Abstract
Interest in heterogeneous photocatalysis has heightened in the past 40 years, underscoring several perspectives and advances. A collection of applications including solar to fuel cells, intelligent ink and remote photocatalysis have been closely examined. As an emerging panacea for the treatment of recalcitrant pollutants, heterogeneous photocatalytic degradation has been highlighted with specific reference to synthetic aliphatic and aromatic organic substances. What’s more, various treatment technologies for integration with photocatalytic degradation have been outlined.
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Abdullah MDP, Nainggolan H (1991) Phenolic water pollutants in a Malaysian river Basin. Env Monit Assess 19:423–431
Abe R (2010) Recent progress on photocatalytic and photoelectrochemical water splitting under visible light irradiation. J Photochem Photobiol C 11:179–209
Abramović BF, Anderluh VB, Topalov AS (2004) Kinetics of photocatalytic removal of 2-amino-5-chloropyridine from water. APTEFF 35:1–80
Ali MF, El-Ali BM, Speight JG (2005) Handbook of industrial chemistry. McGraw-Hill, United States of America
Alipázaga MV, Moreno RGM, Linares E et al (2005) Oxidative DNA damage induced by autoxidation of microquantities of S(IV) in the presence of Ni(II)-Gly-Gly-His. Dalton Trans 44:3738–3744
Amao Y, Yamada Y (2007) Photovoltaic conversion using Zn chlorophyll derivative assembled in hydrophobic domain onto nanocrystalline TiO2 electrode. Biosens Bioelectron 22:1561–1565
An T, Zhang M, Wang X et al (2005) Photocatalytic degradation of gaseous trichloroethene using immobilized ZnO/SnO2 coupled oxide in a flow-through photocatalytic reactor. J Chem Technol Biotechnol 80:251–258
An T-C, Zhu X-H, Xiong Y (2002) Feasibility study of photoelectrochemical degradation of methylene blue with three-dimensional electrode-photocatalytic reactor. Chemosphere 46:897–903
Araña J, Nieto JLM, Melián JAH et al (2004) Photocatalytic degradation of formaldehyde containing wastewater from veterinarian laboratories. Chemosphere 55:893–904
Areerachakul N, Vigneswaran S, Ngo HH et al (2007) Granular activated carbon (GAC) adsorption-photocatalysis hybrid system in the removal of herbicide from water. Sep Purif Technol 55:206–211
Augugliaro V, Coluccia S, Loddo V et al (1999) Photocatalytic oxidation of gaseous toluene on anatase TiO2 catalyst: mechanistic aspects and FT-IR investigation. Appl Catal B 20:15–27
Augugliaro V, Litter M, Palmisano L et al (2006) The combination of heterogeneous photocatalysis with chemical and physical operations: A tool for improving the photoprocess performance. J Photochem Photobiol A 7:127–144
Augugliaro V, Loddo V, Palmisano G et al (2010) Clean by light irradiation practical applications of supported TiO2. Royal Society of Chemistry, United Kingdom
Bahnemann W, Muneer M, Haque MM (2007) Titanium dioxide-mediated photocatalysed degradation of few selected organic pollutants in aqueous suspensions. Catal Today 124:133–148
Bao Z-C, Barker JR (1996) Temperature and ionic strength effects on some reactions involving sulfate radical [SO4 –(aq)]. J Phys Chem 100:9780–9787
Bao-xiu Z, Xiang-zhong L, Peng W (2007) Degradation of 2,4-dichlorophenol with a novel TiO2/Ti-Fe-graphite felt photoelectrocatalytic oxidation process. J Environ Sci 19:1020–1024
Barceló D, Hennion MC (2008) Trace determination of pesticidesand their degradation products in water, techniques and instrumentation in analytical chemistry. Elsevier, Amsterdam
Bertelli M, Selli E (2004) Kinetic analysis on the combined use of photocatalysis, H2O2 photolysis, and sonolysis in the degradation of methyl tert-butyl ether. Appl Catal B 52:205–212
Bianchi CL, Pirola C, Ragaini V (2006) Mechanism and efficiency of atrazine degradation under combined oxidation processes. Appl Catal B 64:131–138
Bissen M, Vieillard-Baron M-M, Schindelin AJ et al (2001) TiO2-catalyzed photooxidation of arsenite to arsenate in aqueous samples. Chemosphere 44:751–757
Bláha L, Klánová J Klán P et al (2004) Toxicity increases in ice containing monochlorophenols upon photolysis: environmental consequences. Environ Sci Technol 38:2873–2878
Blount MC, Falconer JL (2002) Steady-state surface species during toluene photocatalysis. Appl Catal B 39:39–50
Boulamanti AK, Philippopoulos CJ (2009) Photocatalytic degradation of C5–C7 alkanes in the gas–phase. Atmos Environ 43:3168–3174
Brillas E, Calpe JC, Casado J (2000) Mineralization of 2,4-D by advanced electrochemical oxidation processes. Water Res 34:2253–2262
Brosillon S, Djelal H, Merienne N et al (2008) Innovative integrated process for the treatment of azo dyes: coupling of photocatalysis and biological treatment. Desalination 222:331–339
Buechler KJ, Noble RD, Koval CA et al (1999) Investigation of the effects of controlled periodic illumination on the oxidation of gaseous trichloroethylene using a thin film of TiO2. Ind Eng Chem Res 38:892–896
