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Effect of 2-Chloro-1,3,2-dioxaphospholane on the radical polymerisation of acrylonitrile, styrene and methyl methacrylate

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Abstract

The effect of 2-Chloro-1,3,2-dioxaphospholane on the AIBN initiated polymerisation of acrylo — nitrile , methyl methacrylate and styrene was investigated kinetically in benzene at 60 – 80°C. With acrylonitrile normal kinetic orders with respect to monomer and AIBN could be observed with the phospholane behaving as a chain transfer agent. With methyl methacrylate and styrene it was observed that the phospholane causes enhancement of the rates due to concurrent radical and ionic polymerisation besides functioning as a chain transfer agent.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, 600 036, Madras, India

    D. V. P. R. Vara Prasad & V. Mahadevan

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  1. D. V. P. R. Vara Prasad
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  2. V. Mahadevan
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Vara Prasad, D.V.P.R., Mahadevan, V. Effect of 2-Chloro-1,3,2-dioxaphospholane on the radical polymerisation of acrylonitrile, styrene and methyl methacrylate. Polymer Bulletin 3, 241–246 (1980). https://doi.org/10.1007/BF00291964

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  • DOI: https://doi.org/10.1007/BF00291964

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