Abstract
Powder metallurgy can proceed in two fundamentally different ways for the fabrication of products from powders of refractory borides. One way — conventional sintering — includes molding or compacting of products from the powder (compression in steel die, isostatic compression, injection molding, rolling, slip casting etc.) with subsequent sintering of the compacts. The other way — hot pressing — combines the pressing and sintering processes and is discussed in Chapter C.XIII. For both ways, the raw boride material must previously be milled to a sufficiently fine particle size.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A.E.M.C. (American Electro Metal Corp.): Cemented Borides. Summary Progress Report. PB 121346. Wash. D.C: O.T.S. 1955
A.E.M.C. (American Electro Metal Corp.): Cemented Metallic Borides. Final Summary Report. PB 139415. Wash. D.C.: O.T.S. 1958
AUGUSTINIK, A.I., DROZDETSKAYA, G.V.: Conditions for making manufactured objects from metal-like refractories by dross casting. Izvest. V.U.Z., Khim. Khim. Tekhnol. l0, 556–558 (1967)
BABICH, B.N., PORTNOI, K.I., SAMSONOV, G.V.: Compacting and sintering of boride powders. Metalloved Term. Obrabot. Metallov, 1, 31–35 (1960). Translation in English: HB-5301; H. Brutcher, Altadena, California; or AD 273601, Washington, D.C.: O.T.S.
BROUSSAUD, D., ACCARY, A., PASTOR, H., MEYER, R.: Preparation et propriétés des cermets TiB2-NiAl. High Temp. High Pressures 6, 455–461 (1974)
BROUSSAUD, D., PASTOR, H., MEYER, R., ACCARY, A.: On the behavior of titanium di-boride towards nickel-aluminium Ni-Al. In: Modern Developments in Powder Metallurgy. Vol. 8. (H.H. Hausner, W.E. Smith, eds.) pp. 589–601. Princeton, N.J.: M.P.I.F., A.P.M.I. (1974)
BUMM, H., LIEPELT, H.: Results of isostatic pressing of metallic and non-metallic powders up to 15000 atmospheres. Z. Werkstoff technik 3, 364–368 (1972)
ČECH, B., OLIVIERUS, P., SEJBAL, J.: Sintering of zirconium boride with activating additions. Powder Met. 8, (N°15), 142–151 (1965)
C.I.M.E. (Compagnie Industrielle des Métaux Electroniques): Boitiers de montre en matériau extra-dur. Fr. 2067099, (Aug. 20, 1971)
COBLE, R.L., HOBBS, H.A.: Sintering. In: Investigation of Boride Compounds for Very High Temperature Applications. (L. Kaufman, E.V. Clougherty, eds.), Report AD 428006, pp. 82–120. Springfield, Va.: N.T.I.S. 1973
DOBROVOL’ SKII, A. G., DOBROVOL’SKII, G.G., LYUDVINSKAYA, T. A., POPICHENKO, E.Y.: Slip casting of zirconium boride. Izvest. Akad. Nauk S.S.S.R., Neorg. Mater. 2, 864–869 (1966)
DOBROVOL’ SKII, A. G., DOBROVOL‘SKII, G.G., LYUDVINSKAYA, T. A., POPICHENKO, E.Y.: Slip casting of zirconium boride. Translation in English: Inorg. Mater. 2, 735–739 (1966)
DOBROVOľ SKII, A.G., NIKITIN, Y.I., SOKHIN, M.S., TUTAKOV, O.V.: Preparation of powders on a planetary mill. Poroshk. Metal 6, 1–7 (1967).
DOBROVOľ SKII, A.G., NIKITIN, Y.I., SOKHIN, M.S., TUTAKOV, O.V.: Preparation of powders on a planetary mill. Translation in English: Soviet Powder Met. 6, 429–433 (1967)
D’YAKONOVA, L.V., KISLYI, P.S.: Comminution characteristics of zirconium diboride. Poroshk. Metal. (1), 1–5 (1972).
