cesareo, A. Bustamante, J. Fabian, C. Calza, M. Dos Anjos, R.T. Lopes, W. Alva, L. Chero, M. Espinoza, R. Gutierrez, R. Rodriguez, M. Seclen, Portable equipment for a non-destructive analysis of pre-Columbian metal artefacts from the Royal Tombs of Sipan by energy-dispersive X-ray fluorescence spectrometry. X-Ray Spectrom. 40, 37–46 (2011)
R. Cesareo, M.A. Rizzutto, A. Brunetti, D.V. Rao, Metal location and thickness in a multilayered sheet by measuring Kα/Kβ, Lα/Lβ and Lα/Lγ X-ray ratios. Nucl. Instrum. Methods Phys. Res. Sect. B 267, 2890–2896 (2009)
R. Cesareo, A. Brunetti, S. Ridolfi, Pigment layers and precious metal sheets by energy-dispersive X-ray fluorescence analysis. X-Ray Spectrom. 37, 309–316 (2008)
R. Cesareo, A. Brunetti, Metal sheets thickness determined by energy-dispersive X-ray fluorescence analysis. J. X-Ray Sci. Technol. 16, 119–130 (2008)
A. Bustamante, R. Cesareo, A. Brunetti, M. Rizzutto, C. Calza, R. Pereira de Freitas, U. Holmsquit, D. Diestra, Analysis of Pre-Columbian objects from Cupisnique, one of the oldest culture from Perú, using a portable X-ray fluorescence equipment. Appl. Phys. A Mater. Sci. Process. 113, 1065–1067 (2013)
R. Cesareo, A. Brunetti, R. D’Oriano, A. Canu, G.M. Demontis, A. Celauro, A Roman bronze statuette with gilded silver mask from Sardinia: an EDXRF study. Appl. Phys. A Mater. Sci. Process. 113, 905–910 (2013)
N. Schiavon, A. Celauro, M. Manso, A. Brunetti, F. Susanna, Early Iron Age bronze statuettes in Southern Portugal: combining archaeological data with EDXRF and BSEM + EDS to assess provenance and production technology. Applied Physics Part A 113(4), 865–875 (2013). doi:10.1007/s00339-013-7747-7
N. Schiavon, V. Soria, A. M. Arruda, M. Beltrame, J. Mirão, “Losanga” decorated Imitations of Italic Late Republican Black Gloss Tableware from South-Western Iberia: a multi-analytical/microchemical characterization. Microchem. J. 124, 712–718 (2016)
C. Bottaini, J. Mirão, M. Figuereido, A. Candeias, A. Brunetti, N. Schiavon, Energy dispersive X-ray fluorescence Spectroscopy/Monte Carlo simulation approach for the non-destructive analysis of corrosion patina-bearing alloys in archaeological bronzes: the case of the bowl from the Fareleira 3 site (Vidigueira, South Portugal). Spectrochim. Acta B 103–104, 9–13 (2015)
M. Manso, N. Schiavon, I. Queralt, A.M. Arruda, J.M. Sampaio, A. Brunetti, Alloy characterization of a 7th Century BC archaeological bronze vase—overcoming patina constraints using Monte Carlo simulations. Spectrochim. Acta B 107, 93–96 (2015). doi:10.1016/j.sab.2015.03.001
G. Marchand, E. Guilminot, S. Lemoine, L. Rossetti, M. Vieau, N. Stephant, Degradation of archaeological horn silver artefacts in burials. Herit. Sci. 2, 5 (2014)
R.T. Cesareo, J.T. de Assis, C. Roldán, C. Bustamante, A. Brunetti, N. Schiavon, Multilayered samples reconstructed by measuring Ka/Kß or La/Lß X-ray intensity ratios by EDXRF. Nucl. Instrum. Methods Phys. Res. Sect. B 312, 15–22 (2013)
R.P. Gardner, J.M. Doster, Reduction of matrix effects in x-ray fluorescence analysis by the monte carlo, fundamental parameters method. Adv. X-Ray Anal. 22, 343–356 (1979)
R.P. Gardner, J.M. Doster, The complete spectral response for EDXRF systems—calculation by Monte Carlo and Analysis applications. 1 Homogeneous samples. X-ray Spectro. 11, 173–180 (1982)
R.P. Gardner, J.M. Doster, The complete spectral response for EDXRF systems—calculation by Monte Carlo and Analysis applications. 1 Heterogeneous samples. X-Ray Spectrom. 11, 181–186 (1982)
J.E. Fernandez, Monte Carlo computer simulation of the XRF intensity dependence on the propagation plane inclination. Comput. Phys. Commun. 54, 211–220 (1989)
U. Bottigli, A. Brunetti, B. Golosio, P. Oliva, S. Stumbo, L. Vincze, P. Randaccio, P. Bleuet, A. Simionovici, A. Somogyi, Voxel-based Monte Carlo simulation of X-ray imaging and spectroscopy experiments. Spectrochim. Acta B 59, 1747–1754 (2004)
B. Golosio, A. Brunetti, G.L. Masala, P. Oliva, T. Schoonjans, Monte Carlo simulation of X-ray imaging and spectroscopy experiments using quadric geometry and variance reduction techniques. Comput. Phys. Commun. 185, 1044–1052 (2014)
L. Vincze, K. Janssen, F. Adams, A general Monte Carlo simulation of energy-dispersive X-ray fluorescence spectrometers—I: unpolarized radiation, homogeneous samples. X-Ray Spectrom. 48, 553–573 (1993)
T. Schoonjans, L. Vincze, V.A. Solé, M. Sanchez del Rio, P. Brondeel, G. Silversmit, K. Appel, C. Ferrero, A general Monte Carlo simulation of energy-dispersive X-ray fluorescence spectrometers—Part 5. Polarized radiation, stratified samples, cascade effects, M-lines. Spectrochim. Acta, B 70, 10–23 (2012)
A. Brunetti, M. Sanchez del Rio, B. Golosio, A. Simionovici, A. Somogyi, A library for X-ray-matter interaction cross sections for X-ray fluorescence applications. Spectrochim. Acta B 59, 1725–1731 (2004)
T. Schoonjans, A. Brunetti, B. Golosio, M. Sanchez del Rio, V.A. Solé, C. Ferrero, L. Vincze, The xraylib library for X-ray-matter interactions. Recent developments. Spectrochim. Acta Part B 66, 776–784 (2011)
R.F.M. Hedges, On the occurrence of bromine in corroded silver. Stud. Conserv. 21, 44–46 (1976)
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Brunetti, A., Fabian, J., La Torre, C.W. et al. A combined XRF/Monte Carlo simulation study of multilayered Peruvian metal artifacts from the tomb of the Priestess of Chornancap. Appl. Phys. A 122, 571 (2016). https://doi.org/10.1007/s00339-016-0096-6
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DOI: https://doi.org/10.1007/s00339-016-0096-6