Abstract
A petrographic and electron microprobe study of an interbedded calc-mica schist from Gassetts, Vermont reveals the complexities of Fe-Mg crystalline solution and gradients in X H2O/X CO2 during regional metamorphism. The common association of microcline+diopside ± zoisite formed from biotite +calcite+quartz may be produced by continuous (Fe-Mg) exchange reactions, despite the implied metastability in the CaO-K2O-MgO-Al2O3-SiO2-H2O-CO2 system. Different assemblages are produced in a reaction zone between carbonate and pelite beds of varying thickness. This illustrates the importance of exhaustion of fluid buffering assemblages due to mineral reactions proceeding on a local scale. Siliceous dolomites at the same metamorphic grade have produced significantly different assemblages to the interlayered carbonatepelite sequence.
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References
Barron, L.M.: Template plotting II. Transformation of fluidbearing reactions and invariant points. Contrib. Mineral. Petrol. 46, 241–247 (1974)
Bowen, N.L.: The evolution of the igneous rocks, 334 p. New York: Dover Pubs. 1928
Burnham, C.W., Holloway, J.R., Davis, N.F.: Thermodynamic properties of water to 1000 °C and 10,000 bars. Geol. Soc. Am. Spec. Papers 132, 96 (1969)
Carmichael, D.M.: Intersecting isograds in the Whetstone Lake Area, Ontario. J. Petrol. 11, 147–181 (1970)
Cermignani, C., Anderson, G.M.: Origin of a diopside-tremolite assemblage near Tweed, Ontario. Can. J. Earth Sci. 10, 84–90 (1973)
Doll, C.G, Cady, W.M., Thompson, J.B., Jr., Billings, M.P.: Centennial geologic map of Vermont: Montpelier, Vermont Geol. Survey (1961)
Epstein, S., Taylor, H.P.: Variation of O18/O16 in minerals and rocks In: Researches in Geochemistry, vol. 2. (Abelson, P.H., ed.), p. 29–62. New York: John Wiley and Sons 1967
Ferry, J.M.: Metamorphism of calcareous sediments in the Waterville-Vassalboro area, Maine. Ph. D. thesis, Harvard University, 1975
Ferry, J.M., Thompson, A.B.: Mineral reactions in impure carbonate rocks and calc-mica schists. (in prep.)
Frey, M., Orville, P.M.: Plagioclase in margarite-bearing rocks, Am. J. Sci. 274, 31–47 (1974)
Greenwood, H.J.: The N-dimensional tie-line problem. Geochim. Cosmochim. Acta 31, 465–490 (1967)
Greenwood, H.J.: Buffering of pore fluids by metamorphic reactions. Am. J. Sci. 275, 573–593 (1975)
Hewitt, D.A.: An experimental and field investigation of the metamorphism of micaceous limestones. Ph.D. thesis, Yale University, 126p. (1970)
Hewitt, D.A.: The metamorphism of micaceous limestones from south-central Connecticut. Am. J. Sci. 273A, 444–469 (1973a)
Hewitt, D.A.: Stability of the assemblage muscovite-calcite-quartz. Am. Mineralogist 58, 785–791 (1973b)
Hewitt, D.A.: Stability of the assemblage phlogopite-calcite-quartz. Am. Mineralogist 60, 391–397 (1975)
Hoschek, G.: Die Reaktion Phlogopite+Calcit+Quarz = Tremolit+Kalifeldspat+H2O+CO2. Contrib. Mineral. Petrol. 39, 231–237 (1973)
Johannes, W., Orville, P.M.: Zur Stabilität der mineral paragenesen Muskovit+Calcit+Quarz, Zoisit + Muskovit + Quarz, Anorthit+K-Feldspat und Anorthit+Calcit. Fortschr. Mineral. 50, 47 (1972)
Lyttle, P.T., Thompson, A.B.: Mica-feldspar phase relations and Fe-Mg cation exchange geothermometry in the Gassetts pelitic schist, Vermont, U.S.A. (in prep.)