D’YAKONOVA, L.V., KISLYI, P.S.: Translation in English: Soviet Powder Met. (1), 1–4 (1972)
ELLIOTT, A.G., LAVENDEL, H.W.: Sintering of TaB2. In: Sintering and Related Phenomena. (G.C. Kuczynski, N.A. Hooton, C.F. Gibbon, eds.) pp. 565–579. New York: Gordon and Breach, 1967
EVANS, R.M.: Boride parts resist molten Zinc. Materials and Methods 43, 132–133 (1956)
FARRIOR, G.M.: An investigation of the physical properties of several transition metal diborides and of binary diboride solid solutions. Dissert. Graduate Council Univ. Tennessee in partial fulfillment of the requirements for the degree of Dr. of Philos. 158 pp. (1965)
FITZER, E.: Classical sintering, reaction-sintering, and hotpressing of high-melting AB2-hard alloys. Arch. Eisenhüttenw. 44, 703–709 (1973)
FUNKE, V.F., YUDKOVSKII, S.I., SAMSONOV, G.V.: Alloys in the system B-Ti-Fe. Zhur. Prikladn, Khim. 34, 1013–1020 (1961).
FUNKE, V.F., YUDKOVSKII, S.I., SAMSONOV, G.V.: Alloys in the system B-Ti-Fe. Translation in English: Russ. J. Appl. Chem. 34, 973–978 (1961)
FUNKE, V.F., YUDKOVSKII, S.I.: High-temperature oxidation of the alloys of titanium boride with iron group metals. Zhur. Fiz. Khim. 37, 1557–1562 (1963).
FUNKE, V.F., YUDKOVSKII, S.I.: High-temperature oxidation of the alloys of titanium boride with iron group metals. Translation in English: Russ. J. Phys. Chem. 37, 835–837 (1963)
GROPYANOV, V.M.: Effect of dispersion on powder sintering, Ogneupory 34, 46–52 (1969).
GROPYANOV, V.M.: Effect of dispersion on powder sintering, Translation in English: Refractories 34, 769–775 (1969)
HOFMANN, J., ADAM, J.: Influence of some characteristics of powdered zirconium diboride on its sinterability (in Czech.) Pokroky Praskove Met. (1), 3–12 (1970)
HOYT, E.W., CHORNE, J.: Preparation of self-bonded borides. Vallecitos Atomic Laboratory, General Electric Co., Pleasanton, Calif., CEAP-3332. Wash. D.C.: O.T.S. 1960
ISKOLDSKY, I.I., BOGORODSKAYA, L.P.: The possibility of production of metalloceramic (sintered) hard alloys based on chromium, titanium and tungsten borides. Zh. Priklad. Khim. 30, 177–185 (1957).
ISKOLDSKY, I.I., BOGORODSKAYA, L.P.: The possibility of production of metalloceramic (sintered) hard alloys based on chromium, titanium and tungsten borides. Translation in English: Russian J. Appl. Chem. 30, 181–188 (1957)
JAYNE, T.D.: (to Rand Development Corp., Cleveland, Ohio). Tool material. US 2996793, (Aug. 22, 1961)
KANEKO, A., NISHIMURA, T., ISHIBASHI, O., TOMONO, S.: The sintering process of WB-Co and WB-Ni. Nippon Tungsten Review 6, 80–86 (1973)
KIPARISOV, S.S., NIKIFOROV, O.A., KUZ’MINA, Y.K.: Possible sintering of tungsten borides with nickel. Izvest. V.U.Z., Tsvetn. Met. 13, 93–95 (1970)
KISLYI, P.S.: Sintering of blanks obtained by pressing powders of refractory compounds. Poroshkov. Met. (5), 68–78 (1962). Translation in English: Soviet Powder Met. (5), 363–370 (1962)
KISLYI, P.S., KUZENKOVA, M.A.: Gas-impermeable protective thermocouple sheaths from zirconium boride. Poroshk. Met. (1), 32–36 (1965). Translation in English: Soviet Powder Met. (1), 23–26 (1965)
KISLYI, P.S., KUZENKOVA, M.A.: Regularities of sintering of zirconium diboride-molybdenum alloys. Poroshk. Met. (5), 16–23 (1966a). Translation in English: Soviet Powder Met. (5), 360–365 (1966a)
KISLYI, P.S., KUZENKOVA, M.A.: Some properties of ZrB2-Mo alloys. Izvest. Akad, Nauk S.S.S.R., Neorg. Mater. 2, 2139–2144 (1966b).
