Summary
This article discusses surface-active quaternary ammonium compounds (QACs), an important class of industrial chemicals with a broad spectrum of commercial and consumer uses. Major emphasis is placed on the environmental chemistry and ecotoxicology of the most important classes of QACs. The discussion of environmental chemistry encompasses physical/chemical properties, analytical methods and monitoring data, wastewater treatment and environmental fate. Also addressed are production methods, volumes and uses. A summary of data on human health effects is presented. Existing data on the environmental chemistry and toxicity of QACs are critically reviewed, with the aim of determining where data are adequate for risk assessment, and where significant data gaps exist. This analysis shows that many QACs are readily biodegraded in sewage treatment and in receiving waters, but that their fate in benthic sediments is poorly understood. The bioavailability of sorbed or complexed QACs is another critical issue that deserves more emphasis in future research.
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References
Reck R (1982) In: Grayson M (ed) Kirk-Othmer encyclopedia of chemical technology, 3rd edn, vol 19. John Wiley, New York, p 521
Hardy FE, Talkes BE (1980) U.S. Patent 4238373, assigned to the Procter and Gamble Company, 9 December 1980
Chem Eng News (1987) 65:21
Charles H Kline and Co Inc (1981) Household cleaning products 1981
SRI (1984) Specialty chemicals. Strategies for success. Specialty surfactants, vol 9. SRI International, Menlo Park, CA
Chem Econ Eng Rev (1986) 18:32
Roes IJI, de Groot S (1988) In: Proceedings, 2nd world surfactants congress, “Surfactants in our World-Today and Tomorrow”, 24–27 May 1988, Paris
SRI (1981) Chemical economics handbook. SRI International, Menlo Park, CA
USEPA (1979) Needs survey. Conveyance and treatment of municipal wastewater. Summaries of technical data. U.S. Environmental Protection Agency, Washington, D.C. EPA-430/9–79–002
Gerike P, Fischer WK, Jasiak W (1978) Water Res 12:1117
Huber L (1982) Tens Deterg 19:178
Procter and Gamble (1984) Unpublished information submitted to A Stern (USEPA) by T Mooney (The Procter and Gamble Co), 12 September 1984
Woltering DM, Bishop WE (1989) In: Paustenbach DJ (ed) The risk assessment of environmental and human health hazards: a textbook of case studies. Wiley, New York, p 345
Games LM, King JE, Larson RJ (1982) Environ Sci Technol 16:483
Larson RJ, Vashon RD (1983) Dev Indust Microbiol 24:425
Weber JB, Coble HD (1968) J Agric Food Chem 16:475
Barbaro RD, Hunter JV (1965) Proc Indust Waste Conf, Purdue Univ 20:189
Moraru VN, Markova SA, Ovcharenko (1981) Ukr Khim Zh 47:1058
Skrylev LD, Streltsova EA (1979) Zh Prikl Khim 52:1493
Putnam FW (1948) Advan Protein Chem 4:79
Knox WE, Auerbach VH, Zarudnaya K, Spirtes M (1949) J Bacteriol 58:443
Klotz IM (1950) Sci Monthly 70:24
Chaplin CE (1951) Can J Bot 29:373
Mueller H, Krempl E (1963) Fette Seif Anstrich 65:532
May A, Neufahrt A (1976) Tens Deterg 13:65
McQuillen K (1950) Biochem Biophys Acta 5:463
Salton MRJ (1951) J Gen Microbiol 5:391
Fugita T, Koga S (1966) J Gen Appl Microbiol 12:229
Salt WG, Wiseman D (1968) J Pharmac (Suppl) 20:14S
Mackrell JA, Walker JRL (1978) Int Brodeterior Bull 14:77
Ginn ME (1970) In: Jungermann E (ed) Cationic surfactants. Marcel Dekker, New York, p 341
Swisher RD (1970) Surfactant biodegradation. Marcel Dekker, New York
Neufahrt A, Lötzsch K, Pleschke D, Spaar G (1983) Comun Jorn Com Esp Deterg 14:9
Scowen RV, Leja J (1967) Can J Chem 45:2821
Huber L (1979) Munchn Beitr J Abwasser Fischerei Flu Biol 31:203
Kupfer W (1982) Tens Deterg 19:158
Topping BW, Waters J (1982) Tens Deterg 19:164
Wee VT, Kennedy JM (1982) Anal Chem 54:1631
Lewis MA, Wee VT (1983) Environ Toxicol Chem 2:105
Wee VT (1984) Water Res 18:223
Llenado RA, Jamieson RA (1981) Anal Chem 53:174R
Waters J, Kupfer W (1976) Anal Chim Acta 85:241
Cain RB (1977) In: Callely AG, Forster CF, Stafford DA (eds) Treatment of industrial effluents. Hodder and Stoughton, London, p 283
Osburn QW (1982) J Am Oil Chem Soc 59:453
Michelsen ER (1978) Tens Deterg 15:169
Pitter P (1961) Sb Vysoke Skoly Chem Technol Praze, Technol Vody 5:25
Uhl A, Sedlmayer H (1965) Brauwelt Jg 105:1529
Pauli O, Franke G (1971) Gesundwes Desinfekt 63:150
Barden L, Isaac PCG (1957) Proc Inst Civ Engr 6:371
