Abstract
Acoustic cavitation is the formation and collapse of bubbles in liquid irradiated by intense ultrasound. The speed of the bubble collapse sometimes reaches the sound velocity in the liquid. Accordingly, the bubble collapse becomes a quasi-adiabatic process. The temperature and pressure inside a bubble increase to thousands of Kelvin and thousands of bars, respectively. As a result, water vapor and oxygen, if present, are dissociated inside a bubble and oxidants such as OH, O, and H2O2 are produced, which is called sonochemical reactions. The pulsation of active bubbles is intrinsically nonlinear. In the present review, fundamentals of acoustic cavitation, sonochemistry, and acoustic fields in sonochemical reactors have been discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Kinsler LE, Frey AR, Coppens AB, Sanders JV (1982) Fundamentals of acoustics. Wiley, New York
Cheeke JDN (2002) Fundamentals and applications of ultrasonic waves. CRC Press, Boca Raton
Maris H, Balibar S (2000) Negative pressures and cavitation in liquid helium. Phys Today 53:29–34
Yasui K, Tuziuti T, Sivakumar M, Iida Y (2004) Sonoluminescence. Appl Spectrosc Rev 39:399–436
Neppiras EA (1980) Acoustic cavitation. Phys Rep 61:159–251
Young FR (1999) Cavitation. Imperial College, London
Suslick KS, Flannigan DJ (2008) Inside a collapsing bubble: Sonoluminescence and the conditions during cavitation. Ann Rev Phys Chem 59:659–683
Pecha R, Gompf B (2000) Micoimplosions: cavitaion collapse and shock wave emission on a nanosecond time scale. Phys Rev Lett 84:1328–1330
Holzfuss J, Rüggeberg M, Billo A (1998) Shock wave emissions of a sonoluminescing bubble. Phys Rev Lett 81:5434–5437
Weninger KR, Camara CG, Putterman SJ (2001) Observation of bubble dynamics within luminescent cavitation clouds: sonoluminescence at the nano-scale. Phys Rev E 63:016310
Fujikawa S, Akamatsu T (1980) Effects of the nonequilibrium condensation of vapor on the pressure wave produced by the collapse of a bubble in a liquid. J Fluid Mech 97:481–512
Henglein A (1993) Contributions to various aspects of cavitation chemistry. In: Mason TJ (ed) Advances in Sonochemistry, vol. 3:17–83, JAI Press, London
Riesz P, Kondo T (1992) Free radical formation induced by ultrasound and its biological implications. Free Radic Biol Med 13:247–270
Leighton TG (1994) The acoustic bubble. Academic Press, London
Yasui K, Tuziuti T, Lee J, Kozuka T, Towata A, Iida Y (2010) Numerical simulations of acoustic cavitation noise with the temporal fluctuation in the number of bubbles. Ultrason Sonochem 17:460–472
Yasui K (2002) Influence of ultrasonic frequency on multibubble sonoluminescence. J Acoust Soc Am 112:1405–1413
Ashokkumar M, Lee J, Iida Y, Yasui K, Kozuka T, Tuziuti T, Towata A (2009) The detection and control of stable and transient acoustic cavitation bubbles. Phys Chem Chem Phys 11:10118–10121
Ashokkumar M, Hodnett M, Zeqiri B, Grieser F, Price G (2007) Acoustic emission spectra from 515 kHz cavitation in aqueous solutions containing surface-active solutes. J Am Chem Soc 129:2250–2258
Lee J, Ashokkumar M, Kentish S, Grieser F (2005) Determination of the size distribution of sonoluminescence bubbles in a pulsed acoustic field. J Am Chem Soc 127:16810–16811
Guan J, Matula TJ (2003) Time scales for quenching single-bubble sonoluminescence in the presence of alcohols. J Phys Chem 107:8917–8921
Madanshetty SI, Apfel RE (1991) Acoustic microcavitation: Enhancement and applications. J Acoust Soc Am 90:1508–1514
Tuziuti T, Yasui K, Sivakumar M, Iida Y, Miyoshi N (2005) Correlation between acoustic cavitation noise and yield enhancement of sonochemical reaction by particle addition. J Phys Chem A 109:4869–4872
