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Contact Angles and the Surface Free Energy of Solids

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Surface and Colloid Science

Abstract

This chapter, and the following one by Neumann and Good, deal with the measurement of contact angles in three-phase systems. The contact angle is, intrinsically, a macroscopic property, and one that should be amenable to a phenomenological treatment, e.g., to measurement without regard to its thermodynamic or microscopic interpretation. But inevitably, the desire for a thermodynamic and molecular interpretation arises. In addition, some fundamental questions about solid surfaces come up, and the problem of hysteresis must be given explicit consideration. So there is a need to go beyond phenomenology.

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References

  1. R. J. Good and L. A. Girifalco, J. Phys. Chem. 64, 561, (1960).

    Article  CAS  Google Scholar 

  2. O. Driedger, A. W. Neumann, and P.-J. Sell, Kolloid-Z. u. Z. Polym. 201, 52 (1965); 204, 101 (1965).

    Article  CAS  Google Scholar 

  3. R. J. Good, in Wetting, a Symposium, Bristol, England, 1966, SCI Monograph No. 25, p. 328 (1967).

    Google Scholar 

  4. R. J. Good, J. Colloid Interface Sci. 59, 398 (1977).

    Article  Google Scholar 

  5. A. W. Neumann and R. J. Good, J. Colloid Interface Sci. 38, 341 (1972).

    Article  CAS  Google Scholar 

  6. J. D. Eick, R. J. Good, and A. W. Neumann, J. Colloid Interface Sci. 53, 235 (1975).

    Article  Google Scholar 

  7. R. J. Good, J. Phys. Chem. 74, 5041 (1953).

    Google Scholar 

  8. W. Funke, G. E. H. Hellwig, and A. W. Neumann, Angew. Makromolec. Chem. 8, 185 (1969).

    Article  CAS  Google Scholar 

  9. R. J. Good, J. A. Kvikstad, and W. O. Bailey, J. Colloid Interface Sci. 35, 314 (1971).

    Article  CAS  Google Scholar 

  10. N. K. Adam and G. Jessop, J. Chem. Soc. 1925, 1863 (1925).

    Google Scholar 

  11. G. Goldfinger (ed.), Clean Surfaces,Marcel Dekker, New York (1970): (a) S. Ross and J. J. Hinchen, p. 115; (b) M. J. Sparnaay, p. 153; (c) M. L. White, p. 361.

    Google Scholar 

  12. R. N. Wenzel, Ind. Eng. Chem. 28, 988 (1936).

    Article  Google Scholar 

  13. b. J. Phys. Colloid. Chem. 53 1466 (1949).

    Google Scholar 

  14. R. E. Johnson, Jr. and R. H. Dettre, Advan. Chem. Ser. 43, 112, (1964).

    Article  CAS  Google Scholar 

  15. R. E. Johnson, Jr., and R. H. Dettre, J. Phys. Chem. 68, 1744 (1964).

    Article  CAS  Google Scholar 

  16. R.J. Good and E. Diamanti-Kotsidas, 173rd National ACS Meeting, 1977; J. Adhesion (1978), in press.

    Google Scholar 

  17. T. Young, Miscellaneous Works (G. Peacock, ed.), Vol. 1, J. Murray, London (1855).

    Google Scholar 

  18. R. E. Johnson, Jr., J. Phys. Chem. 63, 1655 (1959).

    Article  CAS  Google Scholar 

  19. A. W. Neumann, Advan. Colloid Interface Sci. 4, 105 (1975).

    Google Scholar 

  20. R. J. Good, J. Colloid Interface Sci. 52, 308 (1975).

    Article  Google Scholar 

  21. A. W. Adamson and I. Ling, Advan. Chem. Ser. 43, 57 (1964).

    Article  CAS  Google Scholar 

  22. M. E. Tadros, P. Hu, and A. W. Adamson, J. Colloid Interface Sci. 49, 184 (1974).

    Article  CAS  Google Scholar 

  23. R. J. Good, Advan. Chem. Ser. 43, 74 (1964).

    Article  Google Scholar 

  24. R. J. Good and E. Elbing, Ind. Eng. Chem. 62 (3), 54 (1970).

    Article  CAS  Google Scholar 

  25. J. L. Gardon, Encyclopedia of Polymer Science and Technology (Mark, Gaylord, and Bikales, eds.), Vol. 3, p. 883, Interscience, New York (1965).

