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Introduction to Solid-State NMR

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Solid-State NMR I Methods

Part of the book series: NMR ((NMR,volume 30))

Abstract

Solid-state NMR spectra generally reflect the sum of several independent interactions such as Zeeman, dipolar and quadrupolar coupling as well as magnetic shielding effects. To obtain the desired information, separation of these effects and their decoding is essential. Within the first part, as a basis of the successful separation of the NMR effects, the common and also the different (tensorial) properties of each interaction are discussed in detail. The second part mainly deals with the experimental design of solid-state high-resolution NMR experiments to suppress certain interactions and with wide-line experiments. Finally the principles of NMR imaging and NMR microscopy are described as an alternative method for investigating solids by NMR.

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References

  1. la. Purcell EM, Torey HC, Pound ME (1946) Phys. Rev. 69: 37

    CAS  Google Scholar 

  2. Pake GE (1948) J. Chem. Phys. 16: 327

    CAS  Google Scholar 

  3. Dehmelt HG, Kruger H (1950) Naturwiss. 37: 111

    CAS  Google Scholar 

  4. Silver AH, Bray JB (1958) J. Chem. Phys. 29: 984

    CAS  Google Scholar 

  5. Proctor WG, Yu FC (1950) Phys. Rev 77: 717

    CAS  Google Scholar 

  6. Dickinson WC (1950) Phys. Rev. 77: 736

    CAS  Google Scholar 

  7. Gutowsky HS, McCall DW, Slichter CP (1953) J. Chem. Phys. 21: 279

    CAS  Google Scholar 

  8. Ebert I, Seifert G (1966) Kernresonanz im Festkörper. Leipzig, p 51

    Google Scholar 

  9. Zschunke A (1977) Kernmagnetishe Resonanzspektroskopie in der organischen Chemie, Berlin, p 70

    Google Scholar 

  10. Andrew ER (1961) Nuclear magnetic resonance. Oxford University Press, Oxford

    Google Scholar 

  11. Pines A, Gibby MG, Waugh JS (1972) J. Chem. Phys. 56: 1776, ibd. (1973) 59: 569

    CAS  Google Scholar 

  12. Waugh JS, Huber LM, Haeberlen U (1986) Phys. Rev. Lett. 20: 108

    Google Scholar 

  13. Ernst RR, Anderson WA (1966) Rev. Sci. Instr. 37: 93

    CAS  Google Scholar 

  14. Jeener J (1971) Lecture at the Ampere Summer School, Basko Polje

    Google Scholar 

  15. Ernst RR, Bodenhausen G, Wokaun A (1987) Principles of NMR in one and two dimensions, Clarendon, Oxford

    Google Scholar 

  16. Lauterbur PC (1973) Nature 242: 190

    CAS  Google Scholar 

  17. Mansfield P, Hahn EL (eds) (1990) NMR Imaging Royal Society. London

    Google Scholar 

  18. Callaghan PT (1991) Principles of nuclear magnetic resonance microscopy. Clarendon, Oxford

    Google Scholar 

  19. Fyfe CA (1983) Solid state NMR for Chemists Guelph

    Google Scholar 

  20. Haeberlen U (1976) High resolution NMR in solids: Selective averaging. Adv. Magn. Reson. Suppl. 1. Academic, New York

    Google Scholar 

  21. Gerstein BC, Dybowski C: R (1985) Transient techniques in NMR of solids. Academic, New York

    Google Scholar 

  22. Abragam A (1961) The principles of Nuclear Magnetism. Clarendon, Oxford

    Google Scholar 

  23. Engelhardt G, Michel D (1987) High Resolution Solid State NMR of Silicates and Zeolites. Wiley, New York

    Google Scholar 

  24. Harris RK (1987) NMR spectroscopy-a physicochemical view. Harlow

    Google Scholar 

  25. Mehring M (1980) Principles of high resolution NMR in solids, 2nd edn. Springer, Berlin Heidelberg, New York

    Google Scholar 

  26. Wieker W, Grimmer A-R (1966) Z. Naturf, 21b: 1103

    Google Scholar 

  27. Farrar FC, Harriman JE (1992) Density matrix theory and its application in spectroscopy. The Farragut Press Madison Vol 1