Byrne HE, Mazyck DW (2009) Removal of trace level aqueous mercury by adsorption and photocatalysis on silica-titania composites. J Hazard Mater 170:915–919
Calza P, Massolino C, Monaco G et al (2008) Study of the photolytic and photocatalytic transformation of amiloride in water. J Pharm Biomed Anal 48:315–320
Cao S-W, Yuan Y-P, Fang J et al (2013) In-situ growth of CdS quantum dots on g-C3N4 nanosheets for highly efficient photocatalytic hydrogen generation under visible light irradiation. Int J Hydrogen Energy 38:1258–1266
Castiglioni S, Fanelli R, Pomati F et al (2006) Removal of pharmaceuticals in sewage treatment plants in Italy. Environ Sci Technol 40:357–363
Chang M-W, Chen T-S, Chern J-M (2008) Initial degradation rate of p-nitrophenol in aqueous solution by fenton reaction. Ind Eng Chem Res 47:8533–8541
Chatzitakis A, Berberidou C, Paspaltsis I et al (2008) Photocatalytic degradation and drug activity reduction of Chloramphenicol. Water Res 42:386–394
Chen Y-C, Smirniotis P (2002) Enhancement of photocatalytic degradation of phenol and chlorophenols by ultrasound. Ind Eng Chem Res 41:5958–5965
Chen LC, Huang C-M, Hsiao M-C et al (2010) Mixture design optimization of the composition of S, C, SnO2-codoped TiO2 for degradation of phenol under visible light. Chem Eng J 165:482–489
Chin P, Ollis DF (2007) Decolorization of organic dyes on Pilkington ActivTM photocatalytic glass. Catal Today 123:177–188
Chiron S, Minero C, Evione D (2007) Occurrence of 2,4-dichlorophenol and of 2,4-dichloro-6-nitrophenol in the Rhône River Delta (Southern France). Environ Sci Technol 41:3127–3133
Choi W, Ko JY, Park H et al (2001) Investigation on TiO2-coated optical fibers for gas-phase photocatalytic oxidation of acetone. Appl Catal B 31(2001):209–220
Connel DW (2005) Basic concepts of environmental chemistry. Taylor and Francis, London
Dalrymple OK, Yeh DH, Trotz MA (2007) Removing pharmaceuticals and endocrine-disrupting compounds from wastewater by photocatalysis. J Chem Technol Biotechnol 82:121–134
De Padova P, Lucci M, Olivieri B et al (2009) Natural hybrid organic-inorganic photovoltaic devices. Superlattice Microst 45:555–563
Demeestere K, Dewulf J, De WB (2008) Heterogeneous photocatalytic removal of toluene from air on building materials enriched with TiO2. Build Environ 43:406–414
Dholam R, Patel N, Adami M et al (2009) Hydrogen production by photocatalytic water-splitting using Cr- or Fe-doped TiO2 composite thin films photocatalyst. Int J Hydrogen Energy 34:5337–5346
Ding L, Zhou H, Lou S et al (2013) Butterfly wing architecture assisted CdS/Au/TiO2 Z-scheme type photocatalytic water splitting. Int J Hydrogen Energ 38:8244–8253
Dionysiou DD, Khodadoust AP, Kern AM et al (2000) Continuous-mode photocatalytic degradation of chlorinated phenols and pesticides in water using a bench-scale TiO2 rotating disk reactor. Appl Catal B 24:139–155
Djebbar K, Sehili T (1998) Kinetics of heterogeneous photocatalytic decomposition of 2,4-dichlorophenoxyacetic acid over titanium dioxide and zinc oxide in aqueous solution. Pestic Sci 54:269–276
Doong R, Chen C-H, Maithreepala RA et al (2001) The influence of pH and cadmium sulphide on the photocatalytic degradation of 2-chlorophenol in titanium dioxide suspensions. Water Res 35:2873–2880
Driessen MD, Miller TM, Grassian VH (1998) Photocatalytic oxidation of trichloroethylene on zinc oxide: characterization of surface-bound and gas-phase products and intermediates with FT-IR spectroscopy. J Mol Catal A: Chem 131:149–156
Du Y, Zhou M, Lei L (2006) Role of the intermediates in the degradation of phenolic compounds by Fenton-like process. J Hazard Mater 136:859–865
Dutta PK, Pehkonen SO, Sharma VK et al (2005) Photocatalytic oxidation of arsenic (III): evidence of hydroxyl radicals. Environ Sci Technol 39:1827–1834
Einaga H, Futamura S, Ibusuki T (2001) Complete oxidation of benzene in gas phase by platinized titania photocatalysts. Environ Sci Technol 35:1880–1884
Epling GA, Lin C (2002) Photoassisted bleaching of dyes utilizing TiO2 and visible light. Chemosphere 46:561–570
Evgenidou E, Konstantinou I, Fytianos K et al (2007) Photocatalytic oxidation of methyl parathion over TiO2 and ZnO suspensions. Catal Today 124:156–162
Fateh R, Ismail AA, Dillert R et al (2011) Highly active crystalline mesoporous TiO2 films coated onto polycarbonate substrates for self-cleaning applications. J Phys Chem C 115:10405–10411
Faust BC, Hoffmann MR, Bahnemann DW (1989) Photocatalytic oxidation of sulfur dioxide in aqueous suspensions of α-Fe2O3. J Phys Chem 93:6371–6381
Ferguson MA, Hering JG (2006) TiO2-Photocatalyzed As(III) Oxidation in a fixed-bed, flow-through reactor. Environ Sci Technol 40:4261–4267
Fingler S, Dravenkar V (1988) Chlorophenols in the Sava river before, in and after the Zagreb City area. Impact on the purity of the city ground and drinking waters. Toxicol Environ Chem 17:319–328
