Abstract
The application of laser photoacoustic spectroscopy to air pollution monitoring is reviewed and compared to other spectroscopic and nonspectroscopic techniques. Emphasis is put on sensitivity, selectivity and on temporal resolution of the detection scheme. The problem of interfering absorptions by different trace gases present in multi-component mixtures is studied in detail and a new mathematical procedure for the analysis of measured photoacoustic (PA) spectra is presented. The versatility of the PA method is demonstrated by our studies performed with computer-controlled PA systems on ambient air as well as on motor-vehicle and industrial exhausts.
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References
A.P. Altshuller: Atmos. Environ. 17, 2131 (1983)
J.O. Reuss, D.W. Johnson: Acid Deposition and the Acidification of Soils and Waters, Ecological Studies, Vol. 59 ( Springer, Berlin, Heidelberg 1986 )
Rat von Sachverständigen für Umweltfragen (ed.): Waldschäden und Luftverunreinigungen, Sondergutachten ( Kohlhammer Verlag, Stuttgart 1983 )
B. Stimm: Waldsterben ( Ecomed, München 1984 )
A. Weliburn: Air Pollution and Acid Rain ( Longman, Harlow, UK 1988 )
P. Fabian: Atmosphäre und Umwelt, 2.Aufl. (Springer, Berlin, Heidelberg 1987 )
OECD, Organization for Economic Co-operation and Development (ed.): Photochemical Smog (OECD, Paris 1982 )
A.C. Stern (ed.): Air Pollution, Vol. 3, 3rd ed. ( Academic, New York 1976 )
W. Strauss (ed.): Air Pollution Control, Part III ( Wiley, New York 1978 )
W. Thain: Monitoring Toxic Gases in the Atmosphere for Hygiene and Pollution Control ( Pergamon, Oxford 1980 )
L.H. Keith (ed.): Identification and Analysis of Organic Pollutants in Air (Butterworth,Boston 1984)
R.W. Frei, J. Albaiges (eds.): Air and Water Analysis, Curr. Topics in Environ. And Toxicol. Chem., Vol. 9 ( Gordon and Breach, New York 1986 )
R.M. Harrison, R. Perry (eds.): Handbook of Air Pollution Analysis, 2nd ed. ( Chapman and Hall, London 1986 )
D.L. Fox: Air pollution. Anal. Chem. 59, 280R (1987)
G.M. Message: Practical Aspects of Gas Chromatography I Mass Spectrometry ( Wiley, New York 1984 )
W. Jennings: Analytical Gas Chromatography ( Academic, Orlando 1987 )
W. Roedel, G. Woelm: A Guide to Gas Chromatography (Huethig, Heidelberg 1987 )
J. Willet: Gas Chromatography ( Wiley, Chichester, UK 1987 )
F.W. Karasek, R.E. Clement: Basic Gas Chromatography - Mass Spectrometry (Elsevier,Amsterdam 1988 )
F.X. Kneizys, E.P. Shettle, W.D. Gallery, J.H. Chetwynd Jr., L.W. Abreu, J.E.A. Selby, S.A. Clough, R.W. Fenn: Atmospheric Transmittance/Radiance; Computer Code LOWTRAN-6, Environ. Res. Paper No. 846, AFGL-TR-83–0187 (1983)
G. Finger, F.K. Kneubühl: “Spectral Thermal Infrared Emission of the Terrestrial Atmosphere” in Infrared and Millimeter Waves, ed. by K.J. Button, Vol. 12, Part II ( Academic, New York 1984 ) pp. 145–193
