Issue 2, 2005
From the journal:

New Journal of Chemistry

Pyrazolone-based nitrido complexes: synthesis and nitrogen transfer to alkenes

Fredy R. Pérez,a   Julio Belmar,*b   Yanko Moreno,b   Ricardo Baggioc  and  Octavio Peñad  

* Corresponding authors

a Facultad de Ciencias de la Salud, Universidad Privada Antenor Orrego, Av. América Sur 3145, Monserrate, Trujillo, Perú
E-mail: fperez_a@yahoo.es

b Facultad de Ciencias Químicas, Universidad de Concepción, Casilla 160-C, Concepción, Chile
E-mail: jbelmar@udec.cl

c Departamento de Física, Comisión Nacional de Energía Atómica, Avda Gral. Paz 1499, San Martín, Buenos Aires, Argentina

d Laboratoire du Chimie du Solide et Inorganique Moléculaire (CNRS UMR 6511), Université de Rennes 1, Av. du Général Leclerc, Rennes cedex, France

Abstract

The first examples of alkylpyrazolone based nitridomanganese(V) complexes are here reported. Styrene was used as a test substrate to study the complex’s ability to transfer nitrogen in stoichiometric reactions. Preliminary trials yielded 75 to 91% of N-(2-hydroxy-2-phenylethyl)-2,2,2-trifluoroacetamide. An X-ray crystal structure for one of the nitrido complexes is also provided.

Graphical abstract: Pyrazolone-based nitrido complexes: synthesis and nitrogen transfer to alkenes

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Article information

DOI
https://doi.org/10.1039/B415101A
Article type
Letter
Submitted
28 Sep 2004
Accepted
06 Dec 2004
First published
17 Jan 2005

New J. Chem., 2005,29, 283-287

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Pyrazolone-based nitrido complexes: synthesis and nitrogen transfer to alkenes

F. R. Pérez, J. Belmar, Y. Moreno, R. Baggio and O. Peña, New J. Chem., 2005, 29, 283 DOI: 10.1039/B415101A

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