Fox MA (1983) Organic heterogeneous photocatalysis: chemical conversions sensitized by irradiated semiconductors. Acc Chem Res 16:314–321
Fu X, Zeltner WA, Anderson MA (1995) The gas-phase photocatalytic mineralization benzene on porous titania-based catalysts. Appl Catal B 6:209–224
Fujishima K, Fukuoka A, Yamagishi A (2001) Photooxidation of benzene to phenol by ruthenium bipyridine complexes grafted on mesoporous silica FSM-16. J Mol Catal A: Chem 166:211–218
Gao J, Liu L, Liu X et al (2008) Levels and spatial distribution of chlorophenols—2,4-dichlorophenol, 2,4,6-trichlorophenol, and pentachlorophenol in surface water of China. Chemosphere 71:1181–1187
García A, Amat AM, Arques A et al (2006) Detoxification of aqueous solutions of the pesticide “Sevnol” by solar photocatalysis. Environ Chem Lett 3:169–172
García-López E, Marcí G, Serpone N et al (2007) Photoassisted oxidation of the recalcitrant cyanuric acid substrate in aqueous ZnO suspensions. J Phys Chem C 111:18025–18032
Gaya UI, Abdullah AH, Zainal Z et al (2009) Photocatalytic treatment of 4-chlorophenol in aqueous ZnO suspensions: intermediates, influence of dosage and inorganic anions. J Hazard Mater 168:57–63
Gaya UI, Abdullah AH, Zainal Z et al (2010) Photocatalytic degradation of 2,4-dichlorophenol in irradiated aqueous ZnO suspension. Int J Chem 2:180–193
Goel M, Chovelon J-M, Ferronato C et al (2010) The remediation of wastewater containing 4-chlorophenol using integrated photocatalytic and biological treatment. J Photochem Photobiol B 98:1–6
Grätzel M (2005) Solar energy conversion by dye-sensitized photovoltaic cells. Inorg Chem 44:6841–6851
Guillard C, Lachheb H, Houas A et al (2003) Influence of chemical structure of dyes, of pH and of inorganic salts on their photocatalytic degradation by TiO2 comparison of the efficiency of powder and supported TiO2. J Photochem Photobiol A 158:27–36
Haick H, Paz Y (2001) Remote photocatalytic activity as probed by measuring the degradation of self-assembled monolayers anchored near microdomains of titanium dioxide. J Phys Chem B 105:3045–3051
Hernández-Alonso MD, Coronado JM, Maira AJ et al (2002) Ozone enhanced activity of aqueous titanium dioxide suspensions for photocatalytic oxidation of free cyanide ions. Appl Catal B 39:257–267
Hernando MD, Mezcua M, Fernández-Alba AR et al (2006) Environmental risk assessment of pharmaceutical residues in wastewater effluents, surface waters and sediments. Talanta 69:334–342
Hiskia A, Ecke M, Troupis A et al (2001) Sonolytic, photolytic, and photocatalytic decomposition of atrazine in the presence of polyoxometalates. Environ Sci Technol 35:2358–2364
Hong S-S, Lee MS, Kim J-H et al (2002) Photocatalytic decomposition of bromate over titanium dioxides prepared using sol-gel method. J Ind Eng Chem 8:150–155
Horikoshi S, Hidaka H (2003) Non-degradable triazine substrates of atrazine and cyanuric acid hydrothermally and in supercritical water under the UV-illuminated photocatalytic cooperation. Chemosphere 51:139–142
Hsu C-W, Wang L, Su W-F (2009) Effect of chemical structure of interface modifier of TiO2 on photovoltaic properties of poly(3-hexylthiophene)/TiO2 layered solar cells. J Colloid Interface Sci 329:182–187
Huang H, Li W (2011) Destruction of toluene by ozone-enhanced photocatalysis: performance and mechanism. Appl Catal B 102:449–453
Huang C, Chen DH, Li K (2003) Photocatalytic oxidation of butyraldehyde over titania in air: by-product identification and reaction pathways. Chem Eng Comm 190:373–392
Huber R, Moser JE, Grätzel M et al (2002) Observation of photoinduced electron transfer in dye/semiconductor colloidal systems with different coupling strengths. Chem Phys 285:39–45
Hug SJ, Leupin O (2003) Iron-catalyzed oxidation of arsenic (III) by oxygen and by hydrogen peroxide: pH-dependent formation of oxidants in the fenton reaction. Environ Sci Technol 37:2734–2742
Hung C-H, Marias BJ (1997) Role of chlorine and oxygen in the photocatalytic degradation of trichloroethylene vapor on TiO2 films. Environ Sci Technol 31:562–568
Ishibashi K-I, Nosaka Y, Hashimoto K et al (1998) Time-dependent behavior of active oxygen species formed on photoirradiated TiO2 films in air. J Phys Chem B 102(12):2117–2120
Ishibashi K-I, Fujishima A, Watanabe T et al (2000) Generation and deactivation processes of superoxide formed on TiO2 film illuminated by very weak UV light in air or water. J Phys Chem B 104:4934–4938
Jacoby WA, Blake DM, Fennell JA (1996) Heterogeneous photocatalysis for control of volatile organic compounds in indoor air. J Air Waste Manage Assoc 46:891–898
Jańczyk A, Krakowska E, Stochel G (2006) Singlet oxygen photogeneration at surface modified titanium dioxide. J Am Chem Soc 128:15574–15575
Jardim WF, Moraes SG, Takiyama MMK (1997) Photocatalytic degradation of aromatic chlorinated compounds using TiO2: toxicity of intermediates. Wat Res 31:1728–1732
Jayaweera PVV, Perera AGU, Tennakone K (2008) Why Gratzel’s cell works so well. Inorg Chim Acta 361:707–711
