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Chromite-bearing spessartites from Kasuga-mura, Japan, and their bearing on possible mantle origin andesite

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Abstract

An unusual association of chromite and hornblende was found in the spessartites of andesite composition, occurring as a dike swarm associated with a Cretaceous granite batholith. The spessartites are largely porphyritic with phenocrysts of either hornblende or augite. One dike, comprising a finegrained spessartite, exhibits distinct chilled selvages of aphanitic facies. The chromites in the fine-grained and augite-spessartites are significantly higher in Cr/ (Cr+Al) than those occurring rarely as inclusions in the phenocrystic hornblendes in the hornblende spessartite, although both are similar in Mg/ (Mg+Fe), Fe2O3, and TiO2. The phenocrystic hornblendes are titaniferous pargasite with high Mg/ (Mg+Fe), and differ in their higher octahedral Al from the groundmass hornblendes including those in the fine-grained spessartite. The crystallization sequence in the phenocrystic hornblende-bearing spessartites is Al-rich chromite, phenocrystic hornblende, and plagioclase without pyroxene, suggesting a high water content in the magma and the start of the crystallization at relatively high pressures. The finegrained spessartite from which the porphyritic spessartites have been derived by fractionation of dominant mafic minerals, has the high Mg-value and Cr content equivalent to those in primitive, undifferentiated basalts, although still andesitic in SiO2 content. Chemically similar magnesian andesites, although uncommon, found in some orogenic calc-alkalic suites may represent a magma composition in equilibrium with mantle peridotite under the condition of high water pressures.

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References

  • Allen, J.C., Boettcher, A.L., Marland, G.: Amphiboles in andesite and basalt: I. stability as a function of P-T-f O 2. Am. Mineral. 60, 1069–1085 (1975)

    Google Scholar 

  • Arndt, N.T., Naldrett, A.J., Pyke, D.R.: Komatiitic and iron-rich tholeiitic lavas of Munro Township, Northeast Ontario. J. Petrol. 18, 319–369 (1977)

    Google Scholar 

  • Ayuso, R.A., Bence, A.E., Taylor, R.S.: Upper Jurassic tholeiitic basalts from DSDP Leg 11. J. Geophys. Res. 81, 4305–4325 (1976)

    Google Scholar 

  • Brown, G.M.: Pyroxenes from the early and middle stages of fractionation of the Skaergaard intrusion, East Greenland. Mineral. Mag. 31, 511–543 (1957)

    Google Scholar 

  • Bryan, W.B., Frey, F.A., Thompson, G.: Oldest Atlantic seafloor. Mesozoic basalts from western North Atlantic margin and eastern North America. Contrib. Mineral. Petrol. 64, 223–242 (1977)

    Article  Google Scholar 

  • Cawthorn, R.G., McCarthy, T.S.: Partitioning of nikel between immiscible picritic liquids. Earth Planet. Sci. Lett. 37, 339–346 (1977)

    Google Scholar 

  • Cawthorn, R.G., O'Hara, M.J.: Amphibole fractionation in calc-alkaline magma genesis. Am. J. Sci. 276, 309–329 (1976)

    Google Scholar 

  • Cole, J.W.: Andesites of the Tongariro volcanic centre, North Island, New Zealand. J. Volcanol. Geothermal Res. 3, 121–153 (1978)

    Article  Google Scholar 

  • Dallwitz, W.B.: Chemical composition and genesis of clinoenstatite-bearing volcanic rocks from Cape Vogel, Papua: a discussion. Proc. 23rd Intern. Geol. Congr. 2, 229–242 (1968)

    Google Scholar 

  • Donaldson, C.H., Brown, R.W., Reid, A.M.: Petrology and chemistry of basalts from the Nazca plate: part 1 — petrography and mineral chemistry. In: Initial Reports of the Deep Sea Drilling Project, Vol. 34, pp. 227–238. Washington, D.C.: U.S. Government Printing Office 1976

