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Direct Arylation via Cleavage of Activated and Unactivated C-H Bonds

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Cross-Coupling Reactions

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 219))

Abstract

Palladium catalyzed direct coupling of aryl halides not only with various carbon nucleophiles having acidic C-H bonds, but also with aromatic and heteroaromatic compounds accompanied by cleavage of their unactivated C-H bonds, has been significantly developed in recent years. In this review the progress of these reactions as effective methods for preparing aromatic fine compounds is summarized. A brief description of related direct coupling of arenes with unsaturated compounds is also given.

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan

    Masahiro Miura & Masakatsu Nomura

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  1. Masahiro Miura
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  2. Masakatsu Nomura
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Editors and Affiliations

  1. Division of Molecular Chemistry Graduate School of Engineering, Hokkaido University, Sapporo, 060-8628, Japan

    Norio Miyaura

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Miura, M., Nomura, M. (2002). Direct Arylation via Cleavage of Activated and Unactivated C-H Bonds. In: Miyaura, N. (eds) Cross-Coupling Reactions. Topics in Current Chemistry, vol 219. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45313-X_6

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