E.D. Hinkley (ed.): Laser Monitoring of the Atmosphere, Topics Appl. Phys., Vol. 14 ( Springer, Berlin, Heidelberg 1976 )
C.K.N. Patel: Science 202, 157 (1978)
I. Turn, DN. Waters: Int. J. Environ. Stud. 21, 165 (1983)
W.B. Grant, R.T. Menzies: J. Air Pollut. Control Assoc. 33, 187 (1983)
H. Edner, A. Sunesson, S. Svanberg, L. Unéus, S. Wallin: Appl. Opt. 25, 403 (1986)
R. Grisar, H. Preier, G. Schmidtke, G. Restelli (eds.): Monitoring of Gaseous Pollutants by Tunable Diode Lasers (D. Reidel, Dordrecht 1987 )
F. Cappellani, G. Melandrone, G. Restelli: Environ. Monit. Assessment 5, 271 (1985)
D.K. Killinger, A. Mooradian: Optical and Laser Remote Sensing, Springer Ser. Opt. Sci.,Vol. 39 ( Springer, Berlin, Heidelberg 1983 )
A.I. Carswell: Can. J. Phys. 61, 378 (1983)
R.M. Measures: Laser Remote Sensing, Fundamentals and Applications ( Wiley, New York 1984 )
R.N. Dubinsky: Lasers Optron. 7, 93 (April 1988)
T.F. Hunter, P.C. Turtle: “Optoacoustic and Thermo-Opto Detection in Spectroscopy and in the Study of Relaxation Processes” in Advances in Infrared and Raman Spectroscopy, Vol. 7, ed. by R.J.H. Clark, R.E. Hester ( Heyden, London 1980 ) pp. 283–352
A.C. Tam: “Photoacoustics: Spectroscopy and other Applications”, in Ultrasensitive Laser Spectroscopy, ed. by D.S. Kliger (Academic, New York 1983 ) Chap. 1
P. Hess: Top. Curr. Chem. 111, 1 (1983)
P.L. Meyer: “Air Pollution Monitoring with a Mobile CO2-Laser Photoacoustic System”; PhD Thesis, ETH Zurich (1988), to be published
A.D. Wood, M. Camac, E.T. Gerry: Appl. Opt. 10, 1877 (1971)
L.B. Kreuzer: “The Physics of Signal Generation and Detection” in Optoacoustic Spectroscopy and Detection, ed. by Y.-H. Pao (Academic, New York 1977 ) Chap. 1
M.W. Sigrist, S. Bemegger, P.L. Meyer: Infrared Phys. 29, No. 2 / 3 (1989), in press
G.A. West, J.J. Barrett, D.R. Siebert, K.V. Reddy: Rev. Sci. Instrum. 54, 797 (1983)
M.W. Sigrist: J. Appl. Phys. 60, R83 (1986)
V.P. Zharov, V.S. Letokhov: Laser Optoacoustic Spectroscopy, Springer Ser. Opt. Sci., Vol. 37 ( Springer, Berlin, Heidelberg 1986 )
L.B. Kreuzer, C.K.N. Patel: Science 173, 45 (1971)
M.J. Kavaya, J.S. Margolis, M.S. Shumate: Appl. Opt. 18, 2602 (1979)
L.G. Rosengren: Appl. Opt. 14, 1960 (1975)
C.F. Dewey: “Design of Optoacoustic Systems” in Optoacoustic Spectroscopy and Detection, ed. by Y.-H. Pao (Academic, New York 1977 ) Chap. 3
K.P. Koch, W. Lahmann: Appl. Phys. Lett. 32, 289 (1978)
K.H. Fung, H.-B. Lin: Appl. Opt. 25, 749 (1986)
P.M. Morse, K.U. Ingard: Theoretical Acoustics (McGraw-Hill, New York 1968) pp. 270–300, 322–325, 467–492
S. Bernegger, M.W. Sigrist: Appl. Phys. B 44, 125 (1987)
A.C. Tam: Rev. Mod. Phys. 58, 381 (1986)
C.K.N. Patel, R.J. Kerl: Appl. Phys. Lett. 30, 578 (1977)
D.H. Leslie, G.L. Trusty, A. Dandrige, T.G. Giallorenzi: Electron. Lett. 17, 581 (1981)
E.L. Kerr, J.G. Atwood: Appl. Opt. 7, 915 (1968)
L.B. Kreuzer: J. Appl. Phys. 42, 2934 (1971)