    Google Scholar 

  28. Fyfe CA, Gobbi GC, Kunowski J, Thomas JM, Ramdas S (1981) Nature 296: 350

    Google Scholar 

  29. Grimmer A-R, Cudinova AN (1972) Z. Chemie 12: 149

    CAS  Google Scholar 

  30. Jameson CI, de Dios AC (1993) Nuclear magnetics shieldings and molecular structure, ed. Tossell JA, NATO ASI series 386: 95

    Google Scholar 

  31. Slichter CP (1989) Principles of magnetic resonance. 3rd edn. Springer, Berlin, Heidelberg, New York

    Google Scholar 

  32. Spiess HW (1978) Rotation of molecules and nuclear spin relaxation in NMR-Basic principles and progress. 15: 55

    CAS  Google Scholar 

  33. Aleksandrov IV (1975) Teorija magnituoi relaksazija Moskva

    Google Scholar 

  34. Gobetto R, Harris RK, Apperley DC (1972) J. Magn. Reson. 96: 119

    Google Scholar 

  35. Duncan TM (1990) A compilation of chemical shift anisotropics. The Farragut Press, Chicago

    Google Scholar 

  36. Anet FAL, O’Leary DJ (1991) Concepts. Magn. Reson. 3: 193

    CAS  Google Scholar 

  37. Hansen AE, Bouman ThD (1993) Nuclear magnetic shieldings and molecul. structure, ed. Tossell JA, NATO ASI Series 386: 47

    Google Scholar 

  38. Jameson CI, de Dios AC (1993) private communication

    Google Scholar 

  39. Mason J, ed: Multinuclear NMR (1987) Plenum, New York

    Google Scholar 

  40. Herzfeld J, Berger AE (1980) J. Chem. Phys. 73: 6021

    CAS  Google Scholar 

  41. Robert JB, Wiesenfeld L (1982) Physics Report 86: 365

    Google Scholar 

  42. Grimmer A-R, unpublished results

    Google Scholar 

  43. Samoson A, Sun BQ (1992) Pines A in: Pulsed Magnetic Resonance: NMR, ESR, and Optics, p 80, Bagguley DMS, Ed, Clarendon, Oxford

    Google Scholar 

  44. Grimmer A-R, Lunk HJ, in preparation

    Google Scholar 

  45. Blümich B, Hagemeyer A, Schaefer D, Schmidt-Rohr K, Spiess HW (1990) Adv. Mat. 2: 72

    Google Scholar 

  46. Grimmer A-R (1978) Z. Chem. 18: 109

    CAS  Google Scholar 

  47. Power WP, Wasylishen RE (1991) Ann. Repts. NMR 23: 1

    CAS  Google Scholar 

  48. Heidemann D (1987) Ph.D. Thesis, Berlin

    Google Scholar 

  49. Andrew ER, Bersohn R (1950) J. Chem. Phys. 18: 159

    CAS  Google Scholar 

  50. Richards RE, Smith JAS (1952) Trans. Faraday 48: 675

    CAS  Google Scholar 

  51. Doremieux-Morin C (1976) J. Magn. Res. 21: 419

    CAS  Google Scholar 

  52. Doremieux-Morin C (1979) J. Magn. Res. 33: 505

    CAS  Google Scholar 

  53. Zeer EP, Zobov VE, Falaleev OV (1991) Novyi effekty v JaMR polikristallov, Navosibirsk

    Google Scholar 

  54. Grimmer A-R, Massiot D, unpublished results

    Google Scholar 

  55. Barfuss H (1984) XXII. Congress AMPERE, Zuerich 1984, abstracts 285

    Google Scholar 

  56. Müller D, unpublished results

    Google Scholar 

  57. Schadt RJ, Dong RY, Günther RY, Blümich B (1992) J. Magn. Reson. 96: 393

    Google Scholar 

  58. Llor A, Virlet J (1988) Chem Phys. Lett 152: 248

    CAS  Google Scholar 

  59. Wu Y, Sun BQ, Pines A, Samoson A, Lippmaa E (1990) J. Magn. Reson. 89: 297

    Google Scholar 

  60. Mueller KT, Sun BQ, Chingas GC, Zwanziger JW, Terao T, Pines A (1990) J. Magn. Reson. 86: 470

    CAS  Google Scholar 

  61. Stickney de Bourgas F, Waugh JS (1992) J. Magn. Res. 96: 280

    Google Scholar 

  62. Griffin RG, Aue WP, Haberkorn RA, Harbison GS, Herzfeld J, Menger EM, Munowitz MG, Olejniczak ET, Raleigh DP, Roberts JE, Ruben DJ, Schmidt A, Smith SO (1988) S. Vega in: Physics of NMR spectroscopy in biology and medicine, Proc. Int. School of Physics Enrico Fermi, Course C, Maraviglia B ( Ed ), North-Holland p 203

