Abstract
The oxidative addition of alkyl halides is a reaction undergone by coordinatively unsaturated transition metal complexes with concommitant increase in oxidation number and coordination number. In its simplist form, a metal in oxidation state (n) and coordination number (m) adds alkyl halides to give a new complex of oxidation number (n + 2) and coordination number (m + 2) (Equation 1).
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
J. Halpern, Accounts Chem. Res., 3, 386 (1970).
J. P. Coltman, ibid, 1, 136 (1968).
J. P. Collman and W. R. Roper, Advan. Organometal. Chem., 7, 53 (1968).
I. C. Douek and G. Wilkinson, J. Chem. Soc. (A), 2604 (1969).
G. M. Whitesides and D. J. Boschetto, J. Am. Chem. Soc., 93, 1529 (1971).
J. A. Labinger, R. J. Braus, D. Dolphin, and J. A. Osborne, Chem. Comm., 612 (1970).
J. A. Labinger, A. V. Kramer, and J. A. Osborne, J. Am. Chem. Soc., 95, 7908 (1973).
N. von Kutepow, W. Himmele, and H. Hohenschutz, Chem. Ing. Techn. 37, 383 (1965).
W. F. Gresham and R. E. Brooks, U.S. 2,497,304 (to DuPont Company) February 14, 1950.
W. Reppe, W. Schweckendick, and H. Kroeper, U.S. 2,658,075 (to BASF) November 3, 1953.
T. Alderson and V. A. Englehardt, U.S. 3,065,242 (to DuPont) November 20, 1962.
L. Cassar, G. P. Chiusoli, and F. Guerrieri, Synthesis, 509 (1973).
L. Cassar and M. Foa, J. Organometal. Chem., 51, 381 (1973).
C. W. Bird, “Transition Metal Intermediates in Organic Synthesis”, Academic Press, New York, p. 149+ (1967).
F. E. Paulik and J. F. Roth, Chem. Comm., 1578 (1968).
J. F. Roth, J. H. Craddock, A. Hershman, and F. E. Paulik, Chemtech 1, 600 (1971).
H. D. Grove, Hydro. Processing 51, No. 11, 76 (1972).
D. L. Kensler, Jr., G. K. Kohn, and D. D. Walgenbach French 70/37,979 (to Chevron Research Company), July 12, 1971.
J. Tomiska and E. Spousta, Angew. Chem. Int’1 Ed., 1, 211 (1962).
S. J. Lapporte and W. G. Toland, U.S. 3,720,706 (to Chevron Research Company), March 13, 1973.
A. T. Larson, U.S. 2,153,064 (to DuPont), April 4, 1939.
S. K. Bhattacharyya and D. Vir, “Advances in Catalysis”, Vol. IX, Academic Press, New York, 1957, pp. 625–635.
S. J. Lapporte and W. G. Toland, U.S. 3,754,028 (to Chevron Research Company), August 21, 1973.
D. J. Loder and E. P. Bartlett, U.S. 2,211,624 (to DuPont), August 13, 1940.
W. J. Linn and R. E. Benson, J. Am. Chem. Soc., 87, 3657 (1965).
R. F. Heck, ibid, 85, 1460 (1963).
R. Cramer, ibid, 87, 4717 (1965).
K. Mori, T. Mizoroki, and A. Ozaki, Bull. Chem. Soc. Japan, 46, 1505 (1973).
W. W. Spooncer, US. 3,641,171 (to Shell Oil Company), Fèbruary 8, 1972.
E. F. Magoon and L. H. Slaugh, U.S. 3,592,866 (to Shell Oil Company), July 13, 1971.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1975 Plenum Press, New York
About this chapter
Cite this chapter
Lapporte, S.J., Kurkov, V.P. (1975). Catalytic Applications of Oxidative Addition of Alkyl Halides to Transition Metal Complexes. In: Ishii, Y., Tsutsui, M. (eds) Organotransition-Metal Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2142-2_18
Download citation
DOI: https://doi.org/10.1007/978-1-4684-2142-2_18
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-2144-6
Online ISBN: 978-1-4684-2142-2
eBook Packages: Springer Book Archive