Abstract
The metal-nonmetal transition in ionic liquids is reviewed with special emphasis on alkali metal-alkali halide solutions and the ionic alloy Cs-Au. Magnetic measurements, especially nuclear magnetic resonance, are discussed in relation to the nature of localized electronic states at low concentrations of excess metal and electron dynamics in the metal-nonmetal transition region. It is suggested that the stability of non-magnetic species governs the occurrence of a continuous metal-nonmetal transition or, alternatively, liquid-liquid phase separation.
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Warren, W.W. (1982). The metal-nonmetal transition in ionic liquids. In: Bennemann, K.H., Brouers, F., Quitmann, D. (eds) Ionic Liquids, Molten Salts and Polyelectrolytes. Lecture Notes in Physics, vol 172. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-11952-3_3
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DOI: https://doi.org/10.1007/3-540-11952-3_3
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