Summary
2,6-Di-tert-butyl-4-methylpyridine (DBMP) effectively discriminates between the two major initiation mechanisms encountered in cationic polymerisation. Whenever a protonic acid is involved in the formation of chain carriers, directly or through cocatalysis, addition of equivalent amounts of DBMP inhibits the process. If however direct electrophilic addition of a Lewis acid to the monomer is the source of active species, the hindered base cannot intervene to alter its course. When both pathways are operative DBMP only quenches the former and provides a means of assessing the relative importance of each. Examples are given of the three situations. The simplicity of the method is emphasised.
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GANDINI, A. and CHERADAME, H.: Adv.Polym.Sci. 34/35, 93 (1980)
KUBISA, P. and PENCZEK, S.: Cationic Polymerisation. In: Encyclopedia of Polymer Science and Technology, Suppl.Vol.2. New York: Interscience 1977, p.161
COLLOMB, J., MORIN, B., GANDINI, A. and CHERADAME, H.: Europ. Polym. J., in press
COLLOMB, J., GANDINI, A. and CHERADAME, H.: Makromol.Chem., Rapid Comm., in press
CHERADAME, H. and GANDINI, A,:Prep.5th Int.Symp.Cationic Polym.Kyoto, 1980, p.102
BROWN,H.C. and KANNER,B.:J.Am.Chem.Soc.75,3865 (1953)
BROWN, H.C. and KANNER,B.:J.Am.Chem.Soc.88,986 (1966)
ANDERSON,A.G. and STANG,P.J.:J.Org.Chem. 41,3034 (1976)
FORBUS,T.R.Jr. and MARTIN,J.C.:J.Org.Chem. 44, 313 (1979)
LONGWORTH,W.R.,PANTON,C.J.and PLESCH,P.H.:J.Chem.Soc.1965,5579
BOURNE-BRANCHU.R.et al:Bull.Soc.Chim.France 1976, 1349
KENNEDY,J.P. and CHOU,R.T.:Polym.Prepr.20 (2),306 (1979)
MASLINSKA-SOLICH,J.,CHMELIR,M. and MAREK,M.: Coll.Czech.Chem.Comm. 34, 2611 (1969)
DI MAINA,M. et al: Makromol.Chem.178,2223 (1977)
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We wish to thank the Direction des Recherches, Etudes et Techniques for financial support.
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Moulis, J.M., Collomb, J., Gandini, A. et al. The use of 2,6-Di-tert-butyl-4-methylpyridine to distinguish between different modes of initiation in cationic polymerisation. Polymer Bulletin 3, 197–202 (1980). https://doi.org/10.1007/BF00291957
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DOI: https://doi.org/10.1007/BF00291957