KISLYI, P.S., KUZENKOVA, M.A.: Some properties of ZrB2-Mo alloys. Translation in English: Inorg. Mater. 2, 1850–1854 (1966b)
KISLYI, P.S., KUZENKOVA, M.A.: Cermets and alloys of refractory compounds with molybdenum and tungsten. In: Trudy Vsesoyuz. Nauch.-Tekhn. Konf. po Metallokeram. Mater. i Izdeliyam. (ed., N.V. Manukyan et al.), pp. 226–230, Erevan, 1973
KISLYI, P.S., KUZENKOVA, M.A., STRUK, L.I., MORGUNOVSKAYA, B.A., ZVAZHENKO, V.K., BOL’SHECHENKO, A.G., OSTROVERKHOV, V.I.: Protective sheaths of thermocouples for automatic thermal control over metallurgical processes. Poroshk. Met., (12), 49–56 (1972). Translation in English: Soviet Powder Met, (12), 987–992 (1972b)
KISLYI, P.S., KUZENKOVA, M.A., ZAVERUKHA, O.V.: On the sintering process of zirconium diboride with tungsten. Phys. Sintering 3, 29–44 (1971)
KISLYI, P.S., KUZENKOVA, M.A., ZAVERUKHA, O.V.: The effect of the particle size of powders on the sintering kinetics of titanium diboride. Phys. Sintering, 4, 107–118 (1972a)
KISLYI, P.S., SAMSONOV, G.V.: Basic principles of the extrusion-die production of pipes and rods from powders of highmelting compounds. Poroshkov. Met. (3), 31–48 (1962). Translation in English: Soviet Powder Met. (3), 164–177 (1962)
KISLYI, P.S., ZAVERUKHA, O.V.: Vacuum sintering of titanium diboride. Poroshk. Met. (7), 32–35 (1970). Translation in English: Soviet Powder Met. (7), 549–551 (1970)
KOVAL’CHENKO, M.S., SAMSONOV, G.V.: Study of alloys of zirconium boride with molybdenum. Voprosy Poroshkovoi Met. i Prochnosti Materialov, 7, 18–24 (1959)
KUDINTSEVA, G.A., KONDRATOV, I.Y., KUZNETSOVA, G.M.: Preparation and certain prop erties of cermet alloys of tungsten with yttrium hexaboride. Izvest. Akad. Nauk S.S.S.R., Neorg. Mater. 6, 1335–1336 (1970). Translation in English: Inorg. Mater. 6, 1172–1173 (1970)
KUDINTSEVA, G.A., KUZNETSOVA, G.M., NAMEDOV, F.G., MEERSON, G.A., TSAREV, B.M.: Production of sintered cathodes from pure lanthanum hexaboride and determination of their emission properties. Izvest. Akad. Nauk S.S.S.R., Neorg. Mater. 4, 49–53 (1968).
