Abstract
The properties of spin-crossover nanoparticles were investigated within a framework of Ising-like model. By involving the Monte Carlo simulation tools, a thermal transition of spin-crossover solids with local random fields of various statistical characteristics and without stochastic origins has been analyzed. In three-dimensional spin-crossover crystal, the presence of fluctuations may provoke the hysteresis for the system with gradual non-hysteretic transition in contrary to the one that undergoes the first-order phase transition, in which the fluctuations play destructive role on system cooperativity vanishing the hysteresis loop. The changes of transition temperatures characterizing the systems bistable properties for 3D lattices with ferromagnetic and antiferromagnetic couplings of surface’s molecules and their dependence on its size and fluctuation strength were obtained. Also, the regions with hysteretic and non-hysteretic behavior have been found.
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References
Atkins P, Overton T, Rourke JP, Weller MT, Armstrong FA (2010) Shriver and Atkins inorganic chemistry. Oxford University Press, New York
Halcrow MA (ed) (2013) Spin-crossover materials: properties and applications. Wiley, Chichester
Gudyma Iu, Enachescu C, Maksymov A (2015) Kinetics of nonequilibrium transition in spin-crossover compounds. In: Nanocomposites, Nanophotonics, Nanobiotechnology, and Applications, Springer, pp 375–401
Kumar KS, Ruben M (2017) Emerging trends in spin crossover (SCO) based functional materials and devices. Coordin Chem Rev 346:176–205
Iasco O, Boillot M-L, Bellec A, Guillot R, Riviere E, Mazerat S, Nowak S, Morineau D, Brosseau A, Miserque F (2017) The disentangling of hysteretic spin transition, polymorphism and metastability in bistable thin films formed by sublimation of bis (scorpionate) Fe (II) molecules. J Mater Chem C 5(42):11067–11075
Molnár G, Rat S, Salmon L, Nicolazzi W, Bousseksou A (2018) Spin crossover nanomaterials: from fundamental concepts to devices. Adv Mater 30(5):1703862
Simon-Yarza T, Mielcarek A, Couvreur P, Serre C (2018) Nanoparticles of metal-organic frameworks: On the road to in vivo efficacy in biomedicine. Adv Mater 2018:1707365
Salmon L, Catala L (2018) Spin-crossover nanoparticles and nanocomposite materials. Comptes Rendus Chimie 21(12):1230–1269
Mikolasek M, Ridier K, Bessas D, Cerantola V, Félix G, Chaboussant G, Piedrahita-Bello M, Angulo-Cervera E, Godard L, Nicolazzi W, Salmon L, Molnár BA (2019) Phase stability of spin-crossover nanoparticles investigated by synchrotron Mössbauer spectroscopy and small-angle neutron scattering. J Phys Chem Lett 10(7):1511–1515
Wajnflasz J, Pick R (1971) Transitions Low spin—High spin dans les complexes de Fe\(^{2+}\). J de Physique Colloques 32:C1–91
Gudyma Iu, Maksymov A, Bobák A (2017) Modeling problems of spin crossover nanocrystals. In: Nanophysics, nanomaterials, interface studies, and applications, Springer, pp 63–77
Gudyma I, Maksymov A, Enachescu C (2014) Phase transition in spincrossover compounds in the breathing crystal field model. Phys Rev B 89:224412
Gudyma YV (2004) Nonequilibrium first-order phase transition in semiconductor system driven by colored noise. Physica A 331(1–2):61–68
Gudyma I, Maksymov A, Enachescu C (2010) Decay of a metastable high-spin state in spin-crossover compounds: mean first passage time analysis. Eur Phys J B 78(2):167–172
Gudyma Y, Semenko O (2004) Nonequilibrium kinetics in spin-crossover compounds. Phys Status Solidi B 241(2):370–376
Gudyma I, Maksymov A (2011) High spin metastable state relaxation of spin-crossover solids driven by white noise. J Phys Chem Solids 72:73–77
Gudyma I, Maksymov A, Dimian M (2013) Stochastic kinetics of photoinduced phase transitions in spin-crossover solids. Phys Rev E 88(4):042111
Gudyma I, Maksymov A, Spinu L (2015) Size effects in spin-crossover nanoparticles in framework of 2D and 3D Ising-like breathing crystal field model. Appl Surface Sci 352:60–65
Gudyma I, Ivashko V, Bobak A (2017) Surface and size effects in spin-crossover nanocrystals. Nanoscale Res Lett 12(1):101
Gudyma I, Maksymov A (2017) Surface-environment effects in spin-crossover solids. Appl Surface Sci 407:93–98
Gudyma I, Maksymov A, Miyashita S (2011) Noise effects in a finite-size Ising-like model. Phys Rev E 84(3):031126
Gudyma I, Maksymov A (2012) Optically induced switching in spin-crossover compounds: microscopic and macroscopic models and their relationship. Applied Opt 51(10):C55–C61
Gudyma I, Maksymov A (2019) The cooperativity in 3D spin-crossover nanocrystals with ferromagnetic and antiferromagnetic surface. Appl Surface Sci 489:779–784
Acknowledgements
The research of A.M. was partly supported by the project No.2015/19/B/ST2/01028 financed by National Science Centre (Poland).
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Gudyma, I., Maksymov, A. (2021). Ising-Like Model of Nanosize Spin-Crossover Molecular Crystals. In: Fesenko, O., Yatsenko, L. (eds) Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications . Springer Proceedings in Physics, vol 246. Springer, Cham. https://doi.org/10.1007/978-3-030-51905-6_11
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