Jiang Y, Petrier C, Waite TD (2006) Sonolysis of 4-chlorophenol in aqueous solution: effects of substrate concentration, aqueous temperature and ultrasonic frequency. Ultrason Sonochem 13:415–422
Jung KY, Park SB (2004) Photoactivity of SiO2/TiO2 and ZrO2/TiO2 mixed oxides prepared by sol-gel method. Mater Lett 58:2897–2900
Kamble SP, Deosarkar SP, Sawant SB (2004) Photocatalytic Degradation of 2,4-Dichlorophenoxyacetic Acid Using Concentrated Solar Radiation: Batch and Continuous Operation. Ind Eng Chem Res 43(26):8178–8187
Kandiel TA, Dillert R, Robben L et al (2011) Photonic efficiency and mechanism of photocatalytic molecular hydrogen production over platinized titanium dioxide from aqueous methanol solutions. Catal Today 161:196–201
Kebir M, Chabani M, Nasrallah N et al (2011) Coupling adsorption with photocatalysis process for the Cr(VI) removal. Desalination 270:166–173
Khodja AA, Sehili T, Pilichowski J-F et al (2001) Photocatalytic degradation of 2-phenylphenol on TiO2 and ZnO in aqueous suspensions. J Photochem Photobiol A 141:231–239
Kim H, Choi W (2007) Effects of surface fluorination of TiO2 on photocatalytic oxidation of gaseous acetaldehyde. Appl Catal B 69:127–132
Kong F-T, Dai S-Y, Wang K-J (2007) Review of recent progress in dye-sensitized solar cells. Adv OptoElectron. doi:10.1155/2007/75384
Konstantinou IK, Sakkas VA, Albanis TA (2001) Photocatalytic degradation of the herbicides propanil and molinate over aqueous TiO2 suspensions: identification of intermediates and the reaction pathway. Appl Catal B 34:227–239
Krijgsheld KR, Gen A van der (1986) Assessment of the impact of the emission of certain organochlorine compounds on the aquatic environment. Chemosphere 15:825–860
Kubo W, Tatsuma T (2004) Detection of H2O2 released from TiO2 phototcatalyst to air. Anal Sci 24:591–593
Kubo W, Tatsuma T (2005) Photocatalytic remote oxidation with various photocatalysts and enhancement of its activity. J Mater Chem 15:3104–3108
Kubo W, Tatsuma T, Fujishima A et al (2004) Mechanisms and resolution of photocatalytic lithography. J Phys Chem B 108:3005–3009
Kwon BG, Yoon J (2009) Experimental evidence of the mobility of hydroperoxyl/superoxide anion radicals from the illuminated TiO2 interface into the aqueous phase. Bull Korean Chem Soc 30(3):667–670
Kyung HS, Lee JS, Choi W (2005) Simultaneous and synergistic conversion of dyes and heavy metal ions in aqueous TiO2 suspensions under visible-light illumination. Environ Sci Technol 39:2376–2382
L’Amour RJA, Azevedo EB, Leite SGF et al (2008) Removal of phenol in high salinity media by a hybrid process (activated sludge + photocatalysis). Sep Purif Technol 60:142–146
L’homme L, Brosillon S, Wolbert D (2008) Photocatalytic degradation of pesticides in pure water and a commercial agricultural solution on TiO2 coated media. Chemosphere 70(2008):381–386
Lackhoff M, Niessner R (2002) Photocatalytic atrazine degradation by synthetic minerals, atmospheric aerosols, and soil particles. Environ Sci Technol 36:5342–5347
Lai K, Zhu Y, Lu J et al (2013) N- and Mo-doping Bi2WO6 in photocatalytic water splitting. Comput Mater Sci 67:88–92
Lalitha K, Reddy JK, Sharma MVP et al (2010) Continuous hydrogen production activity over finely dispersed Ag2O/TiO2 catalysts from methanol:water mixtures under solar irradiation: a structure–activity correlation. Int J Hydrogen Energy 35:3991–4001
Lathasree S, Rao AN, SivaSankar B et al (2004) Heterogeneous photocatalytic mineralisation of phenols in aqueous solutions. J Mol Catal A: Chem 223:101–105
Lee H, Choi W (2002a) Photocatalytic oxidation of arsenite in TiO2 suspension: kinetics and mechanisms. Environ Sci Technol 36:3872–3878
Lee MC, Choi W (2002b) Solid phase photocatalytic reaction on the soot/TiO2 interface: the role of migrating OH radicals. J Phys Chem B 106:11818–11822
Leng WH, Cheng XF, Zhang JQ et al (2007) Comment on “Photocatalytic oxidation of arsenite on TiO2: understanding the controversial oxidation mechanism involving superoxides and the effect of alternative electron acceptors”. Environ Sci Technol 41:6311–6312
Lewerenz HJ, Heine C, Skorupska K et al (2010) Photoelectrocatalysis: principles, nanoemitter applications and routes to bio-inspired systems. Energy Environ Sci 3:748–760
Li D, Haneda H (2003) Photocatalysis of sprayed nitrogen-containing Fe2O3–ZnO and WO3–ZnO composite powders in gas-phase acetaldehyde decomposition. J Photochem Photobiol A 160:203–212
Li S, Ma Z, Zhang J et al (2008) A comparative study of photocatalytic degradation of phenol of TiO2 and ZnO in the presence of manganese dioxides. Catal Today 139:109–112
Li Q, Easter NJ, Shang JK (2009) As(III) removal by palladium-modified nitrogen-doped titanium oxide nanoparticle photocatalyst. Environ Sci Technol 43:1534–1539
Li W, Lu S, Qiu Z et al (2011) Photocatalysis of clofibric acid under solar light in summer and winter seasons. Ind Eng Chem Res 50:5384–5393