    Google Scholar 

  • Eggler, D.H.: Water-saturated and undersaturated melting relations in a Paricutin andesite and an estimate of water content in the natural magma. Contrib. Mineral. Petrol. 34, 261–271 (1972)

    Article  Google Scholar 

  • Eggler, D.H., Burnham, C.W.: Crystallization and fractionation trends in the system andesite-H2O-CO2-O2 at pressures to 10 kb. Geol. Soc. Am. Bull. 84, 2517–2532 (1973)

    Google Scholar 

  • Ewart, A.: Mineralogy and chemistry of modern orogenic lavas — some statistics and implications. Earth Planet. Sci. Lett. 31, 417–432 (1976)

    Article  Google Scholar 

  • Frey, F.A., Bryan, W.B., Thompson, G.: Atlantic ocean floor: geochemistry and petrology of basalts from Legs 2 and 3 of the Deep Sea Drilling Project. J. Geophys. Res. 79, 5507–5527 (1974)

    Google Scholar 

  • Gandy, M.K.: The petrology of the Lower Old Red Sandstone lavas of the eastern Sidlaw Hills, Perthshire, Scotland. J. Petrol. 16, 189–211 (1975)

    Google Scholar 

  • Green, D.H.: Experimental testing of ‘equilibrium’ partial melting of peridotite under water-saturated, high pressure conditions. Can. Mineral. 14, 255–268 (1976)

    Google Scholar 

  • Green, D.H., Ringwood, A.E., Ware, N.G., Hibberson, W.O.: Experimental petrology and petrogenesis of Apollo 14 basalts. Proc. 3rd Lunar Sci. Conf. 1, 197–206 (1972)

    Google Scholar 

  • Gunn, B.M., Mooser, F.: Geochemistry of the volcanics of central Mexico. Bull. Volcanol. 34, 577–616 (1971)

    Google Scholar 

  • Helz, R.T.: Phase relations of basalts in their melting range at P H 2O = 5kb as a function of oxygen fugacity. J. Petrol. 14, 249–302 (1973)

    Google Scholar 

  • Hill, R., Roeder, P.: The crystallization of spinel from basaltic liquid as a function of oxygen fugacity. J. Geol. 82, 709–729 (1974)

    Google Scholar 

  • Hodges, F.N., Papike, J.J.: Petrology of basalts, gabbros and peridotites from DSDP Leg 37. In: Initial Reports of the Deep Sea Drilling Project, Vol. 37, pp. 711–723. Washington, D.C.: U.S. Government Printing Office 1977

    Google Scholar 

  • Irvine, T.N.: Chromian spinel as a petrogenetic indicator. Part 2, Petrologic applications. Can. J. Earth Sci. 4, 71–103 (1967)

    Google Scholar 

  • Jakeš, P., White, A.J.R.: Major and trace element abundances in volcanic rocks of orogenic areas. Geol. Soc. Am. Bull. 83, 29–40 (1972)

    Google Scholar 

  • Kawano, Y., Ueda, Y.: K-A dating on the igneous rocks in Japan (V). Granitic rocks in southwestern Japan (in Japanese with English abstract). J. Japan. Assoc. Mineral. Petrol. Econ. Geol. 56, 191–211 (1966)

    Google Scholar 

  • Kay, R.W.: Aleutian magnesian andesite: melts from subducted Pacific Ocean crust. J. Volcanol. Geothermal Res. 4, 117–132 (1978)

    Article  Google Scholar 

  • Keller, J., Villari, L.: Rhyolitic ignimbrites in the region of Afyon (Central Anatolia). Bull. Volcanol. 36, 342–358 (1972)

    Google Scholar 

  • Kramer, W.: Genese der Lamprophyre im Bereich der Fichtelgebirgisch-Erzgebirgischen Antiklinalzone. Ein geochemisch-petrologischer Beitrag zum Problem der Kruste-Mantel-Beziehungen. Chem. Erde 35, 1–49 (1976)

