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Silica-grafted polyisobutylene and butyl rubber

I. Synthesis and characterization of silica-grafted polyisobutylene

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Summary

Silica surfaces have been modified by reaction with ClSi(CH3)2CH2-CH2-C6H4CH2Cl (I) and the solids were used in conjunction with Et2AlCl to initiate the surface-graft polymerization of isobutylene. Experimental conditions have been defined to obtain respectable grafting rates, grafting ratios and grafting efficiencies.

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References

  1. HAIR M.L. and HERTL W.: J. Phys. Chem. 73 (7), 2372 (1969)

    Google Scholar 

  2. KENNEDY J.P., Ed. : J. Appl. Polym. Sci., Appl. Polym. Symp. 30 (1977)

  3. KENNEDY J.P. and DAVIDSON D.L.: J. Appl. Polym. Sci., Appl. Polym. Symp. 30, 13 (1977)

    Google Scholar 

  4. KENNEDY J.P. and NAKAO M.: J. Appl. Polym. Sci., Appl. Polym. Symp. 30, 73 (1977)

    Google Scholar 

  5. KRIGBAUM W.R. and FLORY P.J.: J. Am. Chem. Soc. 75, 1775 (1953)

    Google Scholar 

  6. LUKEVICS E., BELYAKOVA Z.V., POMERANTSEVA M.G. and VORONKOV M.G.: J. Organometal. Chem. Library 5, 1 (1977)

    Google Scholar 

  7. VIDAL A., DONNET J.B. and KENNEDY J.P.: J. Polymer Sci., Polymer Letters Ed. 15 (10) 585 (1977)

    Google Scholar 

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Authors and Affiliations

  1. Centre de Recherches sur la Physico-Chimie des Surfaces Solides, 68200, Mulhouse, France

    A. Vidal

  2. Laboratoire des Matériaux Organiques, 69626, Villeurbanne, France

    A. Guyot

  3. Institute of Polymer Science, University of Akron, 44325, Akron, Ohio, USA

    J. P. Kennedy

Authors
  1. A. Vidal
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  2. A. Guyot
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  3. J. P. Kennedy
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Vidal, A., Guyot, A. & Kennedy, J.P. Silica-grafted polyisobutylene and butyl rubber. Polymer Bulletin 2, 315–320 (1980). https://doi.org/10.1007/BF00266707

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  • DOI: https://doi.org/10.1007/BF00266707

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