    Google Scholar 

  26. I. Israelachvili, Quart. Rev. Biophys. 6, 341 (1976).

    Article  Google Scholar 

  27. A. M. Schwartz, Advan. Colloid Interface Sci. 4, 349 (1975).

    Article  Google Scholar 

  28. R. J. Good and N.-W. Han, unpublished results.

    Google Scholar 

  29. N. K. Adam, The Physics and Chemistry of Surfaces ( 3rd ed. ), Oxford University Press, Oxford, England (1941).

    Google Scholar 

  30. R. Albfett, Phil. Mag. 46, 244 (1923).

    Google Scholar 

  31. R. S. Hansen and M. Miotto, J. Amer. Chem. Soc. 79, 1765 (1957).

    Article  CAS  Google Scholar 

  32. T. D. Blake and J. M. Haynes, J. Colloid Interface Sci. 30, 421 (1969).

    Article  CAS  Google Scholar 

  33. E. B. Dusan V and S. H. Davis, J. Fluid Mechan. 65, 71 (1974).

    Article  Google Scholar 

  34. A. B. D. Cassie, Discuss. Faraday Soc. 3, 11 (1948).

    Article  Google Scholar 

  35. A. W. Neumann, D. Renzow, H. Reumuth, and I.-E. Richter, Fortschr. Kolloid u. Polym. 55, 49 (1971).

    CAS  Google Scholar 

  36. R. J. Good and M. L. Koo, unpublished work.

    Google Scholar 

  37. A. W. Neumann, R. J. Good, C. J. Hope, and M. Sejpal, J. Colloid Interface Sci. 49, 291 (1974).

    Article  CAS  Google Scholar 

  38. R. J. Good and K. H. Yu, unpublished results.

    Google Scholar 

  39. G. L. Mack, J. Phys. Chem. 40, 159 (1936).

    Article  Google Scholar 

  40. Ya. I. Frenkel, Zh. Eksp. Teor. Fiziki 18, 659 (1948).

    Google Scholar 

  41. Ya. B. Aron and Ya. I. Frenkel, Zh. Eksp. Teor. Fiziki 20, 453 (1950).

    CAS  Google Scholar 

  42. J. Leja and G. W. Poling, in Proceedings of the International Mineral Processing Congress, London, 1960, Institute of Mining and Metallurgy, London (1960).

    Google Scholar 

  43. R. E. Johnson, personal communication.

    Google Scholar 

  44. H. W. Fox and W. A. Zisman, J. Colloid 5, 520 (1950).

    Google Scholar 

  45. W. A. Zisman, Adv. Chem. Ser. 43 1 (1964).

    Article  Google Scholar 

  46. A. W. Adamson, The Physical Chemistry of Surfaces ( 2nd ed. ), Wiley Interscience, New York (1968).

    Google Scholar 

  47. D. H. Kaelble and K. C. Uy, J. Adhesion 2, 50 (1970).

    Article  CAS  Google Scholar 

  48. A. H. Ellison and W. A. Zisman, J. Phys. Chem. 58, 503 (1954).

    Article  CAS  Google Scholar 

  49. W. A. Zisman, J. Paint Technol. 44, 42 (1972).

    Google Scholar 

  50. J. L. Gardon, J. Phys. Chem. 67, 1935 (1963).

    Article  Google Scholar 

  51. A. Baszkin and L. TerMinassian-Saraga, J. Colloid Interface Sci, 43, 90 (1973).

    Google Scholar 

  52. F. M. Fowkes, J. Phys. Chem. 66, 682 (1962).

    Google Scholar 

  53. F. M. Fowkes, J. Phys. Chem. 67, 2538 (1963).

    Article  Google Scholar 

  54. F. M. Fowkes, Advan. Chem. Ser. 43, 99 (1964).

    Article  Google Scholar 

  55. F. M. Fowkes, J. Phys. Chem. 72, 3700 (1968).

    Google Scholar 

  56. F. M. Fowkes, J. Adhesion 4, 155 (1972).

    Article  Google Scholar 

  57. D. K. Owens and R. C. Wendt, J. Appl. Polym. Sci. 13, 1741 (1969).

    Article  CAS  Google Scholar 

  58. D. H. Kaelble, J. Adhesion 2, 50 (1970).

    Article  Google Scholar 

  59. D. H. Kaelble, Physical Chemistry of Adhesion, Chap. 5, Wiley Interscience, New York (1971).

    Google Scholar 

  60. F. London, Trans. Faraday Soc. 33, 8 (1937).

    Article  CAS  Google Scholar 

  61. M. Sherriff, J. Adhesion 7, 257 (1976).

    Article  Google Scholar 

  62. ASTM D-2578–67, ASTM Standards, Part 26, p. 370 (1968).

    Google Scholar 

  63. J. R. Dann, J. Colloid Interface Sci. 32, 302 (1970).

    Article  Google Scholar 

  64. J. R. Dann, J. Colloid Interface Sci, 32, 320 (1970).

    Google Scholar 

  65. I. Prigogine and R. Defay, J. Chem. Phys. 46, 367 (1949).

    CAS  Google Scholar 

  66. G. J. Jameson and M. G. Del Cerro, J. Chem. Soc. Faraday Trans. I, 72, 883 (1976).

    Google Scholar 

  67. L. R. White, J. Chem. Soc. Faraday Trans. I, 73, 390 (1977).

    Google Scholar 

  68. G. Navascués and M. V. Berry, Mol. Phys. 34, 649 (1977).

    Article  Google Scholar 

  69. H. T. Davis et al., personal communication.

    Google Scholar 

  70. B. Pethica, J. Colloid Interface Sci. 62, 567 (1977).

    Article  CAS  Google Scholar 

  71. R. C. Tolman, J. Chem. Phys. 16, 578 (1948); J. Chem. Phys. 17, 118 (1949).

    Article  CAS  Google Scholar 

  72. F. M. Fowkes and M. A. Mostafa, Ind. Eng. Chem. Prod. Dev. 17, 3 (1978).

    Article  CAS  Google Scholar 

  73. R. S. Drago, G. C. Vogel, and T. E. Needham, J. Am. Chem. Soc. 93, 6014 (1971).

    CAS  Google Scholar 

  74. R. S. Drago, L. B. Parr, and C. S. Chamberlain, J. Am. Chem. Soc. 99, 3203 (1977).

    CAS  Google Scholar 

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© 1979 Plenum Press, New York

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Good, R.J. (1979). Contact Angles and the Surface Free Energy of Solids. In: Good, R.J., Stromberg, R.R. (eds) Surface and Colloid Science. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7969-4_1

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  • DOI: https://doi.org/10.1007/978-1-4615-7969-4_1

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-7971-7

  • Online ISBN: 978-1-4615-7969-4

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