Borkent BM, Arora M, Ohl CD, Jong ND, Versluis M, Lohse D, Morch KA, Klaseboer E, Khoo BC (2008) The acceleration of solid particles subjected to cavitation nucleation. J Fluid Mech 610:157–182
Yount DE, Gillary EW, Hoffman DC (1984) A microscopic investigation of bubble formation nuclei. J Acoust Soc Am 76:1511–1521
Bremond N, Arora M, Dammer SM, Lohse D (2006) Interaction of cavitation bubbles on a wall. Phys Fluids 18:121505 (10 pages)
Calvisi ML, Lindau O, Blake JR, Szeri AJ (2007) Shape stability and violent collapse of microbubbles in acoustic traveling waves. Phys Fluids 19:047101 (15 pages)
Wang E, Chen W, Lu M, Wei R (2003) Bubble oscillations driven by aspherical ultrasound in liquid. J Acoust Soc Am 114:1898–1904
Lee J, Tuziuti T, Yasui K, Kentish S, Grieser F, Ashokkumar M, Iida Y (2007) Influence of surface-active solutes on the coalescence, clustering, and fragmentation of acoustic bubbles confined in a microspace. J Phys Chem C 111:19015–19023
Matula TJ, Cordry SM, Roy RA, Crum LA (1997) Bjerknes force and bubble levitation under single-bubble sonoluminescence conditions. J Acoust Soc Am 102:1522–1527
Yasui K (2001) Temperature in multibubble sonoluminescence. J Chem Phys 115:2893–2896
Crum LA (1980) Measurements of the growth of air bubbles by rectified diffusion. J Acoust Soc Am 68:203–211
Lee J, Kentish S, Ashokkumar M (2005) Effect of surfactants on the rate of growth of an air bubble by rectified diffusion. J Phys Chem B 109:14595–14598
Louisnard O, Gomez F (2003) Growth by rectified diffusion of strongly acoustically forced gas bubbles in nearly saturated liquids. Phys Rev E 67:036610
Iida Y, Ashokkumar M, Tuziuti T, Kozuka T, Yasui K, Towata A, Lee J (2010) Bubble population phenomena in sonochemical reactor: II Estimation of bubble size distribution and its number density by simple coalescence model calculation. Ultrason Sonochem 17:480–486
Mettin R (2005) Bubble structures in acoustic cavitation. In Doinikov AA (ed) Bubble and particle dynamics in acoustic fields: modern trends and applications, pp. 1–36. Research Signpost, Trivandrum
Beyer RT (1997) Nonlinear acoustics. Acoustical Society of America, New York
Mitome H, Kozuka T, Tuziuti T, Wang L (1997) Quasi acoustic streaming induced by generation of cavitation bubbles. IEEE Ultrason Sympo Proc 1:533–536
Mettin R, Akhatov I, Parlitz U, Ohl CD, Lauterborn W (1997) Bjerknes forces between small cavitation bubbles in a strong acoustic field. Phys Rev E 56:2924–2931
Yasui K, Tuziuti T, Lee J, Kozuka T, Towata A, Iida Y (2008) The range of ambient radius for an active bubble in sonoluminescence and sonochemical reactions. J Chem Phys 128:184705
Brenner MP, Hilgenfeldt S, Lohse D (2002) Single-bubble sonoluminescence. Rev Mod Phys 74:425–484
Prosperetti A, Lezzi A (1986) Bubble dynamics in a compressible liquid. Part I. First-order theory. J Fluid Mech 168:457–478
Yasui K (2001) Effect of liquid temperature on sonoluminescence. Phys Rev E 64:016310
Yasui K, Tuziuti T, Sivakumar M, Iida Y (2005) Theoretical study of single-bubble sonochemistry. J Chem Phys 122:224706
Vanhille C, Campos-Pozuelo C (2008) Nonlinear ultrasonic propagation in bubbly liquids: A numerical model. Ultrasound Med Biol 34:792–808
Tuziuti T, Yasui K, Lee J, Kozuka T, Towata A, Iida Y (2009) Influence of surface active solute on ultrasonic waveform distortion in liquid containing air bubbles. J Phys Chem A 113:8893–8900
Hilgenfeldt S, Grossmann S, Lohse D (1999) A simple explanation of light emission in sonoluminescence. Nature (London) 398:402–405
Yasui K (1999) Mechanism of single-bubble sonoluminescence. Phys Rev E 60:1754–1758
An Y (2006) Mechanism of single-bubble sonoluminescence. Phys Rev E 74:026304 (14 pages)