G.A. West, D.R. Siebert, J.J. Barren: J. Appl. Phys. 51, 2823 (1980)
E.E. Marinero, M. Stuke: Opt. Commun. 30, 349 (1979)
A. Di Lieto, P. Minguzzi, M. Tonelli: Appl. Phys. B 27, 1 (1982)
A. Di Lieto, P. Minguzzi, M. Tonelli: Opt. Commun. 31, 25 (1979)
C.M. Klimcak, J.A. Gelbwachs: Appl. Opt. 24, 247 (1985)
S.L. Nickolaisen, S.E. Bialkowski: J. Chromatogr. 366, 127 (1986)
V.P. Zharov: “Laser Opto-acoustic Spectroscopy in Chromatography”, in Laser Analytical Spectrochemistry, ed. by V.S. Letokhov (Adam Hilger, Bristol 1985 ) Chap. 5
D. Fournier, A.C. Boccara, N.M. Amer, R. Gerlach: Appl. Phys. Lett. 37, 519 (1972)
L.B. Kreuzer, N.P. Kenyan, C.K.N. Patel: Science 177, 349 (1972)
C.F. Dewey, Jr., R.D. Kamm, C. E. Hackett: Appl. Phys. Lett. 23, 633 (1973)
P.D. Goldan, K. Goto: J. Appl. Phys. 45, 2058 (1975)
E. Max, L.-G. Rosengren: Opt. Commun. 11, 4350 (1974)
A.S. Gomenyuk, V.P. Zharov, D.D. Ogurok et al.: Kvantovaya Elektron. 1, 1805 (1974)
A.M. Angus, E.E. Marinern, M.J. Colles: Opt. Commun. 14, 223 (1975)
T.F. Deaton, D.A. Depatie, T.W. Walker: Appl. Phys. Lett. 26, 300 (1975)
W. Schnell, G. Fischer: Appl. Opt. 14, 2058 (1975)
P.C. Claspy, Y.-H. Pao, S. Kwong, E. Nodov: Appl. Opt. 15, 1506 (1976)
P.C. Claspy, C. Ha, Y.-H. Pao: Appl. Opt. 16, 2972 (1977)
S. Shtrikman, M. Slatkine: Appl. Phys. Lett. 31, 830 (1977)
R. Gerlach, N.M. Amer: Appl. Phys. Lett. 32, 228 (1978)
E. Kritshman, S. Shtrikman, M. Slatkine: J. Opt. Soc. Am. 68, 1257 (1978)
R.A. Grane: Appl. Opt. 17, 2097 (1978)
E. Nodov: Appl. Opt. 17, 1110 (1978)
N. Ioli, P. Violino, M. Meucci: J. Phys. E 12, 168 (1979)
R.F. Adamowicz, K.P. Koo: Appl. Opt. 18, 2938 (1979)
G.L. Loper, A.R. Calloway, M.A. Stamps, J.A. Gelbwachs: Appl. Opt. 19, 2726 (1980)
T.H. Vansteenkiste, F.R. Faxvog, D.M. Roessler: Appl. Spectrosc. 35, 194 (1981)
C. Chen, Y. Liu, C. Ming, C. Wang, W. Wang, J. Xu, Z. Li, L. Wang: Chin. Phys. 2, 451 (1982)
W. Wang, C. Chen, Y. Liu: Kexue Tongbao 27, 400 (1982)
M.H. Hubert: Laser Optoacoustic Detector, Report No. 83–715–1 (Natl. Res. Council, Canada 1983 )
M.A. Leugers, G.H. Atkinson: Anal. Chem. 56, 925 (1984)
G.L. Loper, J.A. Gelbwachs, S.M. Beck: Can. J. Phys. 64, 1124 (1986)
P. Vujkovic Cvijin, D.A. Gilmore, M.A. Leugers, G.H. Atkinson: Anal. Chem. 59, 300 (1987)
Z. Zelinger, Z. Papouskova, M. Jakoubkova, P. Engst: Collect. Czech. Chem. Commun. 53, 749 (1988)
M. Boutonnat, K.A. Keilbach, D.A. Gilmore, N. Oliphant, P. Vujkovic Cvijin, G.H. Atkinson: In Photoacoustic and Photothermal Phenomena, ed. by P. Hess, J. Pelz, Springer Ser. Opt. Sci., Vol. 58 ( Springer, Berlin, Heidelberg 1988 ) pp. 137–138
C.K.N. Patel, E.G. Burkhardt, C.A. Lambert: Science 184, 1173 (1974)
E.G. Burkhardt, C.A. Lambert, C.K.N. Patel: Science 188, 1111 (1975)
C.K.N. Patel: Opt. Quantum Electron. 8, 145 (1976)
P. Perlmutter, S. Shtrikman, M. Slatkine: Appl. Opt. 18, 2267 (1979)