Liqiang J, Baifu X, Fulong Y et al (2004) Deactivation and regeneration of ZnO and TiO2 nanoparticles in the gas phase photocatalytic oxidation of n-C7H16 or SO2. Appl Catal A 275:49–54
Luo Y, Ollis DF (1996) Heterogeneous photocatalytic oxidation of trichloroethylene and toluene mixtures in air: kinetic promotion and inhibition, time-dependent catalyst activity. J Catal 163:1–11
Maira AJ, Yeung KL, Soria J et al (2001) Gas-phase photo-oxidation of toluene using nanometer-size TiO2 catalysts. Appl Catal B 29:327–336
Malato S, Cáceres J, Fernández-Alba AR (2003) Photocatalytic treatment of diuron by solar photocatalysis: evaluation of main intermediates and toxicity. Environ Sci Technol 37:2516–2524
Mantilla A, Tzompantzi F, Fernández JL et al (2010) Photodegradation of phenol and cresol in aqueous medium by using Zn/Al + Fe mixed oxides obtained from layered double hydroxides materials. Catal Today 150:353–357
Marchante E, Lana-Villarreal T, Sáez V, Gonzólez-García J, Gómez R (2009) Sonopotential: a new concept in electrochemistry. Chem Commun 27:4127–4129
Martra G, Coluccia S, Marchese L (1999) The role of H2O in the photocatalytic oxidation of toluene in vapour phase on anatase TiO2 catalyst. A FTIR study. Catal Today 53:695–702
Matar S, Hatch LF (2000) Chemistry of petrochemical processes. Gulf Publishing Company, Texas
McCusker JK (2001) Fuel from photons. Science 293:1599–1601
McMurray TA, Dunlop PSM, Byrne JA (2006) The photocatalytic degradation of atrazine on nanoparticulate TiO2 films. J Photochem Photobiol A 182:43–51
Mills A, McGrady M (2008) A study of new photocatalyst indicator inks. J Photochem Photobiol A 193:228–236
Mills A, Belghazi A, Rodman D (1996) Bromate removal from water by semiconductor photocatalysis. Water Res 30:1973–1978
Mills A, Hill G, Bhopal S et al (2003) Thick titanium dioxide films for semiconductor photocatalysis. J Photochem Photobiol A 160:185–194
Mills A, Wang J, Lee S-K et al (2005) An intelligence ink for photocatalytic films. Chem Commun 21:2721–2723
Mills A, Wang J, McGrady M (2006) Method of rapid assessment of photocatalytic activities of self-cleaning films. J Phys Chem B 110:18324–18331
Mills A, McGrady M, Wang J et al (2008) A rapid method of assessing the photocatalytic activity of thin TiO2 films using an ink based on the redox dye 2,6-dichloroindophenol. Int J Photoenergy:1–6
Minero C, Mariella G, Maurino V et al (2000a) Photocatalytic transformation of organic compounds in the presence of inorganic anions. 1. Hydroxyl-mediated and direct electron-transfer reactions of phenol on a titanium dioxide-fluoride system. Langmuir 16:2632–2641
Minero C, Mariella G, Maurino V et al (2000b) Photocatalytic transformation of organic compounds in the presence of inorganic ions. 2. Competitive reactions of phenol and alcohols on a titanium dioxide-fluoride system. Langmuir 16:8964–8972
Minero C, Pelizzetti E, Malato S et al (1996) Large solar plant photocatalytic water decontamination: degradation of atrazine. Sol Energy 56:411–419
Mofidi AA, Min JH, Palencia LS et al (2002) Task 2.1: advanced oxidation processes and UV Photolysis for treatment of drinking water, metropolitan water district of Southern California. California Energy Commission, La Verne
Mohan D, Pittman CU Jr (2007) Arsenic removal from water/wastewater using adsorbents—a critical review. J Hazard Mater 142:1–53
Moser J, Grätzel M (1983) Light-induced electron transfer in colloidal semiconductor dispersions: single vs. dielectronic reduction of acceptors by conduction-band electrons. J Am Chem Soc 105:6547–6555
Muradov NZ, Raissi AT, Muzzey D et al (1996) Selective photocatalytic destruction of airbone VOCs. Sol Energy 56:445–456
Murakami Y, Kenji E, Nosaka AY et al (2006) Direct detection of OH radicals diffused to the gas phase from the UV-irradiated photocatalytic TiO2 surfaces by means of laser-induced fluorescence spectroscopy. J Phys Chem B 110(34):16808–16811
Murakami Y, Endo K, Ohta I et al (2007) Can OH radicals diffuse from the UV-irradiated photocatalytic TiO2 surfaces? Laser-induced-fluorescence study. J Phys Chem C 111:11339–11346
Nagata Y, Nakagawa M, Okuno H et al (2000) Sonochemical degradation of chlorophenols in water. Ultrason Sonochem 7:115–120
Naito K, Tachikawa T, Cui S-C et al (2006) Single-molecule detection of airborne singlet oxygen. J Am Chem Soc 128:16430–16431
Nakamura R, Nakato Y (2004) Primary intermediates of oxygen photoevolution reaction on TiO2 (rutile) particles, revealed by in situ FTIR absorption and photoluminescence measurements. J Am Chem Soc 126:1290–1298
Neta P, Huie RE (1985) Free-radical chemistry of sulphite. Environ Health Perspect 64:209–217
Nikolaou AD, Kostopoulou MN, Lekkas TD (1999) Organic by-products of drinking water chlorination. Global Nest: Int J 1:143–156
Nimlos MR, Jacoby WA, Blake DM et al (1979) Direct mass spectrometric studies of the destruction of hazardous wastes. 2. Gas-phase photocatalytic oxidation of trichloroethylene over TiOs: Products and mechanisms. Environ Sci Technol 27:732–740
Ohko Y, Tryk DA, Hashimoto K et al (1998) Autoxidation of acetaldehyde initiated by TiO2 photocatalysis under weak UV illumination. J Phys Chem B 102:2699–2704
Ojanperä I (2000) Pesticides. In: Bogusz MJ (ed) Forensic science. Hanbook of analytical separations, vol 2. Elsevier Science
Oliveira HG, Nery DC, Longo C (2010) Effect of applied potential on photocatalytic phenol degradation using nanocrystalline TiO2 electrodes. Appl Catal B 93:205–211
Oturan N, Brillas E, Oturan MA (2012) Unprecedented total mineralization of atrazine and cyanuric acid by anodic oxidation and electro-Fenton with a boron-doped diamond anode. Environ Chem Lett 10:165–170
Özcan L, Yurdakal S, Augugliaro V et al (2010) Photoelectrocatalytic selective oxidation of 4-methoxybenzyl alcohol in water by TiO2 supported on titanium anodes. Appl Catal B. doi:10.1016/j.apcatb.2012.12.030
Park H, Choi W (2004) Effects of TiO2 surface fluorination on photocatalytic reactions and photoelectrochemical behaviours. J Phys Chem B 108:4086–4093
Parra S, Stanca SE, Guasaquillo I et al (2004) Photocatalytic degradation of atrazine using suspended and supported TiO2. Appl Catal B 51:107–116
Patnaik P (2004) Deanʼs analytical chemistry handbook. McGraw-Hill Handbooks, United States of America
Paul T, Miller PL, Strathmann TJ (2007) Visible-light-mediated TiO2 photocatalysis of fluoroquinolone antibacterial agents. Environ Sci Technol 41:4720–4727
Pelizetti E, Maurino V, Minero C (1990) Photocatalytic degradation of atrazine and other s-triazine herbicides. Environ Sci Technol 24:1559–1565
Peller J, Wiest O, Kamat PV (2003) Synergy of combining sonolysis and photocatalysis in the degradation and mineralization of chlorinated aromatic compounds. Environ Sci Technol 37:1926–1932
Peller J, Wiest O, Kamat PV (2004) Hydroxyl radical’s role in the remediation of a common herbicide, 2,4-Dichlorophenoxyacetic acid (2,4-D). J Phys Chem A 108:10925–10933
Pena ME, Korfiatis GP, Patel M et al (2005) Adsorption of As(V) and As(III) by nanocrystalline titanium dioxide. Water Res 39:2327–2337
Peralta-Zamora P, Gomes deMS, Pelegrinir R et al (1998) Evaluation of ZnO, TiO2 and supported ZnO on the photoassisted remediatlon of black liquor, cellulose and textile mill effluents. Chemosphere 36:2119–2133
Pichat P, Herrmann J-M, Disdler J et al (1979) Photocatalytic oxidation of propene over various oxides at 320 K. Selectivity. J Phys Chem 83:3122–3126
Poulose AC, Veeranarayanan S, Varghese SH et al (2012) Functionalized electrophoretic deposition of CdSe quantum dots onto TiO2 electrode for photovoltaic application. Chem Phys Lett 539–540:197–203
Prairie MR, Evans LR, Stange BM et al (1993) An investigation of TiO2 photocatalysis for the treatment of water contaminated with metals and organic chemicals. Environ Sci Technol 27:1776–1782
Qamar M, Muneer M, Bahnemann D (2006) Heterogeneous photocatalysed degradation of two selected pesticide derivatives, triclopyr and daminozid in aqueous suspensions of titanium dioxide. J Environ Manage 80:99–106
Rahman MA, Muneer M (2005) Photocatalysed degradation of two selected pesticide derivatives, dichlorvos and phosphamidon, triclopyr and daminozid in aqueous suspensions of titanium dioxide. Desalination 185:161–172
Ranjit PJD, Palanivelu K, Lee C-S (2008) Degradation of 2,4-dichlorophenol in aqueous solution by sono-Fenton method. Korean J Chem Eng 25:112–117
Rauf MA, Meetani MA, Hisaindee S (2011) An overview on the photocatalytic degradation of azo dyes in the presence of TiO2 doped with selective transition metals. Desalination 276:13–27
Ravichandran L, Selvam K, Swaminathan M (2007) Effect of oxidants and metal ions on photodefluoridation of pentafluorobenzoic acid with ZnO. Sep Purif Methods 56:192–198
Rayalu SS, Jose D, Joshi MV et al (2013) Photocatalytic water splitting on Au/TiO2 nanocompositessynthesized through various routes: enhancement in photocatalyticactivity due to SPR effect. Appl Catal B 142–143:684–693
Razykov TM, Ferekides CS, Morel D et al (2011) Solar photovoltaic electricity: current status and future prospects. Sol Energy 85:1580–1608
Reyes C, Fernandez J, Freer J et al (2006) Degradation and inactivation of tetracycline by TiO2 photocatalysis. J Photochem Photobiol A 184:141–146
Ryu J, Choi W (2004) Effects of TiO2 surface modifications on photocatalytic oxidation of arsenite: the role of superoxides. Environ Sci Technol 38:2928–2933
Ryu J, Choi W (2006) Photocatalytic oxidation of arsenite on TiO2: Understanding the controversial oxidation mechanism involving superoxides and the effect of alternative electron acceptors. Environ Sci Technol 40:7034–7039
Ryu J, Choi W (2007) Response to comment on “Photocatalytic oxidation of arsenite on TiO2: understanding the controversial oxidation mechanism involving superoxides and the effect of alternative electron acceptors”. Environ Sci Technol 41:6313–6314
Sakthivel S, Neppolian B, Shankar MV et al (2003) Solar photocatalytic degradation of azo dye: comparison of photocatalytic efficiency of ZnO and TiO2. Sol Energy Mater Sol Cells 77:65–82
Sandstead HH (1991) Zinc deficiency. A public health problem? Am J Dis Child 145(8):853–859
Sasaki Y, Iwase A, Kato H et al (2008) The effect of co-catalyst for Z-scheme photocatalysis systems with an Fe3+/Fe2+ electron mediator on overall water splitting under visible light irradiation. J Catal 259(2008):133–137
Sauer ML, Hale MA, Ollis DF (1995) Heterogeneous photocatalytic oxidation of dilute toluene-chlorocarbon mixtures in air. J Photochem Photobiol A 88:169–178
Sawyer DT, Sobkowiak A, Roberts JL Jr (1995) Electrochemistry for chemists. Wiley, New York
Sharma VK, Sohn M (2009) Aquatic arsenic: toxicity, speciation, transformations, and remediation. Environ Int 35:743–759
Shen YS, Ku Y (2002) Decomposition of gas-phase trichloroethene by the UV/TiO2 process in the presence of ozone. Chemosphere 46:101–107
Shen P, Liu X, Jiang S et al (2011) Effects of aromatic p-conjugated bridges on optical and photovoltaic properties of N, N-diphenylhydrazone-based metal-free organic dyes, N, N-diphenylhydrazone-based metal-free organic dyes. Org Electron 12:1992–2002
Simamora A-J, Hsiung T-L, Chang F-C et al (2013) Photocatalytic splitting of seawater and degradation of methylene blue on CuO/nano TiO2. Int J Hydrogen Energy 37:13855–13858
Sleiman M, Ferronato C, Chovelon J-M (2008) Photocatalytic removal of pesticide dichlorvos from indoor air: a study of reaction parameters, intermediates and mineralization. Environ Sci Technol 42:3018–3024
Sobana N, Swaminathan M (2007) The effect of operational parameters on the photocatalytic degradation of acid red 18 by ZnO. Sep Purif Technol 56:101–107
Somasundaram S, Chenthamarakshan CRN, de Tacconi NR et al (2007) Photocatalytic production of hydrogen from electrodeposited p-Cu2O film and sacrificial electron donors. Int J Hydrogen Energ 32:4661–4669
Stock NL, Peller J, Vinodgopal K et al (2000) Combinative sonolysis and photocatalysis for textile dye degradation. Environ Sci Technol 34:1747–1750
Sun L, Bolton JR (1996) Determination of the quantum yield for the photochemical generation of hydroxyl radicals in TiO2 suspensions. J Phys Chem 100:4127–4134
Sun B, Reddy EP, Smirniotis PG (2005) Visible light Cr(VI) reduction and organic chemical oxidation by TiO2 photocatalysis. Environ Sci Technol 39:6251–6259
Suryaman D, Hasegawa K, Kagaya S (2006) Combined biological and photocatalytic treatment for the mineralization of phenol in water. Chemosphere 65:2502–2506
Swaddle TW (1990) Inorganic chemistry. Academic, USA
Tatsuma T, Kubo W (2007) Photocatalytic lithography based on photocatalytic remote oxidation. J Photopolym Sci Technol 20:83–87
Tatsuma T, Tachibana S-I, Miwa T et al (1999) Remote bleaching of methylene blue by UV-irradiated TiO2 in the gas phase. J Phys Chem B 103:8033–8035
Tatsuma T, Kubo W, Fujishima A (2002) Patterning of solid surfaces by photocatalytic lithography based on the remote oxidation effect of TiO2. Langmuir 18:9632–9634
Tetzlaff TA, Jenks WS (1999) Stability of cyanuric acid to photocatalytic degradation. Org Lett 1:463–465
Thampi KR, Reddy TV, Ramakrishnan V et al (1983) Mechanism of the photoelectrocatalytic dehydrogenation of 2-propanolon a polycrystalline ZnO photoelectrode. Electrochim Acta 28:1869–1874
Turchi CS, Ollis DF (1990) Photocatalytic degradation of organic water contaminants: mechanisms involving hydroxyl radical attack. J Catal 122:178–192
Uddin MJ, Davies B, Dickens TJ et al (2013) Self-aligned carbon nanotubes yarns (CNY) with efficient optoelectronic interface for microyarn shaped 3D photovoltaic cells. Sol Energy Mater Sol Cells 115:166–171
US EPA (2006) National Emission Standards for Hazardous Air Pollutants: miscellaneous organic chemical manufacturing. final rule, federal register part V, 40 CFR part 63, United States Environmental Protection Agency
EPA/OSHA US (2000) Chemical advisory and notice of potential risk: skin exposure to molten 2,4-dichlorophenol (2,4-DCP) can cause rapid death, US EPA Office of pollution prevention and toxics and occupational safety and health administration, United States of America
Vimonses V, Jin B, Chow CWK et al (2010) An adsorption-photocatalysis hybrid process using multi-functional-nanoporous materials for wastewater reclamation. Water Res 44:5385–5397
Vincent G, Aluculesei A, Parker A et al (2008) Direct detection of OH radicals and indirect detection of H2O2 molecules in the gas phase near a TiO2 photocatalyst using LIF. J Phys Chem C 112(25):9115–9119
Vinu R, Madras G (2009) Kinetics of sonophotocatalytic degradation of anionic dyes with nano-TiO2. Environ Sci Technol 43:473–479
Vorontsov AV, Stoyanova IV, Kozlov DV et al (2000) Kinetics of the photocatalytic oxidation of gaseous acetone over platinized titanium dioxide. J Catal 189:360–369