    Google Scholar 

  63. Hagemeyer A, Schmidt-Rohr K, Spiess HW (1989) Adv. Magn. Reson. 13: 85

    Google Scholar 

  64. Günther E, Blümich B, Spiess HW (1991) Chem. Phys. Lett. 154: 251

    Google Scholar 

  65. Abragam A, Goldman M (1982) Nuclear magnetism: Order and disorder, Clarendon, Oxford

    Google Scholar 

  66. Dixon WT (1982) J. Chem. Phys. 77: 1800; Titman JJ, Féaux de Lacroix S, Spiess HW (1993) J. Chem. Phys. 98: 3816

    Google Scholar 

  67. Caravatti P, Braunschweiler L, Ernst RR (1983) Chem. Phys. Lett. 100: 305; Caravatti P, Bodenhausen G, Ernst RR (1982) Chem. Phys. Lett. 89: 363

    Google Scholar 

  68. Schmidt-Rohr K, Clauss J, Blümich B, Spiess HW (1990) Magn. Reson. Chem 28: 3

    Google Scholar 

  69. Schmidt-Rohr K (1989) Hochauflösende NMR an Festkörpern und Untersuchung der Phasenstruktur fester Polymere, Diplomarbeit, Johannes-Gutenberg-Universität, Mainz

    Google Scholar 

  70. Chingas GC, Miller JB, Garroway AN (1986) J. Magn. Reson. 66: 530

    CAS  Google Scholar 

  71. Cory DG, Miller JB, Turner R, Garroway AN (1990) Molec. Phys. 70: 331

    CAS  Google Scholar 

  72. Mansfield P, Grannell PK (1973) J. Phys. C 6: L422

    CAS  Google Scholar 

  73. Mansfield P, Grannell PK (1975) Phys. Rev. B12: 3618

    CAS  Google Scholar 

  74. Cory DG (1990) Polymer Preprints 31: 149

    Google Scholar 

  75. Rhim WK, Ellman DD, Vaughan RW (1973) J. Chem. Phys. 58: 1772

    Google Scholar 

  76. Cory DG, Miller JB, Garroway AN (1991) J. Magn. Reson. 90: 205

    Google Scholar 

  77. Burum DP, Rhim WK (1979) J. Chem. Phys. 71: 944

    CAS  Google Scholar 

  78. Mansfield P (1971) J. Phys. C 4: 1444

    Google Scholar 

  79. Prigl R (1990): Hochauflösende Kernresonanz in Festkörpern: Prinzipielle und Praktische Grenzen der Multipuls-Technik, Diplomarbeit, Max-Planck-Institut für Medizinische Fors¬chung, Heidelberg