S. Bernegger, P.L. Meyer, C. Widmer, M.W. Sigrist: In Photoacoustic and Photothermal Phenomena, ed. by P. Hess, J. Pelz!, Springer Ser. Opt. Sci., Vol. 58 ( Springer, Berlin, Heidelberg 1988 ) pp. 122–126
P.L. Meyer, S. Bernegger, M.W. Sigrist: In Photoacoustic and Photothermal Phenomena, ed. by P. Hess, J. Pelzl, Springer Ser. Opt. Sci., Vol. 58 ( Springer, Berlin, Heidelberg 1988 ) pp. 127–130
D.D. Bicanic, B.F.J. Zuidberg, R. Friedhoff, F. Harren, D.P. v.d. Akker, A. Bizzarri: In Photoacoustic and Photothermal Phenomena, ed. by P. Hess, J. Pelzl, Springer Ser. Opt. Sci., Vol. 58 (Springer, Berlin, Heidelberg 1988 ) pp. 145–147
F. Harren, J. Reuss, D.D. Bicanic, E. Woltering: In Photoacoustic and Photothermal Phenomena, ed. by P. Hess, J. Pelzl, Springer Ser. Opt. Sci., Vol. 58 ( Springer, Berlin, Heidelberg 1988 ) pp. 148–149
L.S. Rothman, A. Goldman, J.R. Gillis, R.R. Gamache, H.M. Pickett, R.L. Poynter, N.Husson, A. Chedin: Appl. Opt. 22, 1616 (1983)
L.S. Rothman, R.R. Gamache, A. Barbe, A. Goldman, J.R. Gillis, L.R. Brown, R.A. Toth, J.-M. Flaud, C. Camry-Peyret: Appl. Opt. 22, 2247 (1983)
L.S. Rothman, R.R. Gamache, A. Goldman, L.R. Brown, R.A. Toth, H.M. Picket, R.L. Poynter, J.-M. Flaud, C. Camry-Peyret, A. Barbe, N. Husson, C.P. Rinsland, M.A.H. Smith: Appl. Opt. 26, 4058 (1987)
J. Hinderling, M.W. Sigrist, F.K. Kneubühl: Infrared Phys. 27, 63 (1987)
H. Mehlhorn, A.R. Wellbum: Nature 327, 417 (1987)
R. Gerlach, N.M. Amer: Appl. Phys. 23, 319 (1980)
U. Persson, B. Marthinsson, J. Johansson, S.T. Eng: Appl. Opt. 19, 1711 (1980)
S.M. Beck: Appl. Opt. 24, 1761 (1985)
G. Bergmann, B. von Oepen, P. Zinn: Anal. Chem. 59, 2522 (1987)
I.M. Campbell: Energy and the Atmosphere ( Wiley, London 1977 )
F.B. Abeles, H.E. Heggestad: J. Air Pollut. Control Assoc. 23, 517 (1973)
F. Herlemont, M. Lyszyk, J. Lemaire: J. Mol. Spectrosc. 74, 400 (1979)
M.W. Sigrist: In Photoacoustic and Photothermal Phenomena, ed. by P. Hess, J. Pelzl, Springer Ser. Opt. Sci., Vol. 58 ( Springer, Berlin, Heidelberg 1988 ).pp. 114–121
R.A. Rooth, A.J.L. Verhage, L.W. Wouters, L. van de Beld: In Proc. 4th Int. Conf. on IR Physics (CIRP 4), Zurich, ed. by R. Kesselring, F.K. Kneubühl (ETH Zurich 1988 ) pp. 590–592
V.P. Zharov, Moscow High Technical School (USSR), private communication
S. Bemegger. “CO-Laser Photoacoustic Spectroscopy of Gases and Vapors for Trace Gas Analysis”; PhD Thesis, ETH Zurich (1988), to be published
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Sigrist, M.W., Bernegger, S., Meyer, P.L. (1989). Atmospheric and Exhaust Air Monitoring by Laser Photoacoustic Spectroscopy. In: Hess, P. (eds) Photoacoustic, Photothermal and Photochemical Processes in Gases. Topics in Current Physics, vol 46. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83851-4_7
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DOI: https://doi.org/10.1007/978-3-642-83851-4_7
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