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Infrared Absorption Spectra of Molecular Ions in Solid Argon

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Molecular Ions

Abstract

Molecular ions are of considerable chemical and physical interest for comparing the spectroscopic and bonding properties of neutral molecules with their positive and negative molecular ions. The study of molecular ions in the gas phase by photoelectron, photoionization mass and ion cyclotron resonance spectroscoies can be complemented by infrared and optical absorption spectra of the molecular ion trapped in a solid inert gas host. Further ion studies with tunable infrared lasers will be greatly aided by the vibrational data obtained for molecular ions in noble gas solids. The ion-matrix interaction is of fundamental and practical interest as matrix spectra of ions are related to the gas phase.

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Andrews, L. (1983). Infrared Absorption Spectra of Molecular Ions in Solid Argon. In: Berkowitz, J., Groeneveld, KO.E. (eds) Molecular Ions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3664-8_9

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  • DOI: https://doi.org/10.1007/978-1-4613-3664-8_9

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