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Garnet peridotite from Colorado Plateau ultramafic diatremes: Hydrates, carbonates, and comparative geothermometry

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Abstract

Crystal fragments of pyrope from diatremes of ultramafic microbreccia in the Navajo Province of the Colorado Plateau contain inclusions of olivine, pyroxene, spinel, chlorite, amphibole, chlorapatite, and dolomite. The included suite supports earlier hypotheses that hydrous phases and carbonates were primary parts of some garnet peridotite assemblages in the Plateau lithosphere. Garnets with spinel and orthopyroxene inclusions likely all were sampled at pressures less than 36 kb and perhaps as low as 15–20 kb; no evidence was found for inclusions from greater depths. Temperature estimates are 800°–900° C for garnet-clinopyroxene equilibration, but only 500°–700° C for garnetolivine equilibration. Inherent differences between geothermometry methods account for only part of the discrepancy. Pronounced Fe-Mg zoning in garnet at olivine contacts and the lack of such zoning at clinopyroxene contacts are evidence that the difference in part relates to relative reequilibration rates with cooling. The garnet-olivine temperature estimates may be the best approximations to mantle temperatures before eruption. Our data are compatible both with the hypothesis that the garnet peridotite was emplaced in the mantle by large-scale, horizontal transport in the lithosphere and with the hypothesis that rocks were sampled from Precambrian lithosphere cooled to temperatures like those along a low heat flow geotherm. Discordances between the geothermometers here and in other lherzolite localities may be keys to evaluating tectonic histories of lherzolite masses.

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References

  • Albee AL, Ray L (1970) Correction factors for electron probe microanalysis of silicates, oxides, carbonates, phosphates, and sulfates. Anal Chem 42:1408–1414

    Google Scholar 

  • Allen JE, Balk R (1954) Mineral resources of Fort Defiance and Tohatchi quadrangles, Arizona and New Mexico. N Mex Bur Mines Mineral Res Bull 36:192 p

    Google Scholar 

  • Bence AE, Albee AL (1968) Empirical correction factors for the electron microanalysis of silicates and oxides. J Geol 76:382–403

    Google Scholar 

  • Bird P (1979) Continental delamination and the Colorado Plateau. J Geophys Res 84:7561–7571

    Google Scholar 

  • Boyd FR (1970) Garnet peridotites and the system CaSiO3-MgSiO3Al-2O3. Mineral Soc Am, Spec Pap 3:63–75

    Google Scholar 

  • Boyd FR, Nixon PE (1973) Structure of the upper mantle beneath Lesotho. Carnegie Inst Washington Yearb 72:431–445

    Google Scholar 

  • Boyd FR, McCallister RH (1976) Densities of fertile and sterile garnet peridotites. Geophys Res Lett 3:509–512

    Google Scholar 

  • Buening DK, Buseck PR (1973) Fe-Mg lattice diffusion in olivine. J Geophys Res 78:6852–6862

    Google Scholar 

  • Carter JL (1970) Mineralogy and chemistry of the earth's upper mantle based on the partial fusion-partial crystallization model. Geol Soc Am Bull 81:2021–2034

    Google Scholar 

  • Champion DE, Albee AL, Chodos AA (1975) Reproducibility and operator bias in a computer-controlled system for quantitative electron microprobe analysis. Proc Ann Conf Microbeam Anal Soc 10:55A-E

    Google Scholar 

  • Chapman D, Pollack HN (1977) Regional geotherms and lithospheric thickness. Geology 5:265–268

    Google Scholar 

  • Dawson JB, Smith JV, Delaney JS (1978) Multiple spinel-garnet peridotite transitions in the upper mantle: evidence from a harzburgite xenolith. Nature 273:741–743

    Google Scholar 

  • Delaney JS, Smith JV, Dawson JB, Nixon PH (1979) Manganese thermometer for mantle peridotites. Contrib Mineral Petrol 71:157–169

    Google Scholar 

  • Ehrenberg SN (1978) Petrology of potassic volcanic rocks and ultramafic xenoliths from the Navajo volcanic field, New Mexico and Arizona. Doctoral dissertation, U Calif Los Angeles, 259 p