    Google Scholar 

  80. Hartmann SR, Hahn EL (1962) Phys. Rev. 128: 2042

    Google Scholar 

  81. Burum DP (1990) Concepts Magn. Reson. 2: 213

    Google Scholar 

  82. Scheler G, Haubenreißer U, Rosenberger H (1981) J. Magn. Reson. 44: 134

    CAS  Google Scholar 

  83. Bronnimann CE, Hawkins BL, Zhang M, Maciel GE (1988) Anal. Chem. 60: 1743

    Google Scholar 

  84. Gerstein BC, Chou C, Pembleton RG, Wilson RC (1977) J. Phys. Chem. 81: 565

    CAS  Google Scholar 

  85. Harbison GS, Vogt V-D, Spiess HW (1987) J. Chem. Phys. 86: 1206

    Google Scholar 

  86. Grimmer A-R, Rosenberger H (1978) Z. Chem. 18: 378

    CAS  Google Scholar 

  87. Ratcliffe CI, Ripmeester JA, Tse JS (1985) Chem. Phys. Lett. 120: 427

    CAS  Google Scholar 

  88. Jelinski LW (1985) Adv. Mater. Science 15: 359

    CAS  Google Scholar 

  89. Müller K, Wassmer K-H, Kothe G (1990) Adv. Polym. Science 95: 1

    Google Scholar 

  90. Müller K, Meier P, Kothe G (1985) Progr. NMR Spectrosc. 17: 211

    Google Scholar 

  91. Spiess HW (1985) Adv. Polym. Science 66: 23

    CAS  Google Scholar 

  92. Spiess HW (1982) in: Developments in Oriented Polymers — 1, Ward IM (Ed.), Applied Science Publ., Barking

    Google Scholar 

  93. Grimmer A-R, Müller D, Neels J (1983) Z. Chem. 23: 140

    CAS  Google Scholar 

  94. Blümich B, Spiess HW (1988) Angew. Chem. Int. Ed. Engl. 27: 1655

    Google Scholar 

  95. Voelkel R (1988) Angew. Chem. Int. Ed. Eng. 27: 1468

    Google Scholar 

  96. Stejskal EO, Schaefer J, McKay RA (1977) J. Magn. Reson. 25: 569

    CAS  Google Scholar 

  97. Hentschel R, Schiitter J, Sillescu H, Spiess HW (1978) J. Chem. Phys. 68: 56

    CAS  Google Scholar 

  98. Ward IM (1975) Structure and properties of oriented polymers. Applied Science, London

    Google Scholar 

  99. Wefing S, Spiess HW (1988) J. Chem. Phys. 89: 1219

    Google Scholar 

  100. Wiesner U, Schmidt-Rohr K, Boeffel C, Pawelzik U, Spiess HW (1990) Adv. Materials 2: 484

    CAS  Google Scholar 

  101. Tang P, Santos RA, Harbison GS (1989) Adv. Magn. Reson. 13: 225

    Google Scholar 

  102. Callaghan PT (1984) Aust. J. Phys. 37: 359

    CAS  Google Scholar 

  103. Kärger J, Pfeifer H, Heink W (1988) Adv. Magn. Reson. 12: 1

    Google Scholar 

  104. Stilbs P (1987) Progr. NMR Spectroscopy 19: 1

    CAS  Google Scholar 

  105. Spiess HW (1980) J. Chem. Phys. 72: 6755

    CAS  Google Scholar 

  106. Schmidt C, Blümich B, Spiess HW (1988) J. Magn. Reson. 79: 269

    CAS  Google Scholar 

  107. Schaefer D, Spiess HW, Suter UW, Fleming WW (1990) Macromolecules 23: 3431

    CAS  Google Scholar 

  108. Blümich B, Hagemeyer A (1989) Chem. Phys. Lett. 161: 55

    Google Scholar 

  109. Anderson PW, Weiss PR (1954) J. Phys. Soc. Japan 9: 316

    Google Scholar 

  110. Blümich B, Kuhn W (1992) (eds.): Magnetic Resonance Microscopy. Verlag Chemie, Weinheim

    Google Scholar 

  111. Ackerman JL, Ellingson WA (1990) (eds.): Advanced Tomographic Imaging Methods for the Analysis of Materials. Materials Research Society, Symposium Proceedings Vol 217

