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Polyacetylenes with Substituents: Their Synthesis and Properties

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Catalytical and Radical Polymerization

Part of the book series: Advances in Polymer Science ((POLYMER,volume 81))

Abstract

This review deals with recent advances in the synthesis, characterization, and function of poly-acetylenes with substituents (substituted polyacetylenes). The main features are as follows: A number of catalysts based on group 5 and 6 transition metals (Nb, Ta, Mo, W) have been exploited which polymerize substituted acetylenes, especially sterically crowded ones. By using these catalysts, new substituted polyacetylenes [—(—CR=CR′—)n—] with molecular weight up to one million have been synthesizedfrom various monomers; e.g., HC≡C—t—Bu, MeC≡C—n—C5H11, MeC≡CPh, ClC≡CPh, and McC≡CSiMe3. Unlike polyacetylene, these substituted polyacetylenes are generally colorless (or light yellow), soluble, amorphous, air-stable, electrically insulating, and non-paramagnetic. Some of these polymers have been found to be useful as membranes for separation of gases and liquids, thus constituting a new category of speciality polymers.

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  1. Department of Polymer Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606, Japan

    Toshio Masuda & Toshinobu Higashimura

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  1. Toshio Masuda
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Masuda, T., Higashimura, T. (1986). Polyacetylenes with Substituents: Their Synthesis and Properties. In: Catalytical and Radical Polymerization. Advances in Polymer Science, vol 81. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-15187-7_3

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  • DOI: https://doi.org/10.1007/978-3-662-15187-7_3

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