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Processes occurring during the induction period of inhibited oxidation of polyethylene

I. Inhibitor: 2,2'-methylene-bis (4-methyl-6-tert.butylphenol)

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Summary

The kinetics of oxygen consumption during the induction period of oxidation of high density polyethylene was studied in the presence of inhibitor 2,2'-methylene-bis(4-methyl-6-tert.butylphenol) within the range 180–220° C. The oxygen consumption curves are complicated, the initial and maximum rates of oxygen consumption pass through minimum with increasing inhibitor concentration. The molecular weight distribution narrows in the course of inhibited oxidation.

Analysis of the regularities found enabled us to distinguish the rates of oxygen consumption by the polymer and by the inhibitor.

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References

  1. Yu.A. Shlyapnikov, V.B. Miller, E.S. Torsueva, Izvestiya Akad. Nauk SSR, 1961, p. 1966,

  2. Yu.A. Shlyapnikov, Uspekhi Khimii, 50, 1105 (1981).

    Google Scholar 

  3. L.G. Angert, A.S. Kuzminskii, International Symposium on Macromolecular Chemistry, Moscow, 1960, Section III, p. 423,

  4. N.K. Tyuleneva, S.G. Kiryushkin, Yu.A. Shlyapnikov, Dokl. Akad. Nauk SSSR, 279, 145 (1984).

    Google Scholar 

  5. Yu.A. Shlyapnikov, T.A. Bogaevskaya, E.S. Torsueva, N.K.Tyuleneva, Europ.Polymer J., 18, 9 (1982).

    Google Scholar 

  6. T. A. Bogaevskaya, N. K. Tyuleneva, Yu.A. Shlyapnikov, Vysokomolek. Soedin., A23, 181 (1981).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, USSR Academy of Sciences, SU-117334, Moscow, USSR

    Yu. A. Shlyapnikov, S. G. Kiryushkln & N. K. Tyuleneva

  2. Central Research Institute for Chemistry, Hungarian Academy of Sciences, Pf. 17, H-1525, Budapest, Hungary

    M. Iring & Zs. Fodor

Authors
  1. Yu. A. Shlyapnikov
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  2. S. G. Kiryushkln
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  3. N. K. Tyuleneva
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  4. M. Iring
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  5. Zs. Fodor
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Shlyapnikov, Y.A., Kiryushkln, S.G., Tyuleneva, N.K. et al. Processes occurring during the induction period of inhibited oxidation of polyethylene. Polymer Bulletin 19, 449–455 (1988). https://doi.org/10.1007/BF00263913

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  • DOI: https://doi.org/10.1007/BF00263913

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