Abstract
The luminescence associated with residual carbon acceptors in type-I (direct-gap) ultrathin-layer superlattices (UTLS) with well and barrier widths of 22.7<L z<25.2 Å and 11.5<L b<14.0 Å, respectively, is composed two lines reflecting the on-center and on-edge state of the impurities. In these narrow wells the on-center acceptor binding energy increases to 60 meV in agreement with theoretical calculations for GaAs single quantum wells using a valence band offset of 500 meV. While the binding energy of the on-center state does not vary significantly within the studied L z and L b range, the on-edge state shows a strong dependence on the very narrow barrier width. This increase of the acceptor binding energy makes the energy position of the impurity-related luminescence in UTLS very sensitive to the actual barrier height. Investigation of the impurity-related luminescence thus provides a versatile tool to determine the band offset ratio at the heterojunction.
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