Mel'nick, R.P.: Thermodynamic parameters of compressed gases and metamorphic reactions involving water and carbon dioxide. Geochem. Int. 9, 419–426 (1972)
Puhan, D., Johannes, W.: Experimentelle Untersuchung der Reaktion Dolomit + Kalifeldspat + H2O = Phlogopit +Calcit+CO2. Contrib. Mineral. Petrol. 48, 23–31 (1974)
Robie, R.A., Waldbaum, D.R.: Thermodynamic properties of minerals and related substances at 298.15 K (25 °C) and one atmosphere (1.013 bars) pressure and at higher temperatures. U. S. Geol. Surv. Bull. 1259, 256 p. (1968)
Rosenfeld, J.L.: Stress effects around quartz inclusions in almandine and the piezothermometry of coexisting aluminium silicates. Am. J. Sci. 267, 317–351 (1969)
Sheppard, S.M.F., Schwarz, H.P.: Fractionation of carbon and oxygen isotopes and magnesium between coexisting metamorphic calcite and dolomite. Contrib. Mineral. Petrol. 26, 161–198 (1970)
Skippen, G.B.: Experimental data for reactions in siliceous marbles. J. Geol. 79, 451–481 (1971)
Skippen, G.B., Hutcheon, I.: The experimental calibration of continuous reactions in siliceous carbonate rocks. Can. Mineralogist 12, 327–333 (1974)
Slaughter, J., Kerrick, D.M., Wall, V.J.: Experimental and thermodynamic study of equilibria in the system CaO-MgO-SiO2-H2O-CO2. Am. J. Sci. 275, 143–162 (1975)
Storre, B., Nitsch, K.-H.: Die Reaktion 2 Zoisit+1 CO2 =3 Anorthit +1 Calcit+ 1 H2O. Contrib. Mineral. Petrol. 35, 1–10 (1972)
Thompson, A.B.: Calculation of muscovite-paragonite-alkali feldspar phase relations. Contrib. Mineral. Petrol. 44, 173–194 (1974a)
Thompson, A.B.: The instability of feldspar in metamorphism. In: The Feldspars (Mackenzie, W.S., Zussman, J., eds.), p. 645–672. Manchester: Univ. Press, Englang 1974b
Thompson, A.B.: Gibbs energy of aluminous minerals. Contrib. Mineral. Petrol. 48, 123–136 (1974c)
Thompson, A.B.: Calc-silicate diffusion zones between marble and pelitic schist. J. Petrol. 16, 314–346 (1975)
Thompson, A.B.: Mineral reactions in pelitic rocks. Am. J. Sci. (in press)
Thompson, J.B., Jr.: The graphical analysis of mineral assemblages in pelitic schists. Am. Mineralogist 42, 842–858 (1957)
Thompson, P.H.: Mineral zones and isograds in “impure” calcareous rocks, an alternative means of evaluating metamorphic grade. Contrib. Mineral. Petrol. 42, 63–80 (1973)
Trommsdorff, V.: Change in T-X during metamorphism of siliceous dolomitic rocks of the central Alps. Schweiz. Mineral. Petrog. Mitt. 52, 567–570 (1972)
Vidale, R.J.: Metasomatism in a chemical gradient and the formation of calc-silicate bands. Am. J. Sci. 267, 857–874 (1969)
Vidale, R.J., Hewitt, P.A.: “Mobile” components in the formation of calc-silicate bands. Am. Mineralogist 58, 991–997 (1973)
Wones, D.R.: Amphibole-biotite relations. Am. Mineralogist 55, 295–296 (1970)
Zen, E-an.: Gibbs free energy, enthalpy and entropy of ten rockforming minerals: Calculations, discrepancies, implications. Am. Mineralogist 57, 524–553 (1972)
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Thompson, A.B. Mineral reactions in a calc-mica schist from Gassetts, Vermont, U.S.A.. Contr. Mineral. and Petrol. 53, 105–127 (1975). https://doi.org/10.1007/BF00373126
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DOI: https://doi.org/10.1007/BF00373126