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Massenspektrometrische Bestimmung der Spurenelemente in Steinmeteoriten

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Analyse extraterrestrischen Materials

Zusammenfassung

In den letzten Jahren wurde ein Verfahren zur Bestimmung aller schweren Spurenelemente von W bis U durch Festkörper-Massenspektrometrie mit Funkenionenquellen erarbeitet. Zur Bestimmung der Empfindlichkeitsfaktoren wurde der Allende-Standardmeteorit herangezogen. Die Konzentrationen der siderophilen schweren Elemente W, Re, Os, Ir, Pt und Au sind in gewöhnlichen und kohligen Chondriten untereinander streng korreliert, während Bi zu den siderophilen Elementen antikorreliert ist. Enstatitchondrite verhalten sich etwas anders.

Die massenspektrometrische Bestimmung der schweren Elemente wird zur Klassifizierung der vier Yamato-Meteorite angewendet. Dabei zeigt sich, daß jeder der vier Steine einer anderen Klasse zugeordnet werden kann, nämlich als E, Ah, C3 und H.

Abstract

In recent years a method for the determination of heavy trace elements from W to U in solids by means of sparc source mass spectrometry was developed. Sensitivity factors were determined using the Allende reference meteorite. Concentrations of siderophile elements W, Re, Os, Ir, Pt, and Au in ordinary- and carbonaceous chondrites are mutually correlated while Bi is anticorrelated to siderophile elements. Enstatite chondrites show somewhat different characteristics.

The mass spectrometric determination of heavy trace elements may be used for classification of four Yamato meteorites. Each of these four stony meteorites can be assigned to a different class, that is E, Ah, C3 and H respectively.

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W. Kiesl Hanns Malissa Jr. (Präsident der Österreichischen Gesellschaft für Mikrochemie und Analytische Chemie)

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Hintenberger, H., Jochum, K.P., Seufert, M. (1974). Massenspektrometrische Bestimmung der Spurenelemente in Steinmeteoriten. In: Kiesl, W., Malissa, H. (eds) Analyse extraterrestrischen Materials. Springer, Vienna. https://doi.org/10.1007/978-3-7091-8361-8_9

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  • DOI: https://doi.org/10.1007/978-3-7091-8361-8_9

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