Skip to main content
SpringerLink
Log in

Feasibility of polymer film coatings through electroinitiated polymerization in aqueous medium

  • Conference paper
  • First Online:
Electric Phenomena in Polymer Science

Part of the book series: Advances in Polymer Science ((POLYMER,volume 33))

Abstract

The paper deals with the feasibility of polymeric coatings onto conductive substrates by electropolymerization as a new technique of metal protection. Although in theory the electropolymerization might provide by only one stage preparation of the polymer, spreading over the substrate and possibly crosslinking to insoluble networks, the situation is not so favorable. As a matter of fact, reviewing the work performed so far reveals that the polymerization “in situ” of traditional acrylic monomers, when possible, involves high current consumption and leads to unsatisfactory coatings. The reasons of such results are interpreted on the basis of both low production of radical initiator at the electrode and desorption phenomena: thus the most promising routes for further investigation are outlined.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

7 References

  1. Yeats, R. L.: Electro-painting. Teddington: Robert Draper 1970

    Google Scholar 

  2. Cooke, B. A., Ness, N. B., Palluel, A. L. L.: The electrodeposition of paint. In: Industrial electrochemical processes. Kuhn, A. T. (ed.) p. 417. Amsterdam-London-New York: Elsevier 1971

    Google Scholar 

  3. Brewer, G. E. F.: Electrodeposition of coatings, Advances in chemistry series 119, Washington, D. C.: Am. Chem. Soc. 1973

    Google Scholar 

  4. Funt, B. L., Tanner, J.: Electrochemical synthesis of polymers. In: Weinberg, N. L., (ed.): Technique of electroorganic synthesis, Vol. II, p. 559. London: John Wiley & Sons 1975

    Google Scholar 

  5. Mengoli, G., Tidswell, B. M.: Polymer 16, 64 (1975)

    Article  Google Scholar 

  6. Asahara, T., Seno, M., Tsuchiya, M.: Kinzoku Hyomen Gijutsu 20, 64 (1969); idem ibid. 20, 411 (1969); idem ibid. 20, 617 (1969)

    CAS  Google Scholar 

  7. Kaneko, H.: Kinzoku Hyomen Gijutsu 21, 93 (1970)

    CAS  Google Scholar 

  8. Bezuglji, V. D., Korshikov, L. A., Kravtsova, L. I., Bandarenko, I. B., Fioshin, M. Ya.: Elektrokhimiya 8, 1658 (1972)

    Google Scholar 

  9. Korshikov, L. A., Kravtsova, L. I., Bezuglyi, V. D.: Elektrokhimiya 10, 106 (1974)

    CAS  Google Scholar 

  10. Korshikov, L. A., Karpinetes, A. P., Bezuglyi, V. D.: Elektrokhimiya 10, 990 (1974)

    CAS  Google Scholar 

  11. Bockris, J. O'M., Reddy, A. K. N.: Modern electrochemistry, Vol. II. New York: Plenum Press 1970

    Google Scholar 

  12. Levin, E. S., Yamshchikov, A. V.: Elektrochemical reduction mechanism in organic peroxides. In: Frumkin, A. M., Ershler, A. B., (eds.): “Progress in electrochemistry of organic compounds”, p. 319. London: Plenum Press 1971

    Google Scholar 

  13. Barnes, D., Zuman, P.: Trans. Faraday Soc. 65, 1668 (1969)

    Article  CAS  Google Scholar 

  14. Grace, W. R. et al.: Br. Pat. 1.134.387 (1967), Chem. Abstr. 70, 30197 g; idem, Br. Pat. 1.179.543 (1969), Chem. Abstr. 72, 101933 g

    Google Scholar 

  15. Jostan, J. L., Krusemak, W., Bogenschütz, A. F, Oberfläche-Surface 10, 677 (1969)

    CAS  Google Scholar 

  16. Bogenschütz, A. F., Jostan, J. L., Krusemark, W.: Galvanotechnik 60, 750 (1969)

    Google Scholar 

  17. Oliver, J.: Prod. Finish (Cincinnati) 34, 60 (1970)

    Google Scholar 

  18. Sobiesky, J. F., Zerner, M. C.: U.S. Pat. 3.464.960 (1969), Chem. Abstr. 71, 103294 n

    Google Scholar 

  19. Collins, G. L., Thomas, N. W.: J. Polymer Sci., Polymer Chem. Ed. 15, 1819 (1977)

    Article  CAS  Google Scholar 

  20. Garg, B. K., Raff, R. A. V., Subramanian, R. V.: U.S. NTIS, AD Rep. 1977 from Gov. Rep. Announce. Index (U.S.) 1977 (7711) 158; Chem. Abstr. 87, 5458614

    Google Scholar 

  21. Teng, F. S., Makalingam, R., Subramanian, R. V., Raff, R. A. V.: J. Electrochem. Soc. 124, 995 (1977)

    Article  CAS  Google Scholar 

  22. Damaskin, B., B., Petrii, O. A., Batrakov, U. V.: Adsorption of organic compounds on electrodes. New York: Plenum Press, 1971

    Google Scholar 

  23. Hodes, H. A., Sobieski, J. F., Zerner, M. C.: U. S. Pat. 3.554.882 (1971); Chem. Abstr. 74, 65723K

    Google Scholar 

  24. Kolthoff, I. M., Ferstanding, L. L.: J. Polym. Sci. 5, 563 (1951)

    Article  Google Scholar 

  25. Hodes, H. A., Sobieski, F., Zerner, M. C.: U.S. Pat. 3.650.909 (1972); Chem. Abstr. 77, 7471 c

    Google Scholar 

  26. Grace, W. R. et al.: Br. Pat. 1.155.497 (1969); Chem. Abstr. 71, 41328 m

    Google Scholar 

  27. Fr. Pat. 2.193.067 (1973); Chem. Abstr. 80, 147037C

    Google Scholar 

  28. Shimizu, S., Shinohara, H., Kondon, T., Yamada, N.: U.S. Pat. 3.865.617 (1975); Chem. Abstr. 78, 161041 q

    Google Scholar 

  29. Mengoli, G., Daolio, S., Giulio, U, Folonari, C.: J. Appl. Polym. Sci., in press

    Google Scholar 

  30. Mengoli, G. et al. to be published

    Google Scholar 

  31. Hay, A. S.: Adv. Polym. Sci. 4, 496 (1967)

    Article  CAS  Google Scholar 

  32. Grace, W. R. et al.: Br. Pat. 1.156.309 (1969); Chem. Abstr. 71, 72049

    Google Scholar 

  33. Bruno, F., Pham, M. C., Dubois, J. E.: Electrochim. Acta 22, 451 (1977)

    Article  CAS  Google Scholar 

  34. Mengoli, S., Daolio, S., Giulio, U., Folonari, C.: J. Appl. Electrochem., in press

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratorio di Polarografia ed Elettrochimica Preparativa del C.N.R., Corso Stati Uniti 10, I-35 100, Padova, Italy

    Giuliano Mengoli

  2. Centro Ricerche Fiat, I-10043, Orbassano (Torino), Italy

    Giuliano Mengoli

Authors
  1. Giuliano Mengoli
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

Copyright information

© 1979 Springer-Verlag

About this paper

Cite this paper

Mengoli, G. (1979). Feasibility of polymer film coatings through electroinitiated polymerization in aqueous medium. In: Electric Phenomena in Polymer Science. Advances in Polymer Science, vol 33. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-09456-3_1

Download citation

  • DOI: https://doi.org/10.1007/3-540-09456-3_1

  • Received:

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-09456-2

  • Online ISBN: 978-3-540-35229-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation