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Polymer electrolytes

The route towards solid polymer electrolytes with stable electrochemical performances upon long term storage

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Summary

The room temperature conductivity of lithium salts dissolved in polyethylene oxide, proposed as polymer electrolytes, is shown to decrease drastically upon storage. The crystallization process, which is responsible for that ageing, can be blocked, if two further components are added : an elastomer copolymer butadiene-acrylonitrile and a macromer of polyoxyethylene. In addition, a crosslinking process must be carried out.

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References

  1. M.B. ARMAND, J.M. CHABAGNO and M.J. DUCLOT — Second International Meeting on Solid Electrolytes (extended abstracts) St Andrews (1978) (Scotland)

  2. P.V. WRIGHT,Br. Polym. J., 7, 319 (1975)

    Article  CAS  Google Scholar 

  3. J.M. PARKER, P.V. WRIGHT, C.C. LEE,Polymer, 22 1305 (1981)

    Article  CAS  Google Scholar 

  4. C.C. LEE, P.V. WRIGHT, Polymer, 23 681 (1982)

    Article  CAS  Google Scholar 

  5. D.R. PAYNE, P.V. WRIGHT, Polymer, 23 690 (1982)

    Article  CAS  Google Scholar 

  6. B.L. PAPKE, M.A. RATNER, D.F. SHRIVER, J. Phys. Chem. Sol., 42 493 (1982) and J. Electrochem. Soc., 129 1694 (1982)

    Article  Google Scholar 

  7. D.F. SHRIVER, B.L. PAPKE, M.A. RATNER, R. DUPON, T. WRONG and M. BRODWIN, Solid State Ionics, 5 83 (1981)

    Article  CAS  Google Scholar 

  8. R. DUPON, B.L. PAPKE, M.A. RATNER, D.H. WHITMORE and D.F. SHRIVER, J. Am. Chem. Soc., 104 6247 (1982)

    Article  CAS  Google Scholar 

  9. J.E. WESTON and B.C.H. STEELE, Solid State Ionics, 7 75 (1982)

    Article  CAS  Google Scholar 

  10. P.R. SORENSEN and T. JACOBSEN, Electrochim. Acta, 27 1671 (1982)

    Article  Google Scholar 

  11. C. BERTHIER, W. GORECKY, M. MINIER, M. ARMAND, M. CHABAGNO and P. RIGAUD, Solid State Ionics, 11 91 (1983) and J. Chim. Phys., 45 739 (1984)

    Article  CAS  Google Scholar 

  12. A. KILLIS, J.F. LE NEST and H. CHERADAME, Makromol. Chem. Rapid Comm., 1 595 (1980)

    Article  CAS  Google Scholar 

  13. M. WATANABE, M. RIKUKAWA, K. SANUI, N. OGATA, H. KATO, T. KOBAYASHI and Z. OHTAKI, Macromolecules, 17, 2902, 2908 (1984)

    Article  CAS  Google Scholar 

  14. D.J. BANNISTER, G.R. DAVIES, J.M. WARD and J.E. Mc YNTYRE, Polymer, 25 1291, 1600 (1984)

    Article  CAS  Google Scholar 

  15. W.Y. KU and J. SMID, J. Am. Chem. Soc., 106, 3790 (1984) and Makromol.Chem. Rapid. Comm., 5 173 (1984)

    Article  Google Scholar 

  16. D.W. XIA and J. SMID, J. Polym. Sci. Polym. Lett. Ed., 22 617 (1984)

    Article  CAS  Google Scholar 

  17. A. LE MEHAUTE et al. Europ. Patent 0078505

  18. A. REVILLON, T. HAMAIDE, Polym. Bull., 6 235 (1982)

    CAS  Google Scholar 

  19. T. HAMAIDE, A. REVILLON and A. GUYOT, Europ. Polym. J., 20 855 (1984)

    Article  CAS  Google Scholar 

  20. A. LE MEHAUTE, G. CREPY, G. MARCELLIN, T. HAMAIDE and A. GUYOT (Submitted to Macrcmolecules)

  21. A. LE MEHAUTE, Plenary Conference on “Solid State Electrolyte” Riso meeting (september 1985)

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Authors and Affiliations

  1. CGE, Laboratoire de Marcoussis, F-91460, Marcoussis, France

    Alain Le Mehaute, Gilles Crepy & Georges Marcellin

  2. CNRS, Laboratoire des Matériaux Organiques, BP 24, F-69390, Lyon Vernaison, France

    Thierry Hamaide & Alain Guyot

Authors
  1. Alain Le Mehaute
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  2. Gilles Crepy
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  3. Georges Marcellin
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  4. Thierry Hamaide
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  5. Alain Guyot
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Le Mehaute, A., Crepy, G., Marcellin, G. et al. Polymer electrolytes. Polymer Bulletin 14, 233–237 (1985). https://doi.org/10.1007/BF00254943

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  • DOI: https://doi.org/10.1007/BF00254943

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