Adsorption isotherms of 4He on Grafoil coated with a monolayer of neon were made for the temperature range of 2–10 K and in the pressure range of 0.10–15.00 Torr, using a standard volumetric method. From these isotherms the isosteric heats of adsorption were calculated as a function of coverage. The binding energy of 4He on Ne was obtained from the isosteric heat for V → 0, yielding a value of 39.4 K. The differential molar entropy and the internal molar energy were calculated as a function of coverage. A comparison of monolayer coverage obtained by analyzing different procedures is presented. Whenever possible the results are compared with theoretical evaluations and previous experimental data.
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References
E. Lerner and J. G. Daunt, J. Low. Temp. Phys. 10, 299 (1973).
R. L. Elgin and D. L. Goodstein, Phys. Rev. A 9, 2657 (1974).
G. J. Goellner, J. G. Daunt, and E. Lerner, J. Low Temp. Phys. 21, 347 (1975).
J. G. Daunt, S. G. Hegde, and E. Lerner, J. Low Temp. Phys. 36, 567 (1979).
M. Bienfait, J. G. Dash, and J. Stoltenberg, Phys. Rev. 21, 2765 (1980).
M. Bretz et al., Phys. Rev. A 8, 1589 (1973).
S. V. Hering, S. W. Van Sciver, and O. E. Vilches, J. Low Temp. Phys. 25, 793 (1976).
S. B. Crary, PhD Thesis, University of Washington (1978), unpublished.
S. W. Van Sciver, Phys. Rev. B 18, 277 (1978).
C. M. Koutsogeorgis and J. G. Daunt, J. Phys. (Paris) 39, C6–308 (1978).
P. Wennerstrom et al., J. Low Temp. Phys. 33, 79 (1978).
O. Ferreira, PhD Thesis, Universidade Federal de Campinas (1979), unpublished.
M. J. Tejwani, O. Ferreira, and O. E. Vilches, Phys. Rev. Lett. 44, 152 (1980).
S. E. Polanco and M. Bretz, Phys. Rev. B 17, 151 (1978).
S. W. Van Sciver and O. E. Vilches, Phys. Rev. B 18, 285 (1978).
J. G. Dash, Phys. Reports, Phys. Lett. C 38C, 177 (1978).
J. G. Dash, Films on Solid Surfaces (Academic Press, New York, 1975).
M. Chester et al., J. Phys. C 7, 1949 (1974).
E. Lerner and F. Hanono, J. Low Temp. Phys. 35, 363 (1979).
T. R. Roberts and S. G. Sydoriak, Phys. Rev. 102, 304 (1956).
D. E. Hagen et al., in Proc. of II Intern. Symp. on Adsorption-Desorption Phenomena (Academic Press, New York, 1971).
A. D. Novaco and F. J. Milford, Phys. Rev. A 5, 783 (1972).
A. D. Novaco, Phys. Rev. B 15, 5217 (1977).
A. D. Novaco, Phys. Rev. A 7, 165 (1973).
T. L. Hill, P. H. Emmett, and L. G. Joyner, J. Am. Chem. Soc. 73, 5102 (1950).
A. A. Antoniou, J. Chem. Phys. 62, 779 (1975).
D. M. Young and A. D. Crowell, Physical Adsorption of Gases (Butterworths, London, 1962).
J. G. Daunt and E. Lerner, J. Low Temp. Phys. 8, 79 (1972).
B. K. Oh and S. K. Kim, J. Chem. Phys. 61, 1808 (1974).
B. K. Oh and S. K. Kim, J. Chem. Phys. 67, 3427 (1977).
J. G. Daunt, S. G. Hegde, S. P. Tsui, and E. Lerner, to be published.
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Work supported by FINEP, CNPq, and CEPG. Part of the Cooperative Program UFRJ/Stevens Institute of Technology, sponsored by CNPq/NSF International Program.
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Hanono, F., Lerner, E. Adsorption of 4He on neon-coated exfoliated graphite. J Low Temp Phys 41, 629–638 (1980). https://doi.org/10.1007/BF00114369
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DOI: https://doi.org/10.1007/BF00114369