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Part of the book series: NATO ASI Series ((ASIC,volume 182))

Abstract

The cyclization properties of polymer chains serve as a useful vehicle for examining various theoretical predictions about the polymer conformation and dynamics. Cyclization phenomena are particularly sensitive to excluded volume phenomena. This chapter provides a review of pertinent theoretical concepts and a description of experiments, based upon luminescence spectroscopy, which allow one to examine the predictions of the theory.

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References

  1. H. Freundlich and A. Krestovnikoff, Z. Phys. Chem. 1911, 76, 26.

    Google Scholar 

  2. (b) For an early review, see G.M. Bennet, Trans. Faraday Soc., 1941, 37, 794.

    Article  Google Scholar 

  3. W.H. Kuhn, Kolloid Z., 1934, 68, 2.

    Article  CAS  Google Scholar 

  4. H. Jacobson and W.H. Stockmayer, J. Chem. Phys., 1950, 18, 1600.

    CAS  Google Scholar 

  5. P.J. Flory and J.A. Semlyen, J. Am. Chem. Soc., 1966, 18, 3209.

    Article  Google Scholar 

  6. S. Tazuke and M.A. Winnik, chapter 2 in this volume.

    Google Scholar 

  7. J.B. Birks, ‘Photophysics of Aromat ic Molecules,’ Wiley-Interscience, New York, 1971.

    Google Scholar 

  8. G. Wilemski and M. Fixman, J. Chem. Phys., 1974, 60, 866.

    Article  CAS  Google Scholar 

  9. C. Cuniberti and A. Perico, Prog. Polym. Sci., 1984, 10, 271.

    Article  CAS  Google Scholar 

  10. P.J. Flory, ‘Statistical Mechanics of Chain Molecules,’ Wiley-Interscience, New York, 1969.

    Google Scholar 

  11. L.H. Sperling, Polym. Eng. Sci., 1984, 24, 1.

    Article  CAS  Google Scholar 

  12. J.F. Brown and G.M. Slusarczuk, J. Am. Chem. Soc., 1966, 88, 3209.

    Article  Google Scholar 

  13. P.G. deGennes, ‘Scaling Concepts in Polymer Physics,’ Cornell University Press, Ithaca, N.Y., 1979.

    Google Scholar 

  14. (b) J. des Cloizeaux, J. Phys. (Paris). Colloq., 1978, C2, 135.

    Google Scholar 

  15. M. Doi, Chem. Phys., 1975, 9, 455;

    Article  CAS  Google Scholar 

  16. S. Sunagawa and M. Doi, Polym. J., 1975, 7, 604;

    Article  CAS  Google Scholar 

  17. ibid. 1976, 8, 239.

    Google Scholar 

  18. A. Perico and C. Cuniberti, J. Polym. Sci. Polym. Phys. Ed., 1977, 15, 1435.

    Article  CAS  Google Scholar 

  19. A. Perico and M. Battezzati, J. Chem. Phys., 1981, 75, 4430.

    Article  CAS  Google Scholar 

  20. M. Battezzati and A. Perico, J. Chem. Phys., 1981, 74, 4527.

    Article  CAS  Google Scholar 

  21. M. Battezzati and A. Perico, J. Chem. Phys., 1981, 75, 886.

    Article  CAS  Google Scholar 

  22. A. Szabo, K. Schulten and Z. Schulten, J. Chem. Phys., 1980, 72, 4350.

    Article  CAS  Google Scholar 

  23. H. Yamakawa, ‘Modern Theory of Polymer Solutions,’ Harper and Row, New York, 1971.

    Google Scholar 

  24. A. Perico, P. Piaggio and C. Cuniberti, J. Chem. Phys., 1975, 62, 4911.

    Article  CAS  Google Scholar 

  25. (J.D. Simon and K.S. Peters, J. Am. Chem. Soc., 1981, 103, 6403.

    Article  CAS  Google Scholar 

  26. J.D. Simon and K.S. Peters, J. Am. Chem. Soc., 1982, 104, 6542.

    Article  CAS  Google Scholar 

  27. W. Hub, S. Schneider, F. Dörr, J.D. Oxman and F.D. Lewis, J. Am. Chem. Soc., 1984, 106, 701.

    Article  CAS  Google Scholar 

  28. (c) W. Hub, S. Schneider,F. Dörr, J.D. Oxman and F.D. Lewis, J. Am. Chem. Soc., 1984, 106, 708.

