Abstract
Photocatalytic oxidation of organic substrates occurs with high chemical yield on irradiated semiconductor surfaces. Photocatalysis is defined and exemplified and the theories of photoelectrochemistry are used to construct model cells. Mechanistic criteria needed to define a redox reaction pathway on a heterogeneous photocatalyst are reviewed, and a brief survey of functional group transformations which have been reported on semiconductor surfaces is given. The photocatalytic oxygenation of olefins is considered as a vehicle to illustrate these principles, and several practical applications of such investigations are cited.
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Fox, M.A. (1988). Photocatalytic Oxidation of Organic Substrates. In: Schiavello, M. (eds) Photocatalysis and Environment. NATO ASI Series, vol 237. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3015-5_16
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DOI: https://doi.org/10.1007/978-94-009-3015-5_16
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