    Google Scholar 

  • Kuroda, N., Shiraki, K.: Boninite and related rocks of Chichi-jima, Bonin Islands, Japan. Rep. Fac. Sci. Shizuoka Univ. 10, 145–155 (1975)

    Google Scholar 

  • Kushiro, I.: Melting of hydrous upper mantle and possible generation of andesitic magma: an approach from synthetic systems. Earth Planet. Sci. Lett. 22, 294–299 (1974)

    Article  Google Scholar 

  • Leake, B.E.: A catalog of analysed calciferous and subcalciferous amphiboles together with their nomenclature and associated minerals. Geol. Soc. Am. Spec. Pap. 98, pp. 210 (1968)

    Google Scholar 

  • Lewis, J.F.: Mineralogy of the ejected plutonic blocks of the Soufriere Volcano St. Vincent: olivine, pyroxene, amphibole and magnetite paragenesis. Contrib. Mineral. Petrol. 38, 197–220 (1973)

    Google Scholar 

  • Liou, J.G.: Mineralogy and chemistry of glassy basalts, Coastal Range ophiolites, Taiwan. Geol. Soc. Am. Bull. 85, 1–10 (1974)

    Article  Google Scholar 

  • Miyahisa, M., Ishibashi, K., Sasaki, M.: High-magnesia andesite from the Takanawa Peninsula, western Shikoku, Japan (in Japanese with English abstract). Mem. Ehime Univ. Sci. Ser. D 8, 9–13 (1977)

    Google Scholar 

  • Miyashiro, A.: Volcanic rock series in island arcs and active continental margins. Am. J. Sci. 274, 321–355 (1974)

    Google Scholar 

  • Mysen, B., Boettcher, A.L.: Melting of a hydrous mantle: II. geochemistry of crystals and liquids formed by anatexis of mantle peridotite at high pressures and high temperatures as a function of controlled activities of water, hydrogen, and carbon dioxide. J. Petrol. 16, 549–593 (1975)

    Google Scholar 

  • Mysen, B., Kushiro, I., Nicholls, I.A., Ringwood, A.E.: A possible mantle origin for andesitic magmas: discussion of a paper by Nicholls and Ringwood. Earth Planet. Sci. Lett. 21, 221–229 (1974)

    Article  Google Scholar 

  • Nehru, C.E., Wyllie, P.J.: Compositions of glasses from St. Paul's peridotite partially melted at 20 kilobars. J. Geol. 83, 455–471 (1975)

    Google Scholar 

  • Nocholls, I.A.: Petrology of Santorini Volcano, Cyclades, Greece. J. Petrol. 12, 67–119 (1971)

    Google Scholar 

  • Nicholls, I.A., Whitford, D.A.: Primary magmas associated with Quaternary volcanism in the western Sunda arc, Indonesia. In: Volcanism in Australasia (R.W. Johnson, ed.), pp. 79–90. Amsterdam: Elsevier 1976

    Google Scholar 

  • Noble, D.C., Bowman, H.R., Hebert, A.J., Silberman, M.L., Heropoulos, C.E., Fabbi, B.P., Hedge, C.E.: Chemical and isotopic constraints on the origin of low-silica latite and andesite from the Andes of central Peru. Geology 3, 501–504 (1975)

    Article  Google Scholar 

  • Ridley, W.I., Rhodes, J.M., Reid, A.M., Jakeš, P., Shih, C., Bass, M.N.: Basalts from Leg 6 of the Deep-Sea Drilling Project. J. Petrol. 15, 140–159 (1974)

    Google Scholar 

  • Ringwood, A.E.: The petrological evolution of island arc systems. J. Geol. Soc. London 130, 183–204 (1974)

    Google Scholar 

  • Sato, H.: Nickel content of basaltic magmas: identification of primary magmas and a measure of the degree of olivine fractionation. Lithos 10, 113–120 (1977)

