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Structure and Bonding in Boron-Containing Macrocycles and Cages — Comparison to Related Structures with Other Elements Including Organic Molecules

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Group 13 Chemistry I

Part of the book series: Structure and Bonding ((STRUCTURE,volume 103))

Abstract

The present revision describes the generation of macrocyclic, cage-like and supramolecular structures incorporating three-or four-coordinate boron atoms. Preparative strategies are discussed and include, aside from traditional preparative methods known from organic chemistry, one-step syntheses by self-assembly and template syntheses. Emphasis is placed on chemical and structural analogies to well-known related structures from organic, coordination and organometallic chemistry. Applications of boron-containing hosts in ionic and molecular recognition, including chiral recognition, as well as selective molecular transport through lipophilic membranes are discussed.

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  1. Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, C. P. 62210, Cuernavaca, Mexico

    Herbert Höpfl

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  1. Herbert Höpfl
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  1. Institut für Anorganische Chemie der Universität Göttingen, Tammannstr. 4, 37077, Göttingen, Germany

    Herbert W. Roesky

  2. Department of Chemistry, University of Kentucky, Lexington, Kentucky, 40506 0055, USA

    David A. Atwood

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Höpfl, H. (2002). Structure and Bonding in Boron-Containing Macrocycles and Cages — Comparison to Related Structures with Other Elements Including Organic Molecules. In: Roesky, H.W., Atwood, D.A. (eds) Group 13 Chemistry I. Structure and Bonding, vol 103. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-47808-6_1

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  • DOI: https://doi.org/10.1007/3-540-47808-6_1

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