Abstract
There is a reasonably close analogy between the ring vibrations of benzene and those of pyridine and quinoline, but there are considerable differences in the hydrogen deformation vibrations. However, the out-of-plane hydrogen deformation vibrations appear to be like those of benzene compounds containing an additional substituent. An α-mono-substituted pyridine, therefore, behaves like an ortho-di-substituted aromatic compound in this respect. Substituted pyridines have been extensively studied in both the Raman and infra-red and correlations are now available which enable the substitution pattern to be recognised. Some more limited data are available on the diazines, pyrazine and pyridazines.
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Bellamy, L.J. (1975). Heterocyclic Aromatic Compounds. In: The Infra-red Spectra of Complex Molecules. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-6017-9_16
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