    Article  CAS  Google Scholar 

  29. A. Weller, Z. Phys. Chem. (Wiesbaden), 1976, 101, 371.

    Article  Google Scholar 

  30. A. Weller, Z. Phys. Chem. (Wiesbaden), 1982, 130, 129.

    Article  CAS  Google Scholar 

  31. A. Weller, Z. Phys. Chem. (Wiesbaden), 1982, 133, 93.

    Article  CAS  Google Scholar 

  32. I. Soutar and D. Philips, chapter 6 in this volume.

    Google Scholar 

  33. J. Vandendriessche, R. Goedeweek, P. Collart and F. DeSchryver, chapter 10 in this volume.

    Google Scholar 

  34. R.M. Noyes, Prog. Reaction Kinetics, 1961, 1, 129.

    CAS  Google Scholar 

  35. H. Ushiki, K. Horie, A. Okamoto and I. Mita, Polym. J., 1981, 13, 191.

    Article  CAS  Google Scholar 

  36. K. Horie, W. Schnabel, I. Mita and H. Ushiki, Macromolecules, 1981, 14, 1422.

    Article  CAS  Google Scholar 

  37. M.A. Winnik, A.E.C. Redpath, K. Paton and J. Danhelka, Polymer, 1984, 25, 91.

    Article  CAS  Google Scholar 

  38. (b) A.E.C. Redpath and M.A. Winnik, Ann. N.Y. Acad. Sci., 1981, 10, 359.

    Google Scholar 

  39. J.B. Birks, Rep. Prog. Phys., 1975, 38, 903.

    Article  CAS  Google Scholar 

  40. J. Brandrup and E.H. Immergut, editors, ‘Polymer Handbook,’ 2nd ed., section IV, J. Wiley, New York, 1975.

    Google Scholar 

  41. M.A. Winnik, A.M. Sinclair and G. Beinert, Macromolecules, 1985, 18, 1517.

    Article  CAS  Google Scholar 

  42. M.A. Winnik, Accounts Chem. Res., 1985, 18, 73.

    Article  CAS  Google Scholar 

  43. A.E.C. Redpath and M.A. Winnik, J. Am. Chem. Soc., 1984

    Google Scholar 

  44. M.A. Winnik, A.M. Sinclair and G. Beinert, Can. J. Chem., 1985, 63, 1300.

    Article  CAS  Google Scholar 

  45. M.A. Winnik, A.M. Sinclair and G. Beinert, J. Am. Chem. Soc., 1985 in press.

    Google Scholar 

  46. J. Raczek and G. Meyerhoff, Proceedings of the 27th International Symposium on Macromolelcules, Strasbourg, France, July 1981, pp. 700–703.

    Google Scholar 

  47. J. Raczek, Eur. Polym. J., 1983, 19, 607.

    Article  CAS  Google Scholar 

  48. Y. Oono and K.F. Freed, J. Phys. A. Math. Gen., 1982, 15, 1931.

    Article  CAS  Google Scholar 

  49. M.A. Winnik, X.B. Li and J.E. Guillet, J. Polym. Sci. Polym. Symp., in press, 1985.

    Google Scholar 

  50. S. Saeki, N. Kuwahara, S. Konno and M. Kaneko, Macromolecules, 1973 6, 589.

    Article  CAS  Google Scholar 

  51. A.M. Sinclair, Ph.D. Thesis, University of Toronto, 1986.

    Google Scholar 

  52. C. Cuniberti and A. Perico, Eur. Polym. J., 1977, 13, 369.

    Article  CAS  Google Scholar 

  53. S.T. Cheung, A.E.C. Redpath and M.A. Winnik, Makromol. Chem., 1982, 183, 1815.

    Article  CAS  Google Scholar 

  54. A.E.C. Redpath, P. Svirskaya, J. Danhelka and M.A. Winnik, Polymer 1983, 24, 319.

    Article  Google Scholar 

  55. S. Slomkowski and M.A. Winnik, submitted for publication (1985).

    Google Scholar 

  56. (a) C. Cuniberti and A. Perico, Eur. Polym. J., 1980, 16, 887.

    Article  CAS  Google Scholar 

  57. (b) C. Cuniberti and A. Perico, Ann. N.Y. Acad. Sci., 1981, 366, 35.

    Article  Google Scholar 

  58. M.A. Winnik, X.B. Li and J.E. Guillet, Macromolecules, 1983, 16, 992.

    Article  Google Scholar 

  59. A.E.C. Redpath and M.A. Winnik, Polymers, 1983, 24, 1286.

    Article  CAS  Google Scholar 

  60. C. Cuniberti, L. Musi and A. Perico, J. Poly. Sci. Poly. Lett., 1982, 20, 265.

    Article  CAS  Google Scholar 

  61. M.A. Winnik, X.B. Li and J.E. Guillet, Macromolecules, 1984, 17, 699.

    Article  CAS  Google Scholar 

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© 1986 D. Reidel Publishing Company

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Winnik, M.A. (1986). The Cyclization of Polymer Chains in Solution. In: Winnik, M.A. (eds) Photophysical and Photochemical Tools in Polymer Science. NATO ASI Series, vol 182. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4726-9_13

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  • DOI: https://doi.org/10.1007/978-94-009-4726-9_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8601-1

  • Online ISBN: 978-94-009-4726-9

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