Gerike P (1982) Tens Deterg 19:162
Wierich P, Gerike P (1981) Ecotoxicol Environ Saf 5:161
Janicke W, Hilge G (1979) Tens Deterg 16:117
Gerike P, Fischer WK (1979) Ecotoxicol Environ Saf 3:159
Krzeminski SF, Martin JJ, Brackett CK (1973) Household and Personal Products Indust 10:22
Sulllivan DE (1983) Water Res 17:1145
Ruiz Cruz J (1987) Grasas Aceites 38:383
Sheets WD, Malaney GW (1956) Sew Indust Wastes 28:10
Gawel LJ, Huddleston RD (1972) American Oil Chemists’ Society national meeting, 23–26 April 1972. Los Angeles, CA
Dean-Raymond D, Alexander M (1977) Appl Environ Microbiol 33:1037
Masuda F, Machida S, Kanno M (1978) In: Proc. 7th international congress on surface-active agents. Moscow, U.S.S.R., p 129
Miura K, Yamanaka K, Sangai T, Yoshimura K, Hayashi N (1979) Yukagaku 28:351
Larson RJ (1979) Appl Environ Microbiol 38:1153
Larson RJ, Wentler GE (1982) Soap/Cosmetics/Chemical Spec 58:33
Larson RJ (1983) Residue Rev 85:159
Kaplin VT, Zernova LS, Kosogova AS (1968) Ghidrokhim Mater 44:196
Baleux B, Caumette P (1977) Water Res 11:833
Ruiz Cruz J, Dobarganes Garcia MC (1979) Grasas Aceites 30:67
Larson RJ, Perry RL (1981) Water Res 15:697
Vives-Rego J, Vaque MD, Sanchez Leal J, Parra J (1987) Tens Deterg 24:20
Ruiz Cruz J (1979) Grasas Aceites 30:293
Ruiz Cruz J (1981) Grasas Aceites 32:147
Ventullo RM, Larson RJ (1986) Appl Environ Microbiol 51:356
Larson RJ, Bishop WE (1988) Soap/Cosmetics/Chemical Spec 64:58
Shimp RJ, Young RL (1988) Ecotoxicol Environ Saf 15:31
Shimp RJ (1989) Environ Toxicol Chem 8:201
Larson RJ (1984) Household and Personal Products Indust 21:55
Federle TW, Pastwa GM (1988) Ground Water 26:761
Lawrence CA (1970) In: Jungermann E (ed) Cationic surfactants. Marcel Dekker, New York, p 491
Sayama N (1981) Nippon Eiseigaku Zasshi 35:869
Van Beneden G (1952) Bull CEBEDEAU no. 17:159
Manganelli R, Crosby ES (1953) Sew Indust Wastes 25:262
Reynolds L, Blok J, de Morsier A, Gerike P, Wellens H, Bontinck WJ (1987) Chemosphere 16:2259
Manganelli R (1952) Sew Indust Wastes 24:1057
Fenger BH, Mandrup M, Rohde G, Kjaer Sorensen JC (1973) Water Res 7:1195
Larson RJ, Schaeffer SL (1982) Water Res 16:675
Pitter P, Horska M (1968) Sb Vysoke Skoly Chem Technol Praze, Technol Vody F14:19
Taft CH (1946) Texas Rpt Biol Med 4:27
Pessoa SB (1952) Folia Clin Biol 18:137
Vallejo-Freire A, Ribeiro OF, Ribeiro IF (1954) Science 119:470
Knauf W (1973) Tens Deterg 10:251
Fischer WK, Gode P (1977) Vom Wasser 48:247
Reiff B, Lloyd R, How MJ, Brown D, Alabaster JS (1979) Water Res 13:207
Kappeier TU (1982) Tens Deterg 19:169
Waters J (1982) Tens Deterg 19:177
Walker JRL, Evans S (1978) Marine Pollut Bull 9:136
Lewis MA (1986) Environ Toxicol Chem 5:319
Lewis MA, Hamm BG (1986) Water Res 20:1575
Lewis MA, Taylor M, Larson R (1986) In: Cairns J (ed) Multispecies toxicity testing. American Society for Testing and Materials, Philadelphia, PA, p 241. ASTM STP 920
Woltering DM, Larson RJ, Hopping WD, Jamieson RA, de Oude NT (1987) Tens Deterg 24:286
Cooper JC (1988) Ecotoxicol Environ Saf 16:65
Marchetti R (1964) Riv Ital Sostanze Grasse 41:553
Biesinger KE, Stokes GN (1968) J Water Pollut Contr Fed 58:207
Neufahrt A, Eckert HG, Kellner HM, Lötzsch K (1978) CED Congress, March 1978. Madrid
Knezovich JP, Lawton MP, Inouye LS (1989) Bull Environ Contam Toxicol 42:87
Matthijs E, de Henau H (1987) Vom Wasser 69:73
Schneider E, Levsen K (1986) Comm Eur Commun, EUR 10388 Org Micropollut Aquatic Environ, p 14
ITC (1988) Fed Regist 53:18196
Kunieda H, Shinoda K (1978) J Phys Chem 82:170
Pittinger CA, Hand VC, Masters JA, Davidson LF (1988) In: Adams WJ, Chapman GA, Landis WG (eds) Aquatic toxicology and hazard assessment, 10th vol. American Society for Testing and Materials, Philadelphia, PA, p 138. ASTM STP 971
Armak Co (1980) Toxicity data for aliphatic nitrogen compounds. Armak Co, Chicago, IL
Deichmann WB, Gerarde H W (1969) Toxicology of drugs and chemicals. Academic, New York, p 690
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Boethling, R.S., Lynch, D.G. (1992). Quaternary Ammonium Surfactants. In: de Oude, N.T. (eds) Detergents. Anthropogenic Compounds, vol 3 / 3F. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-47108-0_3
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DOI: https://doi.org/10.1007/978-3-540-47108-0_3
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