Flannigan DJ, Suslick KS (2005) Plasma formation and temperature measurement during single-bubble cavitation. Nature (London) 434:52–55
Hatanaka S, Mitome H, Yasui K, Hayashi S (2002) Single-bubble sonochemiluminescence in aqueous luminol solutions. J Am Chem Soc 124:10250–10251
Didenko YT, Suslick KS (2002) The energy efficiency and formation of photons, radicals and ions during single-bubble cavitation. Nature (London) 418:394–397
Koda S, Tanaka K, Sakamoto H, Matsuoka T, Nomura H (2004) Sonochemical efficiency during single-bubble cavitation in water. J Phys Chem A 108:11609–11612
Yasui K, Tuziuti T, Iida Y, Mitome H (2003) Theoretical study of the ambient-pressure dependence of sonochemical reactions. J Chem Phys 119:346–356
Yasui K, Tuziuti T, Iida Y (2004) Optimum bubble temperature for the sonochemical production of oxidants. Ultrasonics 42:579–584
Brotchie A, Grieser F, Ashokkumar M (2009) Effect of power and frequency on bubble-size distributions in acoustic cavitation. Phys Rev Lett 102:084302 (4 pages)
Mason TJ (1999) Sonochemistry. Oxford University Press, Oxford
Suslick KS, Hammerton DA, Cline RE, J (1986) The sonochemical hot spot. J Am Chem Soc 108:5641–5642
Yasui K (1996) Variation of liquid temperature at bubble wall near the sonoluminescence threshold. J Phys Soc Jpn 65:2830–2840
Storey BD, Szeri AJ (2000) Water vapour, sonoluminescence and sonochemistry. Proc R Soc Lond A 456:1685–1709
Hua I, Hochemer RH, Hoffmann MR (1995) Sonolytic hydrolysis of p-nitrophenyl acetate: The role of supercritical water. J Phys Chem 99:2335–2342
Sostaric JZ (1999) Interfacial effects on aqueous sonochemistry and sonoluminescence. PhD thesis, University of Melbourne, Australia
Yasui K (2002) Effect of volatile solutes on sonoluminescence. J Chem Phys 116:2945–2954
Yasui K, Tuziuti T, Kozuka T, Towata A, Iida Y (2007) Relationship between the bubble temperature and main oxidant created inside an air bubble under ultrasound. J Chem Phys 127:154502
Parlitz U, Mettin R, Luther S, Akhatov I, Voss M, Lauterborn W (1999) Spatio-temporal dynamics of acoustic cavitation bubble cloud. Philos Trans R Soc London A 357:313–334
Oolman TO, Blanch HW (1986) Bubble coalescence in stagnant liquids. Chem Engnrg Commun 43:237–261
Iida Y, Ashokkumar M, Tuziuti T, Kozuka T, Yasui K, Towata A, Lee J (2010) Bubble population phenomena in sonochemical reactor: I Estimation of bubble size distribution and its number density with pulsed sonocation – laser diffraction method. Ultrason Sonochem 17:473–479
Lee J, Yasui K, Tuziuti T, Kozuka T, Towata A, Iida Y (2008) Spatial distribution enhancement of sonoluminescence activity by altering sonication and solution conditions. J Phys Chem B 112:15333–15341
Ashokkumar M, Hall R, Mulvaney P, Grieser F (1997) Sonoluminescence from aqueous alcohol and surfactant solutions. J Phys Chem B 101:10845–10850
Segebarth N, Eulaerts O, Reisse J, Crum LA, Matula TJ (2002) Correlation between acoustic cavitation noise, bubble population, and sonochemistry. J Phys Chem B 106:9181–9190
Tuziuti T, Yasui K, Iida Y, Sivakumar M, Koda S (2004) Laser-light scattering from a multibubble system for sonochemistry. J Phys Chem A 108:9011–9013
Tuziuti T, Yasui K, Lee J, Kozuka T, Towata A, Iida Y (2008) Mechanism of enhancement of sonochemical-reaction efficiency by pulsed ultrasound. J Phys Chem A 112:4875–4878
Chow R, Blindt R, Chivers R, Povey M (2005) A study on the primary and secondary nucleation of ice by power ultrasound. Ultrasonics 43:227–230
Luque de Castro MD, Priego-Capote F (2007) Ultrasound-assisted crystallization (sonocrystallization). Ultrason Sonochem 14:717–724
Kordylla A, Krawczyk T, Tumakaka F, Schembecker G (2009) Modeling ultrasound-induced nucleation during cooling crystallization. Chem Engnrg Sci 64:1635–1642