KUDINTSEVA, G.A., KUZNETSOVA, G.M., NAMEDOV, F.G., MEERSON, G.A., TSAREV, B.M.: Production of sintered cathodes from pure lanthanum hexaboride and determination of their emission properties. Translation in English: Inorg. Mater. 4, 38–42 (1968)
KUZENKOVA, M.A., KISLYI, P.S.: Grain growth in zirconium diboride during sintering. Poroshk. Met. (1), 12–16 (1966a). Translation in English: Soviet Powder Met., (1), 10–13 (1966a)
KUZENKOVA, M.A., KISLYI, P.S.: The mechanism of shrinkage of zirconium diboride during sintering. Poroshkov. Met. (2), 46–55 (1966b). Translation in English: Soviet Powder Met. (2), 114–121 (1966b)
KUZENKOVA, M.A., KISLYI, P.S., ZAVERUKHA, O.V., KUZ’MA, Y.B.: Structure and prop erties of zirconium diboride — tungsten alloys. Poroshk. Met. (11), 32–37 (1971) Translation in English: Soviet Powder Met. (11), 879–883 (1971)
KUZNETSOVA, G.M., KUDINTSEVA, G.A., LIKHACHEVA, T.K., SUCHKOV, L.K.: Production of large-sized lanthanum hexaboride parts. Poroshk. Met. (10), 46–51 (1972). Translation in English: Soviet Powder Met. (10), 810–814 (1972)
LAFFERTY, J.M.: Boride cathodes. J. Appl. Phys. 22, 299–309 (1951)
MANDORF, V., HARTWIG, J., SELDIN, E.J.: High temperature properties of titanum diboride. In: High Temperature Materials. (G.M. AUTL, W.F. Barclay, H.P. Munger, eds.), Vol.II, pp. 455–467. New York: Wiley Interscience 1963
MATSERA, V.E., PUGIN, V.S., DOBROVOľ SKII, A.G., NIKITIN, Y.I., POGORELYI, B.V., STRASHINSKAYA, L.V., GORNOSTAEV, V.F.: Ultrasonic comminution of refractory compound powders. Poroshk. Met. (12), 11–16 (1971). Translation in English: Soviet Powder Met. (12), 948–952 (1971)
MATSERA, V.E., PUGIN, V.S., DOBROVOľ SKII, A.G., GORNOSTAEV, V.F., STRASHINSKAYA, L.V., DERENOVSKAYA, N.A.: Comminution of powders in the planetary centrifucal mill. I. Determination of the optimum comminution conditions. Poroshk. Met. (6), 11–15 (1973a). Translation in English: Soviet Powder Met. (6), 447–450 (1973a)
MATSERA, V.E., PUGIN, V.S., STRASHINSKAYA, L.V., DOBROVOL’ SKII, A.G., NIKITIN, Y.I., POGORELYI, B.V.: Comminution of powders in the planetary centrifugal mill. II. Some milling characteristics. Poroshkov. Met. (7), 11–17 (1973b). Translation in English: Soviet Powder Met. (7), 525–530 (1973b).
MATTERSON, K.J., JONES, H.: A study of the tetraborides of uranium and thorium. Trans. Brit. Ceram. Soc, 60, 475–493 (1961)
MCTAGGART, G.D., WILLMORE, T.A., BENNETT, D.G.: Metal bonded zirconium diboride. Washinton, D.C.: O.T.S. 1954
MEDVEDEV, O.G., TRUNOV, G.V., CHERNYAK, L.V., SHLYUKO, V.Y.: Production of parts of complex shape in lanthanum hexaboride. Poroshk. Met. (3), 101–102 (1971). Translation in English: Soviet Powder Met. (3), 250–251 (1971).
MEERSON, G.A., GORBUNOV, A.F.: Activated sintering of zirconium boride. Izvest. Akad. Nauk S.S.S.R., Neorg. Mater. 4, 320–324 (1968).
MEERSON, G.A., GORBUNOV, A.F.: Activated sintering of zirconium boride. Translation in English: Inorg. Mater. 4, 267–270 (1968)
MEERSON, G.A., MAMEDOV, F.G.: Investigation of sintering conditions for lanthanum hexaboride. Izvest. Akad. Nauk S.S.S.R., Neorg. Mater., 3, 942–949 (1967).
MEERSON, G.A., MAMEDOV, F.G.: Investigation of sintering conditions for lanthanum hexaboride. Translation in English: Inorg. Mater. 3, 844–850 (1967)
MEERSON, G.A., MANELIS, R.M., TELYUKOVA, T.M.: Peculiarities of the production of objects from lanthanum and yttrium hexaborides by sintering under vacuum. Izvest. Akad. Nauk S.S.S.R., Neorg. Mater. 2, 291–298 (1966).
