Abstract
Infrared-absorbing trace gases other than CO2 are accumulating in the atmosphere. The climatic effect of these gases will be comparable and will add to that expected from CO2. Tropospheric chemistry plays an important role in the budgets and trends of two radiatively important trace gases, i. e., CH4 and tropospheric O3.
The observed trend of CH4 indicates that there has been a factor of two increases in its concentration in the last 350 years and the rate of increase has become greater in the last century. The increase in CH4 is most likely due to increases in its sources, such as human activities in agriculture and energy use. Changes in the photochemical sink of CH4 may also contribute.
There is strong evidence that tropospheric O3 in industrial countries has increased significantly due to anthropogenic emissions of NOx and hydrocarbons. However, the trend of tropospheric O3 has not been quantitatively established because there are large spatial and temporal variations in the distribution of O3. More extensive measurements are needed to quantify this trend.
In this report we have identified the major photochemical processes that control the budgets and trends of CH4 and tropospheric O3. It is shown that human activities may have significantly perturbed the atmospheric distributions of CO, NOx, O3, nonmethane hydrocarbons, and CH4. The observed trends of O3 and CH4 are qualitatively consistent with the current understanding of their photochemistry and budgets. However, models with realistic transport and photochemical processes need to be developed to evaluate and predict the trends quantitatively.
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Literatur
Aldaz, L., 1969: Flux measurements of atmospheric ozone over land and water. J. Geophys, Res., 74, 6943–6946.
Angell, J. K. and J. Korshover, 1983: Global variation in total ozone and layermean ozone: an update through 1981. J. of Climate and Applied Meteorology, 22, 1611–1627.
Blake, D. R., E W. Mayer, S. C. Tyler, V. Makide, D. C. Montague and F. S. Rowland, 1982: Global increase in atmospheric methane concentrations between 1978 and 1980, Geophys. Res. Lett., 9, 477–480.
Bojkov, R. D., 1986: Surface ozone during the second half of the nineteenth century. J. Climate and Applied Met., 25, 343–352.
Chameides, W. L., S. C. Liu and R. J. Cicerone, 1977: Possible variations in atmospheric methane. J. Geophys. Res., 82, 1788–1795.
Chemical Manufacturers Association, 1983: 1982 World Production and Sales of Flurocar-bons FC-11 and FC-12. 29 pp., Washington, D. C.
Colbeck, I. and R. M. Harrison, 1985: Dry deposition of ozone: Some measurements of deposition velocity and of vertical profiles to 100 meters. Atmos. Environ., 19, 1807–1818.
Costanza, V. and J. H. Seinfeld, 1982: Optimal emission control strategies for photochemical smog. Environ. Sci., and Tech., 16, 98–101.
Cox, R. A., A. E. J. Eggleton, R. G. Derwent, J. E. Lovelock and D. E. Pack, 1975. Long-range transport of photochemical ozone in North-western Europe. Nature, 255, 118–121.
Craig, H. and C. C. Chou, 1982: Mathane: The record in polar ice cones. Geophys. Res. Lett., 9, 1221–1224.
Cunnold, D., R. Prinn, R. Rasmussen, P. Simmonds, F. Alyea, C. Cardelino and A. Crawford, 1983: The Atmospheric Lifetime Experiment, 4. Results for CF2Cl2 based on 3 years of data. J. Geophys. Res., 88, 8401–8414.
Danielsen E. F. and V. A. Mohnen, 1977: Project dust storm report: ozone transport, in situ measurements, and meteorological analyses of tropopause folding. J. Geophys. Res., 82, 5867–5877.
Delany, A. C., P. J. Crutzen, P. Haagenson, S. Walters and A. F. Wartburg, 1985: Photochemically produced ozone in the emissions from large-scale tropical vegetation fires. J. Geophys. Res., 90, 2425–2429.
Ehhalt, D. H., 1974: The atmospheric cycle of methane. Tellus, 26, 58–70.
Fishman, J., S. Solomon and P. J. Crutzen, 1979: Observational and theoretical evidence in support of a significant in-situ photochemical source of tropospheric ozone. Tellus, 31, 432–446.
Fishman, J., F. M. Vukovich, E. V. Browell, 1985: The photochemistry of synopticscale ozone budget. J. of Atm. Chemistry, 3, 299–320.
Hov, O., Ozone in the troposphere: high level pollution. Ambio, 13, 73–79.
Khalil, M. A. K. and R. A. Rasmussen, 1983: Sources, sinks, and seasonal cycles of atmospheric methane. J. Geophys. Res., 88, 5131–5144.
Lenschow, D. H., R. Pearson, Jr., and B.B. Stankor, 1982: Measurements of ozone vertical flux to ocean and forest. J. Geophy. Res., 87, 8833–8837.
