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1H-NMR-spin-spin relaxation in cross-linked SBR with and without carbon black filling

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Summary

For the first time 1H-NMR-spin-spin relaxation curves of a chemically crosslinked statistical copolymer of styrene and butadiene (SBR) with and without carbon black filling are interpreted in terms of a dynamical model which includes two correlation times typical for flexible polymers and which makes use of common phantom network properties. The residual second moment of the magnetic dipolar interaction of spin pairs in network chains gives average molecular masses Mc for unfilled SBR and SBR which is filled with carbon black. All the parameters of the model used are selfconsistent and in good accordance with the results of stress-strain experiments.

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Authors and Affiliations

  1. Department of Physics, Technical University ≪Carl Schorlemmer≫ Leuna-Merseburg, DDR-4200, Merseburg, German Democratic Republic

    G. Simon, B. Götschmann & H. Schneider

  2. Kombinat Chemische Werke BUNA, DDR-4212, Schkopau, German Democratic Republic

    D. Matzen

Authors
  1. G. Simon
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  2. B. Götschmann
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  3. D. Matzen
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  4. H. Schneider
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Simon, G., Götschmann, B., Matzen, D. et al. 1H-NMR-spin-spin relaxation in cross-linked SBR with and without carbon black filling. Polymer Bulletin 21, 475–482 (1989). https://doi.org/10.1007/BF00271970

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  • DOI: https://doi.org/10.1007/BF00271970

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