MEERSON, G.A., MANELIS, R.M., TELYUKOVA, T.M.: Peculiarities of the production of objects from lanthanum and yttrium hexaborides by sintering under vacuum. Translation in English: Inorg. Mater. 2, 250–255 (1966)
MEYER, R., PASTOR, H.: Les borures réfractaires. Étude particulière des borures de titane et de zirconium: préparation, propriétés et applications. Bull. Soc. Fr. Céramique (N°66), 59–80 (1965)
MEYER, R., PASTOR, H.: Frittage et compression à chaud des diborures de titane et de zirconium. Planseeber. Pulvermet. 17, 111–122 (1969)
MORDUCH, D.W.: An investigation into the suitability of using borides of the transi tion elements for cutting tool and drawing die purpose. Thesis for Diploma of Imperial College of Science and Technology, London 1962
M.P. GmbH (Metallwerk Plansee GmbH): Bodies of chromium boride and chromium molybdenum and their production. Brit. 809555 (Feb. 25, 1959)
NELSON, J.A., WILLMORE, T.A., BENNETT, D.G.: Metal bonded titanium diboride. Report PB 143651, Washington, D.C.: O.T.S. 1952
PASTOR, H.: Le frittage et la compression à chaud des composés réfractaires non oxydes: borure, carbures, nitrures et siliciures. L’industrie Céramique (N°615), 89–104 (1969)
PECHINEY: Réfractaires, Fr. 1215 862, (April 21, 1960a)
PECHINEY: Réfractaires spéciaux, Fr. 1216 522, (April 26, 1960b)
PENDSE, D.R., PRATT, P.L.: A study of the physical and mechanical properties of cemented borides. In: Special Ceramics. Vol. 5. (P. Popper, ed.), pp. 135–146. Stoke-on-Trent: The British Ceramic Research Association, 1972
PRSHEDROMIRSKAYA, E.M., SKEPTSOV, V.M.: Some regular features in the sintering of porous parts from high-melting-point compounds. Poroshk. Met. (4), 11–15 (1966). Translation in English: Soviet Powder Met. (4), 269–272 (1966)
RASSKAZOV, N.I.: Sintering of zirconium diboride in the presence of molybdenum, tungsten and boron. In: Third International Powder Metallurgy Conference, Karlovy Vary, Czechoslovakia, Vol. 2, pp. 228–238 (1970)
REDDY, R.L., MONTGOMERY, L.C., GRULKE, C.A.: Slip casting composition. Brit. Pat. 1052 590 (Dec. 30, 1966)
REIDL, R.W., HARTWIG, J.: Titanium diboride articles and methods for making same. US 3215 545 (Nov. 2, 1965)
SAMSONOV, G.V.: Nature of interaction between titanium boride and the iron group metals. Metalloved. Term. Obrabot. Metal. (1), 35–38 (1958). Translation in English: HB 4122, H. Brutcher, Altadena, California
SAMSONOV, G.V., KONDRATOV, I.Y.: Cermet alloys of rhenium with yttrium hexaboride. Poroshk. Met. (8), 87–91 (1969). Translation in English: Soviet Powder Met. (8), 673–676 (1969)
SAMSONOV, G.V., KOVAL’CHENKO, M.S.: Some features of the sintering of powders of refractory compounds. Poroshk. Met. (1), 2029 (1961). Translation in English: AEC-tr-5604. Washington, D.C.: O.T.S.
