Summary
Iron-containing aromatic copolyesters were synthesized from 1,1′-bis-(chlorocarbonyl)ferrocene, terephthaloyl chloride, isophthaloyl chloride and methylhydroquinone. The copolymers obtained were characterized for their liquid crystalline properties by a variety of methods, and all of the copolyesters synthesized were nematic.
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References
B. Wunderlich and J. Grebowicz, Adv. Polym. Sci., 60/61, 1 (1984).
J. L. White, J. Appl. Polym. Sci., Appl. Polym. Symp., 401, 3 (1985).
W. J. Jackson, J. Appl. Polym. Sci., Appl. Polym. Symp., 41, 25 (1985).
R. W. Lenz, J.-I. Jin and C. Ober, Adv. Polym. Sci., 59, 103 (1984).
P. J. Graham, R. V. Lindsay, G. W. Parshall, M. L. Peterson and G. M. Whitman, J. Am. Chem. Soc., 79, 3416 (1957).
L. Verbit and T. R. Halbert, Mol. Cryst. Liq. Cryst., 30, 209 (1975).
J. Malthete and J. Billard, Mol. Cryst. Liq. Cryst., 34 (Letters), 117 (1976).
J. W. Harwood, Industrial Applications of Organometallic Compounds, Reinhold, New York, 1963.
J. C. Johnson, Jr., Metallocene Technology, Noyes Data Corp., Park Ridge, New Jersey, 1973.
E. W. Neuse, J. R. Woodhouse, G. Montaudo and C. Puglis, Appl. Organomet. Chem., 2, 53 (1988); see also references cited therein.
F. W. Knobloch and W. H. Rauscher, J. Polym. Sci., 54, 651 (1961).
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Singh, P., Rausch, M.D. & Lenz, R.W. Ferrocene containing liquid crystalline copolyesters. Polymer Bulletin 22, 247–252 (1989). https://doi.org/10.1007/BF00282848
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DOI: https://doi.org/10.1007/BF00282848