Wang K-H, Jehng J-M, Hsieh Y-H et al (2002) The reaction pathway for the heterogeneous photocatalysis of trichloroethylene in gas phase. J Hazard Mater 90:63–75
Wang X, Jia J, Wang Y (2011) Degradation of C. I. reactive red 2 through photocatalysis coupled with water jet cavitation. J Hazard Mater 185:315–321
Wang Q, An N, Bai Y et al (2013) High photocatalytic hydrogen production from methanol aqueous solution using the photocatalysts CuS/TiO2. Int J Hydrogen Energy. http://dx.doi.org/10.1016/j.ijhydene.2013.02.131
Wegman RCC, Den BHH van (1983) Chlorophenols in river sediments in the Netherlands (1976–1977). Water Res 17:227–230
Wu W, Li J, Guo F et al (2010) Photovoltaic performance and long-term stability of quasi-solid-state fluoranthene dyes-sensitized solar cells. Renew Energ 35:1724–1728
Wunderlich W, Oekermann T, Miao L et al (2004) Electronic properties of nano-porous TiO2- and ZnO-thin films-comparison of simulations and experiments. J Ceram Process Res 5:343–354
Xu T, Kamat PV, O’Shea KE (2005) Mechanistic evaluation of arsenite oxidation in TiO2 assisted photocatalysis. J Phys Chem A 109:9070–9075
Yahiat S, Fourcade F, Brosillon S et al (2011a) Photocatalysis as a pre-treatment prior to a biological degradation of cyproconazole. Desalination 281:61–67
Yahiat S, Fourcade F, Brosillon S et al (2011b) Removal of antibiotics by an integrated process coupling photocatalysis and biological treatment—case of tetracycline and tylosin. Int Biodeter and Biodegr 65:997–1003
Yamaguchi M, Tomizawa M, Takagaki K, Masui D, Yamagishi T et al (2006) Photooxidation of alkane under visible light irradiation catalyzed by ruthenium complexes. Catal Today 117:206–209
Yan J, Zhang L, Yang H et al (2009) CuCr2O4/TiO2 heterojunction for photocatalytic H2 evolution under simulated sunlight irradiation. Sol Energy 83:1534–1539
Yang H, Lin WY, Rajeshwar K (1999) Homogeneous and heterogeneous photocatalytic reactions involving As(III) and As(V) species in aqueous media. J Photochem Photobiol A 123:137–143
Yang G-P, Zhao X-K, Suna X-J et al (2005a) Oxidative degradation of diethyl phthalate by photochemically-enhanced Fenton reaction. J Hazard Mater 126:112–118
Yang J, Chen C, Ji H et al (2005b) Mechanism of TiO2-assisted photocatalytic degradation of dyes under visible irradiation: photoelectrocatalytic study by TiO2-film Electrodes. J Phys Chem B 109:21900–21907
Yang L, Yu LE, Ray MB (2009) Photocatalytic oxidation of paracetamol: dominant reactants, intermediates, and reaction mechanisms. Environ Sci Technol 43:460–465
Yoon SH, Lee JH (2005) Oxidation mechanism of As(III) in the UV/TiO2 system: evidence for a direct hole oxidation mechanism. Environ Sci Technol 39:9695–9701
Yoon SH, SE Oh, Yang JE et al (2009) TiO2 photocatalytic oxidation mechanism of As(III). Environ Sci Technol 43:864–869
Zainal Z, Lee CY, Hussein MZ et al (2007) Electrochemical-assisted photodegradation of mixed dye and textile effluents using TiO2 thin films. J Hazard Mater 146:73–80
Zainudin NF, Abdullah AZ, Mohamed AR (2010) Characteristics of supported nano-TiO2/ZSM-5/silica gel (SNTZS): photocatalytic degradation of phenol. J Hazard Mater 174:299–306
Zama K, Fukuoka A, Sasaki Y (2000) Selective hydroxylation of benzene to phenol by photocatalysis of molybdenum complexes grafted on mesoporous FSM-16. Catal Lett 66:251–253
Zhang F, Zhaoa J, Shen T et al (1998) TiO2-assisted photodegradation of dye pollutants II. Adsorption and degradation kinetics of eosin in TiO2 dispersions under visible light irradiation. Appl Catal B 15:147–156
Zhang Q, Liu J, Wang W et al (2006a) A novel regular catalyst for gas-phase photodestruction of organic substances of dilute concentrations. Catal Commun 7:685–688
Zhang S, Zheng Z, Wang J et al (2006b) Heterogeneous photocatalytic decomposition of benzene on lanthanum-doped TiO2 film at ambient temperature. Chemosphere 65:2282–2288
Zheng S, Cai Y, O’Shea KE (2010) TiO2 photocatalytic degradation of phenylarsonic acid. J Photochem Photobiol A 210:61–68
Zhong J, Wang J, Tao L et al (2007) Photocatalytic degradation of gaseous benzene over TiO2/Sr2CeO4: kinetic model and degradation mechanisms. J Hazard Mater 139:323–331
Zhu X, Yuan CW, Chen H (2007) Photocatalytic degradation of pesticide pyridaben. 3. In surfactant/TiO2 aqueous dispersions. Environ Sci Technol 41:263–269
Zou S-W, How C-W, Chen JP (2007) Photocatalytic treatment of wastewater contaminated with organic waste and copper ions from the semiconductor industry. Ind Eng Chem Res 46:6566–6571
Zuo G-M, Cheng Z-X, Chen H (2006) Study on photocatalytic degradation of several volatile organic compounds. J Hazard Mater 128:158–163
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Gaya, U. (2014). Perspectives and Advances in Photocatalysis. In: Heterogeneous Photocatalysis Using Inorganic Semiconductor Solids. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-7775-0_5
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