SAMSONOV, G.V., MARKOVSKII, L.Y., ZHIGACH, A.F., VALYASHKO, M.G.: Bor, ego soedineniya i splavy. Kiev.: Akad. Nauk. Ukrain. S.S.R., 1960. Translation in English: Boron, its Compounds and Alloys. AEC-tr-5032, Washington, D.C.: O.T.S. 1962
SAMSONOV, G.V., MATSERA, V.E.: Manufacture and properties of powder metallurgical refractury compound fibers and porous fiber materials. Poroshk. Met. (9), 42–47 (1972). Translation in English: Soviet Powder Met. (9), 719–723 (1972)
SAMSONOV, G.V., MATSERA, V.E.: Pore-rich fiber materials made from high-melting compounds. Powder Met. Int. 5, 133–134; 136 (1973)
SAMSONOV, G.V., NESHPOR, V.S.: Compressibility of powders of borides, carbides and nitrides of refractory metals. Doklady Akad. Nauk S.S.S.R. 104, 405–408 (1955). Translation in English: HB-3661, H. Brutcher, Altadena, California
SAMSONOV, G.V., PORTNOI, K.I.: Splavy na osnove tugoplavkikh soedineniy. Moscow: Gosudarst. Nauchno-Tekhn. Izdat. Oborongiz, 1961. Translation in English: Alloys Based on High Melting Compounds. AD 283 859. N.T.I.S., Springfield, Va.: N.T.I S 1962
S.E.C.E.M.A.E.U. (Société d’Electrochimie, d’Electrométallurgie et des Aciéries Electriques d’Ugine): Procédé de fabrication d’un mélange de borure de chrome et d’alliage chrome-molybdène et produit obtenu par ce procédé. French Pat. 1147 790 (Nov. 29, 1957)
SHLYUKO, V.Y., CHERNYAK, L.V.: Investigation of the sintering conditions of parts made from lanthanum hexaboride. Poroshk. Met. (12), 41–45 (1967). Translation in English: Soviet Powder Met. (12). 969–972 (1967)
SLEPTSOV, V.M., PRSHEDROMIRSKAYA, E.M., KUKOTA, Y.P.: Porous materials from carbides and borides of the transition metals. Poroshk. Met. (10), 85–90 (1965). Translation in English: Soviet Powder Met. (10), 849–853 (1965)
SLEPTSOV, V.M., PRSHEDROMIRSKAYA, E.M., VITRYANYUK, V.K.: Porous materials from refractory compounds. Rev. Int. Hautes Temper. et Refract. 6, 131–135 (1969)
SMITH, E.A.: Comminuting very hard and soft solids. Metals and Materials 4, 426–428 (1970)
STRUK, L.I.: Study of the densification of refractory compound powders by the electrical conductivity method. Poroshk. Met. (3), 14–20 (1966). Translation in English: Soviet Powder Met. (3), 184–188 (1966)
TAKAGI, R., TAMURA, K., YOSHIDA, S.: Some properties of sintered CrB. Nippon Kinzoku Gakkaishi 20, 375–377 (1956)
TANGERMANN, I.: On the behavior of heavy-metal borides toward binder metals. Neue Hütte 8, 359–365 (1963). Translation in English: HB-6007, H. Brutcher, Altadena, California
TYRRELL, M.E., HOUCK, C.W.: Metallic binders for zirconium diboride: iron, cobalt and nickel. US Bureau of Mines, RI-6262 (1963)
TYRRELL, M.E., HOUCK, C.W.: Metallic binders for zirconium diboride: chromium, molybdenum and tungsten. US Bureau of Mines, RI-6549 (1964)
U.S. Borax (United States Borax and Chemical Corporation): Improvements in or relating to abrasion-resistant materials. Brit. 994 435 (June 10, 1965)
YUDKOVSKII, S.I., EIKHMANS, E.F., GUSEVA, A.N., FUNKE, V.F., ROMANOV, K.F., SMIRNOV, F.F.: Cutting and physical mechanical properties of alloys with a titanium boride base. Sbornik Tr. vsesoyuz. nauchn.-issled. Inst. Tverd. Splavov 5, 130–141 (1964)
ZAVERUKHA, O.V.: Sintering titanium diboride — molybdenum compacts. In: Tekhnologiya polucheniya novikh materialov, pp. 93–98. Kiev: Akad. Nauk. Ukr. S.S.R., Institut Problem Materialovedeniya, 1972. Translation in English: Technology of Producing New Materials. JPRS-59873, pp. 53–58; N.T.I.S., Springfield, Va.: N.T.I.S. 1973
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1977 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Pastor, H. (1977). Metallic Borides: Preparation of Solid Bodies — Sintering Methods and Properties of Solid Bodies. In: Matkovich, V.I. (eds) Boron and Refractory Borides. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-66620-9_25
Download citation
DOI: https://doi.org/10.1007/978-3-642-66620-9_25
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-66622-3
Online ISBN: 978-3-642-66620-9
eBook Packages: Springer Book Archive