  • Ehrenberg SN (1979) Garnetiferous ultramafic inclusions in minette from the Navajo volcanic field. In: FR Boyd, HOA Meyer (eds) The Mantle Sample: Inclusions in Kimberlites and Other Volcanics. Proc Sec Int Kimb Conf 2:330–344

  • Ellis DJ, Green DH (1979) An experimental study of the effect of Ca upon garnet-clinopyroxene Fe-Mg exchange equilibria. Contrib Mineral Petrol 71:13–22

    Google Scholar 

  • Ernst WG (1978) Petrochemical study of lherzolitic rocks from the western Alps. J Petrol 19:341–392

    Google Scholar 

  • Evans BW, Trommsdorff V (1978) Petrogenesis of garnet lherzolite, Cima di Gagnone, Lepontine Alps. EPSL 40:333–348

    Google Scholar 

  • Ferguson J, Ellis DJ, England RN (1977) Unique spinel-garnet lherzolite inclusion in kimberlite. Geology 5:278–280

    Google Scholar 

  • Frey FA, Prinz M (1978) Ultramafic inclusions from San Carlos, Arizona: petrologic and geochemical data bearing on their petrogenesis. EPSL 38:129–176

    Google Scholar 

  • Ganguly J (1979) Garnet and clinopyroxene solid solutions and geothermometry based on Fe-Mg distribution coefficient. Geochim Cosmochim Acta 43:1021–1029

    Google Scholar 

  • Helmstaedt H, Doig R (1975) Eclogite nodules from kimberlite pipes of the Colorado Plateau-samples of subducted Franciscan-type oceanic lithosphere. Phys Chem Earth 9:95–111

    Google Scholar 

  • Helmstaedt H, Schulze DJ (1979) Garnet clinopyroxenite-chlorite eclogite transition in a xenolith from Moses Rock: further evidence for metamorphosed ophiolites under the Colorado Plateau. In: Boyd FR, Meyer HOA (eds) The mantle sample: Inclusions in kimberlites and other volcanics. Proc Sec Int Kimb Conf 2:357–365

  • Hunter WC (1979) The Garnet Ridge and Red Mesa kimberlitic diatremes, Colorado Plateau: geology, mineral chemistry, and geothermobarometry. Doctoral dissertation, U Texas Austin, 230 p

  • Hunter WC, Smith D (1979) Chemistry and geothermometry of inclusions in pyrope from Garnet Ridge, AZ and Red Mesa, UT, diatremes, Colorado Plateau. Geol Soc Am Abstr 11:447–448

    Google Scholar 

  • Jenkins DM, Newton RC (1979) Experimental determination of the spinel peridotite to garnet peridotite inversion at 900° C with natural garnet and olivine. Contrib Mineral Petrol 68:407–419

    Google Scholar 

  • Jordan TH (1979) Mineralogies, densities and seismic velocities of garnet lherzolites and their geophysical implications. In FR Boyd, HOA Meyer (eds) The mantle sample: Inclusions in kimberlites and other volcanics Proc Sec Int Kimb Conf 2:1–14

  • Kawasaki T (1979) Thermodynamic analyses on the Fe-Mg exchange equilibrium between olivine and garnet: an application to the estimation of P-T relations of ultramafic rocks. J Japan Assoc Min Pet Econ Geol 74:395–405

    Google Scholar 

  • Kushiro I (1970) Stability of amphibole and phlogopite in the upper mantle. Carnegie Inst Washington Yearb 68:245–247

    Google Scholar 

  • Lasaga AC, Richardson SM, Holland HD (1977) The mathematics of cation diffusion and exchange between silicate minerals during retrograde metamorphism. In: SK Saxena, S Bhattacharji (eds) Energetics of geological processes. New York, Springer-Verlag, pp 353–388

    Google Scholar 

  • Leake BE (1978) Nomenclature of amphiboles. Am Mineral 63:1023–1052

    Google Scholar 

  • Lindsley DH, Dixon SE (1976) Diopside-enstatite equilibria at 850° C to 1,400° C, 5 to 35 kb. Am J Sci 276:1285–1301

    Google Scholar 

  • Malde HE, Thaden RC (1963) Serpentine at Garnet Ridge. US Geol Surv Bull 1103:54–61