    Google Scholar 

  112. Krestel E (1990): Imaging systems for medical diagnosis, Siemens AG, Berlin

    Google Scholar 

  113. Mansfield P, Morris PG (1982): NMR imaging in biomedicine. Adv. Magn. Reson. Suppl. 2, Academic, New York

    Google Scholar 

  114. Morris PG (1986): Nuclear magnetic resonance imaging in medicine and biology, Clarendon, Oxford

    Google Scholar 

  115. Wehrli FW, Schaw D, Kneeland JB (1988) ed., Biomedical Magnetic Resoanace Imaging. VCH Publishers, Weinheim

    Google Scholar 

  116. Hausser KH, Kalbitzer HR (1988) NMR in Medicine and Biology. Springer, Berlin, Heildeberg, New York

    Google Scholar 

  117. Damadian R (1971) Science 171: 1151

    CAS  Google Scholar 

  118. Damadian R (1981) ed., NMR-Basic Principles and Progress 19: NMR in Medicine, Springer, Berlin

    Google Scholar 

  119. Blümler P and Blümich B (1992) Mag. Reson. Imaging 10: 779

    Google Scholar 

  120. Samoilenko AA, Artemov DYu and Sibeldina LA (1988) JETP Lett 47: 348

    Google Scholar 

  121. Samoilenko AA, Zick K (1990) Bruker Report 1: 40

    Google Scholar 

  122. Carr HY, Purcell EM (1954) Phys. Rev. 94: 630

    CAS  Google Scholar 

  123. Meiboom S, Gill D (1958) Rev. Sci. Instrum. 29: 688

    CAS  Google Scholar 

  124. Blümich B, Blümler P, Jansen J (1992) Solid State Nuc. Magn. Reson. 1: 111

    Google Scholar 

  125. Strange JH (1990) Phil. Trans. R. Soc. Lond. A 333: 427

    Google Scholar 

  126. Cory DG, de Boer JC, Veeman WS (1989) Macromolecules, 22: 1618

    CAS  Google Scholar 

  127. Veeman WS, Cory DG (1989) Adv. Magn. Reson. 13: 43

    Google Scholar 

  128. Schauss G, Blümich B, Spiess HW (1991) J. Magn. Reson. 95: 437

    Google Scholar 

  129. Cory DG (1992) Solid State NMR Imaging. Annual reports of NMR 24: 87

    CAS  Google Scholar 

  130. Miller JB, Cory DG, Garroway AN (1989) Chem. Phys. Lett. 164: 1

    Google Scholar 

  131. Miller JB, Garroway AN (1989) J. Magn. Reson. 82: 529

    CAS  Google Scholar 

  132. McDonald PJ, Lonergan AR (1992) Physica B 176: 173

    CAS  Google Scholar 

  133. Cottrell SP, Halse MR, Strange JH (1990) Meas. Sci. Technol. 1: 624

    CAS  Google Scholar 

  134. McDonald PJ, Tokarcuk PF (1989) J. Phys. E: Sci. Instrum. 22: 948

    Google Scholar 

  135. de Luca F, de Simone BC, Lugeri N, Maraviglia B, Nuticelli C (1990) J. Magn. Reson. 90: 124

    Google Scholar 

  136. de Luca F, de Simone BC, Lugeri N, Maraviglia B (1992) Solid State Commun. 82: 151

    Google Scholar 

  137. Matsui S (1991) Chem. Phys. Lett. 179: 187

    CAS  Google Scholar 

  138. Takegoshi K, McDowell CA (1985) Chem. Phys. Lett. 116: 100

    CAS  Google Scholar 

  139. Hafner S, Demco DE, Kimmich R (1991) Meas. Sci. Technol. 2: 882

    CAS  Google Scholar 

  140. Weigand F, Blümler B, Blümich B, Spiess HW, to be published

    Google Scholar 

  141. Rommel E, Hafner S, Kimmich R (1990) J. Magn. Reson. 86: 264

    Google Scholar 

  142. Blümich B, Blümler P, Günther E, Schauss G, Spiess HW (1991) Makromol. Chem. Macromol. Symp. 44: 37

    Google Scholar 

  143. Blümich B, Blümler P, Günther E, Schauß G (1990) Bruker Report 2: 22

    Google Scholar 

  144. Demco DE, Hafner S, Kimmich R (1991) J. Magn. Reson. 94: 333

    CAS  Google Scholar 

  145. Kuhn W (1990) Angew. Chem. Int. Ed. Engl. 29: 1

    Google Scholar 

  146. Eccles CD, Callaghan PT (1986) J. Magn. Reson. 68: 393

    CAS  Google Scholar 

  147. Kumar A, Welti D, Ernst RR (1975) J. Magn. Reson. 18: 69

    CAS  Google Scholar 

  148. Chingas GC, Frydman L, Barrall, GA, Harwood JS in BLÜ1, p 374

    Google Scholar 

  149. Fleischer D, Fujara F (1993) NMR 30: xxx

    Google Scholar 

  150. Blümich B, Hagemeyer A, Schmidt-Rohr K, Spiess HW (1989) Ber. Bunsenges. Phys. Chem. 93: 1189

    Google Scholar 

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Authors and Affiliations

  1. Projektgruppe Festkörper-NMR in KAI e.V., Rudower Chaussee 5, Haus 4.1, D-12489, Berlin-Adlershof, Germany

    Arnd-Rüdiger Grimmer

  2. Lehrstuhl für Makromolekulare Chemie, RWTH Aachen, Worringerweg 1, D-52074, Aachen, Germany

    Bernhard Blümich

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  1. Arnd-Rüdiger Grimmer
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Editors and Affiliations

  1. Lehrstuhl für Makromolekulare Chemie, RTWH Aachen, Worringer Weg 1, D-52056, Aachen, Germany

    Bernhard Blümich

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Grimmer, AR., Blümich, B. (1994). Introduction to Solid-State NMR. In: Blümich, B. (eds) Solid-State NMR I Methods. NMR, vol 30. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78483-5_1

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