Abstract
An account is given on some new developments in the field of polynuclear iso- and heteropolymolybdates and -tungstates. This class of compounds attracts special attention because of their extremely variable range of applications reaching from the well-known analytical ones to important industrial oxidation catalysts, and, most importantly in the present context of biological applications, extending to possible significance in the fields of antitumor reagents and of anti-HIV and anti-retroviral agents. Starting with the synthesis and structural properties of some typical novel examples of polynuclear heteropolymolybdates and -tungstates, a brief review is given on some most recent results in the latter field of biomedical and pre-clinical research in the field of their biological action.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Pope, M.T. Heteropoly and Isopoly Oxometalatesand Springer-Verlag: Berlin, Heidelberg, New York, Tokyo, 1983.
Pope, M.T. In: Comprehensive Coordination Chemistry (G. Wilkinson, Ed.)and Pergamon Press: Oxford, 1987and Vol. 3, pp 1023–1058.
Pope, M.T; Müller, A. Angew. Chem. Int. Ed. Engl. 1991, 30, 34.
Pope, M.T. Progr. Inorg. Chem. 1991, 39, 181.
Krebs, B; Klein, R. In: Polyoxometalates -From Platonic Solids to Anti-Retroviral Activity (M.T. Pope and A. Müller, Eds.); Kluwer Acad. Publ.: Dordrecht, 1993, pp 41–57.
Krebs, B; Paulat-Böschen, I. Acta Crystallogr. 1982, B38, 1710.
Krebs, B; Stiller, S; Tytko, K.H; Mehmke, J. Eur. J. Solid State Inorg. Chem. 1991, 28, 883.
Krebs, B; Lettmann, B; Pohlmann, H; Fröhlich, R. Z. Kristallogr. 1991, 196, 231
Holmes, R.R; Swamy, K.C.K; Schmid, C.G; Day, R.O. J. Am. Chem. Soc. 1988, 110,7060
Liu, B; Ku, Y; Wang, M; Wang, B; Zheng, P. J. Chem. Soc., Chem. Comm. 1989, 651
Sasaki, Y; Imoto, H; Nagano, O. Bull. Chem. Soc. Jpn. 1984, 57, 1417
Krebs, B; Lettmann, B; Pohlmann, H. Z. Kristallogr. 1989, 186, 233
Matsumoto, K.Y. Bull. Chem. Soc. Jpn. 1979, 52, 3284
Barkigia, K.M; Rajkovic-Blazer, L.M; Pope, M.T; Prince, E; Quicksall, C.O. Inorg. Chem. 1980, 7P,2531
Day, V.W; Fredrich, M.F; Klemperer, W.G; Liu, R.-S., J. Am. Chem. Soc. 1979, 101, 491
Krebs, B; Pohlmann, H. to be published
Wasfí, S.H; Pope, M.T; Barkigia, K; Butcher, R; Quicksall, C.O. J. Am. Chem. Soc. 1978, 100, 7786
Alizadeh, M.H; Harmalker, S.P; Jeannin, Y; Martin-Frère, J; Pope, M.T., J. Am. Chem. Soc. 1985, 107, 2662
Robert, F; Leyrie, M; Hervé, G; Tézé, A; Jeannin, Y. Inorg. Chem. 1980, 19, 1746
Contant, R; Tézé, A. Inorg. Chew. 1985, 24, 4610
Jeannin, Y; Martin-Frère, J. Inorg. Chem. 1979, 18, 3010
Jansen, R.J.J; van Veldhuizen, H.M; Schwegler, M.A; van Bekkum, H. Rec. Trav. Chim. Pays-Bas 1994, 113, 115.
Hill, C.L; Kim, G.-S; Prosser-McCartha, C.M; Judd, D. In: Polyoxometalates -From Platonic Solids to Anti-Retroviral Activity (M.T. Pope and A. Müller, Eds.); Kluwer Acad. Publ.: Dordrecht, 1993, pp 359–371
Yamase, T.ibid., pp 337–358
Blasecki, J.W. ibid, pp 373–385
Clayette, P; Dormont, D. ibid., pp 387–400
Crans, D.C. ibid., pp 401–408.
Yamase, T; Fujita, H; Fukushima, K. Inorg. Chim. Acta 1988, 151, 15.
Inouye, T; Tokutake, Y; Yoshida, Y; Yamamoto, A; Yamase, T; Nakamura, S. Chem. Pharm. Bull. 1991, 39, 1638.
Fukuma, M; Seto, Y; Yamase, T. Antiviral Res. 1991, 16, 327.
Take, Y; Tokutake, Y; Inouye, Y; Yoshida, T; Yamamoto, A; Yamase, T; Nakamura, S. Antiviral Res. 1991, 15, 113.
