Introduction
With the advent of nuclear-based analytical methods in the last 50 years, particle induced X-ray emission (PIXE) has established a role in the elemental analysis of archaeological material and cultural heritage. PIXE is a technique with a diverse array of applications in biology, geology, materials science, and others and has found valuable wide-ranging applications in archaeology and cultural heritage research. Such applications for archaeology and museum work generally fall into the categories of compositional analysis, provenance, understanding surface treatments and changes, and conservation and restoration.
Definition
The general definition of PIXE is “particle-induced X-ray emission” although this is often synonymous with “proton-induced X-ray emission,” which is a specific type of PIXE. Charged particles typically used in PIXE include both protons (p) and α-particles (He+2). Protons are produced in particle accelerators such as Van de Graff instruments, whereas...
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References
Abdelouahed, H. Ben, F. Gharbi, M. RoumiÈ, S. Baccouche, K. Ben Romdhane, B. Nsouli, and A. Trabelsi. 2010. PIXE analysis of medieval silver coins. Materials Characterization 61 (1): 59–64. https://doi.org/10.1016/j.matchar.2009.10.008.
Beck, Lucile. 2014. Recent trends in IBA for cultural heritage studies. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 332: 439–444. https://doi.org/10.1016/j.nimb.2014.02.113.
Beck, L., M. Lebon, L. Pichon, M. Menu, L. Chiotti, R. Nespoulet, and P. Paillet. 2011. PIXE characterisation of prehistoric pigments from Abri Pataud (Dordogne, France). X-Ray Spectrometry 40 (3): 219–223.
Bellot-Gurlet, Ludovic, GÈrard Poupeau, Joseph Salomon, Thomas Calligaro, Brice Moignard, Jean-Claude Dran, Jean-Alix Barrat, and Laurent Pichon. 2005. Obsidian provenance studies in archaeology: A comparison between PIXE, ICP-AES and ICP-MS. Nuclear Instruments and Methods in Physics Research B 240 (1–2): 588.
Calligaro, T. 2008. PIXE in the study of archaeological and historical glass. X-Ray Spectrometry 37 (2): 169–177. https://doi.org/10.1002/xrs.1063.
Calligaro, T., J.C. Dran, and M. Klein. 2003. Application of photo-detection to art and archaeology at the C2RMF. Nuclear Instruments and Methods in Physics Research A 504 (1–3): 213–221.
Dran, Jean-Claude, Joseph Salomon, Thomas Calligaro, and Philippe Walter. 2004. Ion beam analysis of art works: 14 years of use in the Louvre. Nuclear Instruments and Methods in Physics Research B 219–220: 7–15.
Ehmann, William D., and Diane E. Vance. 1991. In Radiochemistry and nuclear methods of analysis, Chemical analysis: A series on monographs on analytical chemistry and its applications, ed. J.D. Winefordner and I.M. Kolthoff, vol. 116. New York: Wiley.
Gazzola, J., M. Sánchez Del Río, C. Solís, and T. Calligaro. 2010. Particle-induced X-ray emission (PIXE) analysis of obsidian from teotihuacan. Archaeometry 52 (3): 343–354.
Johansson, Sven A.E., and John L. Campbell. 1988. PIXE: A novel technique for elemental analysis. Chichester: Wiley.
Johansson, Sven A.E., J.L. Campbell, and Klas G. Malmqvist, eds. 1995. Particle-induced X-ray emission spectrometry (PIXE), Chemical analysis: A series of monographs on analytical chemistry and its applications, ed. J.D. Winefordner, vol. 133. New York: Wiley.
Neelmeijer, C., I. Brissaud, T. Calligaro, G. Demortier, A. Hautojarvi, M. Mader, L. Martinot, M. Schreiner, T. Tuurnala, and G. Weber. 2000. Paintings-a challenge for XRF and PIXE analysis. X-Ray Spectrometry 29 (1): 101–110.
Pallon, Jan, Nathaly De La Rosa, Mikael Elfman, Per Kristiansson, E.J. Charlotta Nilsson, and Linus Ros. 2017. A new quantitative X-ray system for micro-PIXE analysis. X-Ray Spectrometry 46 (5): 319–324. https://doi.org/10.1002/xrs.2779.
Pappalardo, G., J. de Sanoit, A. Musumarra, G. Calvi, and C. Marchetta. 1996. Feasibility study of a portable PIXE system using a 210Po alpha source. Nuclear Instruments & Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms 109/110: 214–217.
Pappalardo, L., F.P. Romano, S. Garraffo, J. De Sanoit, C. Marchetta, and G. Pappalardo. 2003. The improved LNS PIXE-alpha portable system: Archaeometric applications. Archaeometry 45 (2): 333–339.
Polvorinos, A., M. Aucouturier, A. Bouquillon, J. Castaing, and J. Camps. 2011. The evolution of lustre ceramics from Manises (Valencia, Spain), between the 14th and 18th centuries. Archaeometry 53: 490–509. https://doi.org/10.1111/j.1475-4754.2010.00552.x.
Rizzo, F., G.P. Cirrone, G. Cuttone, A. Esposito, S. Garraffo, G. Pappalardo, L. Pappalardo, F.P. Romano, and S. Russo. 2011. Non-destructive determination of the silver content in roman coins (nummi), dated to 308-311 A.D., by the combined use of PIXE-alpha, XRF and DPAA techniques. Microchemical Journal 97 (2): 286–290. https://doi.org/10.1016/j.microc.2010.09.017.
Taylor, Larry, Richard B. Papp, and Bruce D. Pollard. 1994. Instrumental methods for determining elements. New York: VCH.
Torkiha, M., M. Lamehi-Rachti, O.R. Kakuee, and V. Fathollahi. 2010. An external sub-milliprobe optimized for PIXE analysis of archaeological samples. Nuclear Instruments and Methods in Physics Research B 268 (9): 1522.
Vadrucci, M., G. Bazzano, F. Borgognoni, M. Chiari, A. Mazzinghi, L. Picardi, C. Ronsivalle, C. Ruberto, and F. Taccetti. 2017. A new small-footprint external-beam PIXE facility for cultural heritage applications using pulsed proton beams. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 406: 314–317. https://doi.org/10.1016/j.nimb.2017.02.045.
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Popelka-Filcoff, R.S. (2018). Proton-Induced X-Ray Emission Spectroscopy (PIXE): Applications in Archaeology. In: Encyclopedia of Global Archaeology. Springer, Cham. https://doi.org/10.1007/978-3-319-51726-1_342-2
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DOI: https://doi.org/10.1007/978-3-319-51726-1_342-2
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