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Shear-Induced Transitions and Instabilities in Surfactant Wormlike Micelles

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Polymer Characterization

Part of the book series: Advances in Polymer Science ((POLYMER,volume 230))

Abstract

In this review, we report recent developments on the shear-induced transitions and instabilities found in surfactant wormlike micelles. The survey focuses on the nonlinear shear rheology and covers a broad range of surfactant concentrations, from the dilute to the liquid-crystalline states and including the semidilute and concentrated regimes. Based on a systematic analysis of many surfactant systems, the present approach aims to identify the essential features of the transitions. It is suggested that these features define classes of behaviors. The review describes three types of transitions and/or instabilities: the shear-thickening found in the dilute regime, the shear-banding which is linked in some systems to the isotropic-to-nematic transition, and the flow-aligning and tumbling instabilities characteristic of nematic structures. In these three classes of behaviors, the shear-induced transitions are the result of a coupling between the internal structure of the fluid and the flow, resulting in a new mesoscopic organization under shear. This survey finally highlights the potential use of wormlike micelles as model systems for complex fluids and for applications.

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Abbreviations

Al(NO3)3 :

Aluminum nitrate

AlCl3 :

Aluminum chloride

CP/Sal:

Cetylpyridinium salicylate

CPCl:

Cetylpyridinium chloride

CPClO3 :

Cetylpyridinium chlorate

C8F17 :

Perfluorooctyl butane trimethylammonium bromide

C12E5 :

Penta(ethylene glycol) monododecyl ether

C12TAB:

Dodecyltrimethylammonium bromide

C14TAB:

Tetradecyltrimethylammonium bromide

C14DMAO:

Tetradecyldimethylamine oxide

C16TAB:

Hexadecyltrimethylammonium bromide

C16TAC:

Hexadecyltrimethylammonium chloride

C18TAB:

Octadecyltrimethylammonium bromide

C18-C8DAB:

Hexadecyloctyldimethylammonium bromide

CnTAB:

Alkyltrimethylammonium bromide

CTAHNC:

Cetyltrimethylammonium 3-hydroxy-2-naphthalenecarboxylate

CTAT:

Hexadecyltrimethylammonium p-toluenesulfonate

CTAVB:

Cetyltrimethylammonium benzoate

Dec:

Decanol

DJS:

Diffusive Johnson-Segalman

DLS:

Dynamic light scattering

DR:

Drag reduction

EHAC:

Erucyl bis(hydroxyethyl)methylammoniumchloride

FB:

Flow birefringence

FI:

Faraday instability

Gemini 12-2-12:

Ethane diyl-1,2-bis-(dodecyl dimethylammonium bromide)

Hex:

Hexanol

HPC:

Hydroxypropyl cellulose

I/N:

Isotropic-to-nematic

KBr:

Potassium bromide

LAPB:

Laurylamidopropyl betaine

LSI:

Light scattering imaging

LCP:

Liquid crystalline polymer

NaCl:

Sodium chloride

NaClBz:

Sodium chlorobenzoate

NaClO3 :

Sodium chlorate

NaNO3 :

Sodium nitrate

NaSal:

Sodium salicylate

NaTos:

Sodium p-toluenesulfonate or sodium tosylate

NH4Cl:

Ammonium chloride

NMR:

Nuclear magnetic resonance

PBLG:

Poly(benzyl-L-glutamate)

PEO:

Poly(ethylene oxide)

PIV:

Particle image velocimetry

PTV:

Particle tracking velocimetry

SANS:

Small-angle neutron scattering

SALS:

Small-angle light scattering

SAXS:

Small-angle X-ray scattering

SDBS:

Sodium dodecyl benzyl sulfonate

SDES:

Sodium dodecyl trioxyethylene sulfate

SdS:

Sodium decylsulfate

SDS:

Sodium dodecyl sulfate

SIP:

Shear-induced phase

SIS:

Shear-induced structure

TTAA:

Tris(2-hydroxyethyl)-tallowalkyl ammonium acetate

USV:

Ultrasonic velocimetry

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Acknowledgements

The present review would not have been possible without the extended network of colleagues and friends being, as we are, fascinated by this subject. It is a pleasure to acknowledge the collaborations and the fruitful discussions we had over the years with Jacqueline Appell, Wesley Burghardt, Olivier Cardoso, Jean-Louis Counord, Jean-Paul Decruppe, Marc-Antoine Fardin, Olivier Greffier, Guillaume Grégoire, Heinz Hoffmann, Sébastien Manneville, François Molino, Julian Oberdisse, Peter Olmsted, Grégoire Porte, Ovidiu Radulescu, Jean-Baptiste Salmon, Claudia Schmidt, Jean-François Tassin, and Lynn Walker. The Laboratoire Léon Brillouin (CEA, Saclay, France), the Institute Laue-Langevin, and the European Synchrotron Radiation Facilities (Grenoble, France) are also acknowledged for their technical and financial supports. We have also benefited from research organizations and fundings, such as the GDR 1081 “Rhéophysique des Colloides et Suspensions”, European TMR-Network “Rheology of Liquid Crystals” contract number FMRX-CT96-0003 (DG 12 - ORGS), Agence Nationale pour la Recherche (ANR JCJC-0020). We are finally very grateful to Sébastien Manneville for his comments on the first version of the manuscript.

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  1. Laboratoire Matière et Systèmes Complexes (MSC), UMR 7057 CNRS-Université Paris-Diderot, 10 rue Alice Domon et Léonie Duquet, F-75205, Paris Cedex 13, France

    Sandra Lerouge & Jean-François Berret

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  1. Sandra Lerouge
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  2. Jean-François Berret
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Correspondence to Jean-François Berret .

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  1. , Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republi, Heyrovsky Sq. 2, Prague, 16206, Czech Republic

    Karel Dusek

  2. , Physiochimie Curie, Institut Curie, Rue d'Ulm 26, Paris Cedex 05, 75248, France

    Jean-François Joanny

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Lerouge, S., Berret, JF. (2009). Shear-Induced Transitions and Instabilities in Surfactant Wormlike Micelles. In: Dusek, K., Joanny, JF. (eds) Polymer Characterization. Advances in Polymer Science, vol 230. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2009_13

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