(a) Jasmin, C; Raybaud, N; Chermann, J.C; Haapala, D; Sinoussi, F; Boy-Loustau, C; Bonissol, C; Kona, P; Raynaud, M. Biomedicine 1973, 18, 319
Jasmin, C; Chermann, J.C; Hervé, G; Tézé, A; Souchay, P; Boy-Loustau, C; Raybaud, N; Sinoussi, F; Raynaud, M. J. Natl. Cancer Inst. 1974, 53, 469
Larnicol, N; Augery, Y; Le Bousse-Kerdiles, C; Degiorgis, V; Chermann, J.C; Tézé, A., Jasmin, C. J. Gen. Virol. 1981, 55, 17.
Vittecoq, D; Woerle, R; Barre-Sinoussi, F; Chermann, J.C. Biomed. Pharmacother. 1988, 42, 35.
Rozenbaum, W; Dormont, D; Spire, B; Vilmer, E; Gentilini, M; Griscelli, C; Montagnier, L; Barre-Sinoussi, F; Chermann, J.C. Lancet 1985, 450.
Hill, C.L; Weeks, M; Schinazi, R.F. J. Med. Chem. 1990, 33, 2767.
Balzarini, J; Mitsuya, H; De Clercq, E; Broder, S. Int. J. Cancer 1986, 37, 451.
Moskovitz, B.L; the HPA-23 cooperative study group. Antimicrob. Agents Chemother. 1988, 32, 1300.
Tomita, K; Yamase, T; Shishido, K. Inorg. Chim. Acta 1989, 157, 167.
Raynaud, M; Chermann, J.C; Plata, F; Jasmin, C; Mathé, G. C. R. Acad. Sci. Paris, 1971, 272, 347.
Burgard, M; Sansonetti, P; Vittecoq, D; Descamps, P; Guetard, D; Herson, S; Rozenbaum, W; Rouzioux, C. AIDS 1989, 3, 665.
Schinazi, R.F; Hill, C.L. 26th ICAAC, New Orleans, La; Abstract 2; Dagani, R. Chem. Engng. News 1986, 64, 7.
Hill, C; Weeks, M; Hartnup, M; Sommadossi, J.-P; Schinazi, R. Ann. N. Y. Acad. Sci. 1990, 616, 528.
Hill, C.L; Hartnup, M; Faraj, M; Weeks, M; Prosser-McCartha, C.M; Brown, R.B; Schinazi, R.F; Sommadossi, J.-P. In: Advances in Chemotherapy of AIDS, Pharmacology and Therapeutics (R. Diasio, J.-P. Sommadossi, Eds.); Pergamon Press, New York, 1990, pp 331 ff.
Inouye, Y; Take, Y; Tokutake, Y; Yoshida, Y; Yamamoto, A; Yamase, T; Nakamura, S. Chem. Pharm. Bull. 1990, 38, 285.
Inouye, Y; Tokutake, Y; Kunihara, J; Yoshida, T; Yamase, T; Nakata, A; Nakamura, S. Chem. Pharm. Bull. 1992, 40, 805.
Weeks, M.S; Hill, C.L; Schinazi, R.F. J. Med. Chem. 1992, 35, 1216.
Schinazi, R.F; Mead, J.R; Feorino, P.M. AIDS Resarch and Human Retro-viruses 1992, 8, 963.
Kim, G.-S; Judd, D.A; Hill, C.L; Schinazi, R.F. J. Med. Chem. 1994, 37, 816.
Ni, L; Boudinot, F.D; Boudinot, S.G; Henson, G.W; Bossard, G.E; Martellucci, S.A; Ash, P.W; Flicker, S.P; Darkes, M.C; Theobald, B.R.C; Hill, C.L; Schinazi, R.F. Antimicrob. Agents Chemother. 1994, 38, 504.
I.c.. [22(a)], ref. 56.
Werner, G.H; Jasmin, C; Chermann, J.C. J. Gen. Virol. 1976, 31, 59.
Kimberlin, R.H; Walker, C.A. Arch. Vir. 1983, 78, 9.
Kimberlin, R.H; Walker, C.;A.AAC 1986, 30, 409.
Pepin, M; Blancou, J. Arch. Vir. 1985, 83, 327.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1995 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Krebs, B. (1995). Novel Transition Metal Heteropolymetalates and Derivatives: Structural Chemistry, Biological and Catalytic Relevance. In: Kessissoglou, D.P. (eds) Bioinorganic Chemistry. NATO ASI Series, vol 459. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0255-1_27
Download citation
DOI: https://doi.org/10.1007/978-94-011-0255-1_27
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-4113-3
Online ISBN: 978-94-011-0255-1
eBook Packages: Springer Book Archive