Saclier M, Peczalski R, Andrieu J (2010) A theoretical model for ice primary nucleation induced by acoustic cavitation. Ultrason Sonochem 17:98–105
Xu M, Lu Y, Liu Y, Shi S, Qian T, Lu D (2006) Sonochemical synthesis of monosized spherical BaTiO3 particles. Powder Technol 161:185–189
Testinon A, Buscaglia MT, Viviani M, Buscaglia V, Nanni P (2004) Synthesis of BaTiO3 particles with tailored size by precipitation from aqueous solutions. J Am Ceram Soc 87:79–83
Elder SA (1959) Cavitation microstreaming. J Acoust Soc Am 31:54–64
Walton DJ, Phull SS (1996) Sonoelectrochemistry. In: Mason TJ (ed) Advances in Sonochemistry, vol. 4:205–284, JAI Press, Greenwich
Hacias KJ, Cormier GJ, Nourie SM, Kubel EJ (1997) Guide to acid, alkaline, emulsion, and ultrasonic cleaning. ASM International, Materials Park
Lamminen MO, Walker HW, Weavers LK (2006) Cleaning of particle-fouled membranes during cross-flow filtration using an embedded ultrasonic transducer system. J Membrane Sci 283:225–232
Ohl CD, Arora M, Dijkink R, Janve V, Lohse D (2006) Surface cleaning from laser-induced cavitation bubbles. Appl Phys Lett 89:074102 (3 pages)
Kim W, Kim TH, Choi J, Kim HY (2009) Mechanism of particle removal by megasonic waves. Appl Phys Lett 94:081908 (3 pages)
Bakhtari K, Guldiken RO, Busnaina AA, Park JG (2006) Experimental and analytical study of semicrometer particle removal from deep trenches. J Electrochem Soc 153:C603–C607
Bakhtari K, Guldiken RO, Makaram P, Busnaina AA, Park JG (2006) Experimental and numerical investigation of nanoparticle removal using acoustic streaming and the effect of time. J Electrochem Soc 153:G846–G850
Yasui K, Kozuka T, Tuziuti T, Towata A, Iida Y, King J, Macey P (2007) FEM calculation of an acoustic field in a sonochemical reactor. Ultrason Sonochem 14:605–614
Dahnke S, Keil F (1998) Modeling of sound fields in liquids with a nonhomogeneous distribution of cavitation bubbles as a basis for the design of sonochemical reactors. Chem Eng Technol 21:873–877
Wilson PS, Roy RA, Carey WM (2005) Phase speed and attenuation in bubbly liquids inferred from impedance measurements near the individual bubble resonance frequency. J Acoust Soc Am 117:1895–1910
Yasui K, Iida Y, Tuziuti T, Kozuka T, Towata A (2008) Strongly interacting bubbles under an ultrasonic horn. Phys Rev E 77:016609
Yasui K, Lee J, Tuziuti T, Towata A, Kozuka T, Iida Y (2009) Influence of the bubble-bubble interaction on destruction of encapsulated microbubbles under ultrasound. J Acoust Soc Am 126:973–982
Ida M, Naoe T, Futakawa M (2007) Suppression of cavitation inception by gas bubble injection: A numerical study focusing on bubble-bubble interaction. Phys Rev E 76:046309
Gogate PR, Shirgaonkar IZ, Sivakumar M, Senthilkumar P, Vichare NP, Pandit AB (2001) Cavitation reactors: Efficiency assessment using a model reaction. AIChE J 47:2526–2538
Wang X, Zhang Y (2009) Degradation of alachlor in aqueous solution by using hydrodynamic cavitation. J Haz Mater 161:202–207
Acknowledgments
I would like to thank my coworkers T.Tuziuti, J.Lee, T.Kozuka, A.Towata, and Y.Iida for useful discussions. I would also like to thank H.Mitome for his encouragement.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2010 Springer Science+Business Media B.V.
About this chapter
Cite this chapter
Yasui, K. (2010). Fundamentals of Acoustic Cavitation and Sonochemistry. In: Ashokkumar, M. (eds) Theoretical and Experimental Sonochemistry Involving Inorganic Systems. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3887-6_1
Download citation
DOI: https://doi.org/10.1007/978-90-481-3887-6_1
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-3886-9
Online ISBN: 978-90-481-3887-6
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)