Abstract
This chapter, and the following one by Neumann and Good, deal with the measurement of contact angles in three-phase systems. The contact angle is, intrinsically, a macroscopic property, and one that should be amenable to a phenomenological treatment, e.g., to measurement without regard to its thermodynamic or microscopic interpretation. But inevitably, the desire for a thermodynamic and molecular interpretation arises. In addition, some fundamental questions about solid surfaces come up, and the problem of hysteresis must be given explicit consideration. So there is a need to go beyond phenomenology.
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Good, R.J. (1979). Contact Angles and the Surface Free Energy of Solids. In: Good, R.J., Stromberg, R.R. (eds) Surface and Colloid Science. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7969-4_1
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DOI: https://doi.org/10.1007/978-1-4615-7969-4_1
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