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Polymerization of Included Monomers and Behaviour of Resulting Polymers

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Inclusion Polymers

Part of the book series: Advances in Polymer Science ((POLYMER,volume 222))

Abstract

Cyclodextrins (CDs) are of interest to synthetic chemists because of their chemical stability and the possibility to modify these molecules in a regioselective manner. For supramolecular chemistry CDs are of great importance, since they represent a homologous series of water-soluble and chiral host molecules which can be used as models for studying weak interactions. In addition, their low price provides motivation for the discovery of new applications. Thus, CDs are used for the solubilization and encapsulation of drugs, perfumes, and flavourings. These applications are due to their low toxicity and their biodegradablity. Finally, they are of general interest because they are obtained from a renewable resource, starch (Eggersdorfer, M., Warwel, S., Wulff, CT.: Nachwachsende Rohstoffe Perspektiven für die Chemie. VCH, Weinheim (1993) .

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Abbreviations

AIBN:

2,2′-Azobis(2-methylpropionitrile)

AMPS:

2-Acrylamido-2-methylpropansulfonate

ANS:

8-Anilino-1-naphthalinsulfonacid ammonium

CD:

Cyclodextrin

2D-ROESY:

Two-dimensional rotating-frame overhauser spectroscopy

DEF:

Diethyl fumarate

DEM:

Diethyl maleate

DMF:

N,N-Dimethyl formaldehyde

DSC:

Differential scanning calorimetry

MDAA:

N,N-Dimethylacrylamide

EDT:

3,4-Ethylenedioxythiophene

FT-IR:

Fourier transformations infra red

GPC:

Gel Permeation Chromatography

HPLC:

High pressure liquid chromatography

LCST:

Lower critical solution temperature

MALDI-TOF MS:

Matrix assisted laser desorption ionization time of flight mass spectroscopy

Me:

Methylated

M w/M n :

Polydispersities

NIPAAM:

N-Isopropylacrylamide

NMR:

Nuclear magnetic resonance spectroscopy

r:

Copolymerization parameters

RAFT:

Reversible addition–fragmentation chain transfer

R f :

Retention factor

T crit :

Critical solution temperature

T g :

Glass transition temperature

t:

Transparency

TLC:

Thin layer chromatography

TTC:

Thiocarbonylsulfanylpropionic acid

UV:

Ultra violet spectroscopy

V50:

2-Methylpropionamidine dihydrochloride

VA44:

2,2′-Azobis[2-(2-imidazolin-2-yl)propane]dihydrochloride

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Authors and Affiliations

  1. Institute of Organic Chemistry and Polymer Chemistry, Heinrich-Heine-University of Duesseldorf, Universitaetsstr, 1 40225, Duesseldorf, Germany

    SooWhan Choi, Sadik Amajjahe & Helmut Ritter

Authors
  1. SooWhan Choi
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  2. Sadik Amajjahe
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  3. Helmut Ritter
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Corresponding author

Correspondence to Helmut Ritter .

Editor information

Editors and Affiliations

  1. Inst. Organische Makromolekulare Chemie, Universität des Saarlandes, Saarbrücken, 66123, Germany

    Gerhard Wenz

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Choi, S., Amajjahe, S., Ritter, H. (2009). Polymerization of Included Monomers and Behaviour of Resulting Polymers. In: Wenz, G. (eds) Inclusion Polymers. Advances in Polymer Science, vol 222. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2008_6

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