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Intramolecular charge transfer complexes

19. Copolymers having as acceptor structural units 3,5-dinitrobenzoic acid derivatives with different distances from the main chain

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Summary

Increasing the distance between the acceptor group and the double bond for a series of monomers baaed on 3,5-dinitrobenzoic acid, the homopolymerization tendency is decreased. This permits the evidence of complex participation in copolymerization with the donor monomer N-(2-hydroxyethyl)carbazolyl methacrylate. The intramolecular complexation degree depends on the distance between the complexing group and the main chain and also on the side chain flexibility.

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References

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Authors and Affiliations

  1. “Petru Poni” Institute of Macromolecular Chemistry, 6600, Jassy, Romania

    Virgil Percec, Almeria Natansohn & Cristofor I. Simionescu

Authors
  1. Virgil Percec
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  2. Almeria Natansohn
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  3. Cristofor I. Simionescu
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Percec, V., Natansohn, A. & Simionescu, C.I. Intramolecular charge transfer complexes. Polymer Bulletin 5, 239–245 (1981). https://doi.org/10.1007/BF00265171

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  • DOI: https://doi.org/10.1007/BF00265171

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