Levy, A., 1876: Dosage de l’ozone de l’air. Bull. Menssuel Observ. de Montsouris, 5, 57–61.
Liu, M.K., R. E. Morris and J. P. Killus, 1984: Development of a regional oxidant model and application to the north-eastern United States. Atmos. Environ., 16, 1145.
Liu, S. C., D. Kley, M. McFarland, J. D. Mahlman and H. Levy II, 1980: On the origin of tropospheric ozone. J. Geophys. Res., 85, 7546–7552.
Liu, S. C., M. Trainer, F. C. Fehsenfeld, D.D. Parrish, E. J. Williams, D. W. Fahey, G. Hubler and P. C. Murphy, 1987: Ozone production in the rural troposphere and the implications for regional and global ozone distributions. J. Geophys. Res., in press.
Logan, J. A., Nitrogen oxides in the troposphere: 1983: Global and regional budgets. J. Geophys. Res., 88, 10785–10807.
Logan, J. A., 1985: Tropospheric ozone: seasonal behavior, trends, and anthropogenic influence. J. of Geophys, Res., 90, 10463–10482.
Mahlman, J. D., H. Levy II and W. Moxim, 1980: Three-dimensional tracer structureand behavior as simulated in two ozone precursor experiments. J. At-mos. Sci., 37, 655–685.
Noxon, J. E., 1983: NO3 and NO2 in the mid-pacific troposphere. J. Geophys. Res., 88, 11017–11021.
Oltmans, S. J. and W. D. Komhyr, 1986: Surface ozone distributions and variations from 1973–1984 measurements at the NOAA/GMCC baseline observatories. J. Geophys. Res., 91, 5229–5236.
Platt, U., A. M. Winer, H. W. Biermann, R. Atkinson, J. N. Pitts, Jr., 1984: Measurement of nitrate radical concentrations in continental air. Environ. Sci. Technol., 18, 365–369.
Ramanathan, U., R. J. Cicerone, H. B. Singh and J. T. Kiehl, 1985: Trace gas trends and their potential role in climate change, J. Geophys. Res., 90, 5547–5566.
Rasmussen, R. A. and M. A. K. Khalil, 1981: Atmospheric methane: Trends and seasonal cycles. J. Geophys. Res., 86, 9826–9832.
Rasmussen, R. A. and M. A. K. Khalil, 1984: Atmospheric methane in the recent and ancient atmospheres; Concentrations, trends, and interhemispheric gradient. J. Geophys. Res., 89, 11599–11605.
Research Triangle Institute, 1975: Investigations of rural oxidant levels as related to urban hydrocarbon control strategies. EPA-450/3-75-036, Environmental Protection Agency, Research Triangle Park, N. C., 359 pp.
Sakamaki, F., M. Okuda, H. Akimoto and H. Yamazaki, 1982: Computer modeling study of photochemical ozone formation in the propene-nitrogen oxides-dry air system, generalized maximum ozone isopleth. Environ. Sci. and Tech., 16, 45–52.
Sze, N. D., 1977: Anthropogenic CO emissions; Implications for the Atmospheric CO-OH-CH4 Cycles. Science, 195, 673–675.
Thompson, A. M. and R. J. Cicerone, 1986: Atmospheric CH4, CO, and OH from 1860 to 1985. Nature, 321, 148–150.
U. S. EPA, 1977: Uses, limitations and technical basis of procedures for quantifying relationships between photochemical oxidants and precursors. US Environmental Protection Agency, Research Triangle Park, N. C., 1977; EPA 450/2-77-021a.
Volz, A., D. Kley, H. P. Kley and S. Gilge, 1986: A critical evaluation of the Montsouris series of O3 measurements from 1876 to 1907, EOS, Transactiona, American Geophysical Union, 67, 877–878.
Wang, W. C., D.J. Wuebbles, W. M. Washington, R. G. Isaacs and G. Molnar, 1986: Trace gases and other potential perturbations to global climate. Reviews of Geophysics, 24, 110–140.
Weiss, R. F., 1981: The temporal and spatial distribution of tropospheric nitrous oxide. J. Geophys. Res., 86, 7185–7195.
Wesely, M. L., 1983: Turbulent transport of ozone to surfaces common in the eastern half of the United States. Trace Atmospheric Constituents, Edited by S. E. Schwartz, J. Wiley and Sons, 345-370.
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Liu, S.C. (1987). Trends of Radiatively Important Trace Gases and their Relationship to Tropospheric Photochemistry. In: Liou, KN., Xiuji, Z. (eds) Atmospheric Radiation. American Meteorological Society, Boston, MA. https://doi.org/10.1007/978-1-935704-18-8_100
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DOI: https://doi.org/10.1007/978-1-935704-18-8_100
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