    Article  Google Scholar 

  • Shiraki, K.: Some aspects of the geochemistry of chromium. J. Earth Sci. Nagoya Univ. 14, 10–55 (1966)

    Google Scholar 

  • Shiraki, K.: Chromium. In: Handbook of Geochemistry (K.H. Wedepohl, ed.) Vo. 2–5. Berlin-Heidelberg-New York: Springer 1978

    Google Scholar 

  • Shiraki, K., Kuroda, N.: The boninite revisited (in Japanese with English abstract). J. Geogr. 86, 174–190 (1977)

    Google Scholar 

  • Shiraki, K., Kuroda, N., Urano, H.: Boninite: evidence for calc-alkalic primary magma (in Japanese with English abstract). Bull. Volcanol. Soc. Japan 22, 257–261 (1977a)

    Google Scholar 

  • Shiraki, K., Yusa, Y., Kuroda, N., Ishioka, K.: Chrome-spinels in some basalts from Guam, Mariana island arc (in Japanese with English abstract). J. Geol. Soc. Japan 83, 49–57 (1977b)

    Google Scholar 

  • Sigurdsson, H.: Spinels in Leg 37 basalts and peridotites: phase chemistry and zoning. In: Initial Reports of the Deep Sea Drilling Project, Vol. 37, pp. 883–891. Washington, D.C.: U.S. Government Printing Office 1977

    Google Scholar 

  • Sigurdsson, H., Schilling, J.C.: Spinels in Mid-Atlantic ridge basalts: chemistry and occurrence. Earth Planet. Sci. Lett. 29, 7–20 (1976)

    Article  Google Scholar 

  • Sigurdsson, H., Shepherd, J.B.: Amphibole-bearing basalts from the submarine volcano Kick'em-Jenny in the Lesser Antilles island arc. Bull. Volcanol. 38, 891–910 (1975)

    Google Scholar 

  • Suzuki, K.: On some unusual bands and veins metasomatically developed in the contact aureole in Kasuga-mura, Gifu-ken (in Japanese with English abstract). J. Geol. Soc. Japan 81, 487–504 (1975)

    Google Scholar 

  • Suzuki, K.: Local equilibrium during the contact metamorphism of siliceous dolomites in Kasuga-mura, Gifu-ken, Japan. Contrib. Mineral. Petrol. 61, 79–89 (1977)

    Article  Google Scholar 

  • Takeshita, H.: Petrological studies on the volcanic rocks of the northern Fossa Magna region, Central Japan. Pac. Geol. 9, 65–95 (1974)

    Google Scholar 

  • Thompson, R.N.: Titanian chromite and chromian titanomagnetite from a Snake River Plain basalt, a terrestrial analogue to lunar spinels. Am. Mineral. 58, 826–830 (1973)

    Google Scholar 

  • Ujike, O.: Petrogenetic significance of normative corundum in calc-alkaline volcanic rock series. J. Jpn. Assoc. Mineral. Petrol. Econ. Geol. 70, 85–92 (1975)

    Google Scholar 

  • Yamaguchi, M.: Petrology of the Otozan flow on Shodo-shima Island, Setouchi Inland Sea, Japan. Mem. Fac. Sci. Kyushu Univ. Ser. D 6, 217–238 (1958)

    Google Scholar 

  • Yamazaki, T., Onuki, H., Tiba, T.: Significance of hornblende gabbroic inclusions in calc-alkali rocks. J. Jpn. Assoc. Mineral. Petrol. Econ. Geol. 55, 87–103 (1966)

    Google Scholar 

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Suzuki, K., Shiraki, K. Chromite-bearing spessartites from Kasuga-mura, Japan, and their bearing on possible mantle origin andesite. Contr. Mineral. and Petrol. 71, 313–322 (1980). https://doi.org/10.1007/BF00371673

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