Regular ArticleThe Impedance of the Planar Diffuse Double Layer: An Exact Low-Frequency Theory
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Experimental corroboration of general phenomenological theory for dynamics of EDL in viscous medium on rough heterogeneous electrode
2017, Electrochimica ActaCitation Excerpt :The dynamic response of heterogeneous polycrystalline solid electrode can cause the capacitance dispersion. To understand the dynamics of electric double layer relaxation and capacitance dispersion, various theoretical models have been developed in the previous literatures [45–59]. Biesheuvel and coworker developed a theory of the nonlinear dynamics of capacitive charging and desalination by porous electrodes [60], and theory of time dependent ion selectivity in capacitive charging of porous electrodes [61].
AC electrokinetics of conducting microparticles: A review
2016, Current Opinion in Colloid and Interface ScienceDynamic properties of the electric double layer in electrolytes
2013, Journal of ElectrostaticsCitation Excerpt :Many researchers approximated the impedance of an inert planar electrode in contact with an arbitrary electrolyte by a series combination of the bulk electrolyte resistance, the diffuse outer-layer capacitance and the Stern layer capacitance. Gunning et al. [11] proposed a theory which accounts quantitatively for the divergence of the EDL resistance at low frequencies (<10 Hz) and provides high frequency corrections (>10 kHz) to the capacitance due to diffusion effects. They mentioned that the double layer impedance at low frequencies depends on the physical conditions of surface.
A numerical model of streamlines in coplanar electrodes induced by non-uniform electric field
2013, Journal of ElectrostaticsDebye-Falkenhagen dynamics of electric double layer in presence of electrode heterogeneities
2013, Journal of Electroanalytical ChemistryCitation Excerpt :These occurs when a solid electrode is in contact with various electrolytes, viz. aqueous, liquid crystals [14], glassy electrolytes [1], ionic liquids [11] and polyelectrolytes [15]. Usually these systems causes nonuniform change of electrical behavior of the electrode/electrolyte interface and often assumed to be the possible cause of electrode polarization [14,16–29]. In general, the possible cause of change in the electrical behavior leading to electrode polarization may be attributed mainly to two factors: