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Oxo-tricyano complexes of molybdenum(IV) and tungsten(IV) with bidentate Schiff bases

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The reaction of [M(CN)4O(OH2)]2− (M = Mo or W) with 2-acetylpyridine and methyl-or butyl-amine in a water-MeOH mixture gave [M(CN)3O(L-L)]- (L-L= Schiff base ligand), isolated as [AsPh4]+ salts. The complexes have been characterized by elemental analysis, and electronic, i.r. and1H-n.m.r. spectroscopy. The Schiff base ligands complex in a bidentate manner through the two nitrogen atoms giving mixed-ligand compounds similarly to 2,2′-bipyridyl or 1,10-phenanthroline.

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Authors and Affiliations

  1. Department of Chemistry, Leicester University, University Road, LE1 7RH, Leicester, UK

    Beata Burda, John Burgess & Simon A. Parsons

  2. Faculty of Chemistry, Jagiellonian University, R. Ingardena 3, 30-060, Kraków, Poland

    Alina Samotus & Janusz Szklarzewicz

Authors
  1. Beata Burda
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  2. John Burgess
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  3. Simon A. Parsons
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  4. Alina Samotus
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  5. Janusz Szklarzewicz
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On leave from the Faculty of Chemistry, Jagiellonian University, Kraków.

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Burda, B., Burgess, J., Parsons, S.A. et al. Oxo-tricyano complexes of molybdenum(IV) and tungsten(IV) with bidentate Schiff bases. Transition Met Chem 20, 291–294 (1995). https://doi.org/10.1007/BF00143495

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  • DOI: https://doi.org/10.1007/BF00143495

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