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The luminescence of closed-shell transition-metal complexes. New developments

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Luminescence and Energy Transfer

Part of the book series: Structure and Bonding ((STRUCTURE,volume 42))

Abstract

This chapter describes new developments in the understanding of the luminescence of complexes consisting of a central highly-charged transition metal ion without d electrons surrounded by a number of oxygen ions (usually 4 or 6 in a tetrahedral or octahedral arrangement, respectively). Examples are titanates, vanadates, molybdates and tungstates. Recently results from low-temperature measurements have become available. On the other hand reliable molecular-orbital calculations have been performed. These are compared with each other. It is possible to obtain from the luminescence data information on the splitting of energy levels due to crystal-field and spin-orbit interactions. It is stressed that still a lot of data are lacking and that considerable effort has to be made to obtain a complete picture. Also the influence of ions with s2 configuration (Pb2+ Bi3+) on these complexes is considered.

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  1. Physical Laboratory, State University, P.O. Box 80.000, 3508, TA Utrecht, The Netherlands

    George Blasse

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  1. George Blasse
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© 1980 Springer-Verlag

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Blasse, G. (1980). The luminescence of closed-shell transition-metal complexes. New developments. In: Luminescence and Energy Transfer. Structure and Bonding, vol 42. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-10395-3_1

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  • DOI: https://doi.org/10.1007/3-540-10395-3_1

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-10395-0

  • Online ISBN: 978-3-540-38454-0

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