    Google Scholar 

  • Mercier J-C C (1976) Single pyroxene geothermometry and geobarometry. Am Mineral 61:603–625

    Google Scholar 

  • McGetchin TR (1968) The Moses Rock dike: Geology, petrology, and mode of emplacement of a kimberlite-bearing breccia dike, San Juan County, Utah. Doctoral dissertation, Calif Inst Tech, 405 p

  • McGetchin TR, Silver LT (1970) Compositional relations in minerals from kimberlite and related rocks in the Moses Rock dike, San Juan County, Utah. Am Mineral 55:1738–1771

    Google Scholar 

  • McGetchin TR, Silver LT (1972) A crustal-upper mantle model for the Colorado Plateau based on observations of crystalline rock fragments in the Moses Rock dike. J Geophys Res 77:7022–7037

    Google Scholar 

  • McGetchin TR, Besancon JR (1973) Carbonate inclusions in mantlederived pyropes. EPSL 18:408–410

    Google Scholar 

  • Mori T, Banno S (1973) Petrology of peridotite and garnet clinopyroxenite of the Mt. Higasi-Akaisi mass, central Sikoku, Japan-subsolidus relations of anhydrous phases. Contrib Mineral Petrol 41:301–323

    Google Scholar 

  • Nixon PH, Boyd FR (1973) Petrogenesis of the granular and sheared ultrabasic nodule suite in kimberlites. In: PH Nixon (ed) Lesotho Kimberlites. Cape Town, Cape and Transvaal Printers Ltd, pp 48–56

    Google Scholar 

  • O'Hara MJ, Richardson SW, Wilson G (1971) Garnet peridotite stability and occurrence in crust and mantle. Contrib Mineral Petrol 32:48–68

    Google Scholar 

  • O'Neill H St C, Wood BJ (1979) An empirical study of Fe-Mg partitioning between olivine and garnet and its calibration as a geothermometer. Contrib Mineral Petrol 70:59–70

    Google Scholar 

  • Padovani ER, Tracy RJ (1978) A pyrope-spinel (alkremite) xenolith from Colorado Plateau kimberlite: first known North American occurrence. Geol Soc Am Abstr 10:466

    Google Scholar 

  • Richey JL (1968) Significance of piezobirefringence around minerals included in pyropes from diatremes, Four Corners area, Arizona. MS thesis, U Calif Los Angeles, 54 p

  • Roden MF, Smith D, McDowell FW (1979) Age and extent of potassic volcanism on the Colorado Plateau. EPSL 43:279–284

    Google Scholar 

  • Roden MF (1981) Origin of coexisting minette and ultramafic breccia, Navajo volcanic field. Submitted for publication. Contrib Mineral Petrol

  • Rosenfeld JL, Chase AB (1961) Pressure and temperature of crystallization from elastic effects around solid inclusions in minerals? Am J Sci 259:519–541

    Google Scholar 

  • Schmitt HH, Swann GA, Smith D (1974) The Buell Park kimberlite pipe, northeastern Arizona. In: TNV Karlstrom, GA Swann, RL Eastwood (eds) Geology of Northern Arizona. Geol Soc Am Rocky Mtn Sect, Flagstaff, pp 672–698

    Google Scholar 

  • Silver LT, McGetchin TR (1978) The nature of the basement beneath the Colorado Plateau and some implications for plateau uplifts. Abstr Confr on Plateau Uplift: Mode and Mechanism, Lunar Planet Inst Contr 329:45–46

    Google Scholar 

  • Smith D, Levy S (1976) Petrology of the Green Knobs diatreme and implications for the upper mantle below the Colorado Plateau. EPSL 29:107–125

    Google Scholar 

  • Smith D (1979) Hydrous minerals and carbonates in peridotite inclusions from the Green Knobs and Buell Park kimberlitic diatremes on the Colorado Plateau. In: FR Boyd, HOA Meyer (eds) The mantle sample: Inclusions in kimberlites and other volcanics. Proc Sec Int Kimb Conf 2:345–356

  • Smith D, Zientek M (1979) Mineral chemistry and zoning in eclogite inclusions from Colorado Plateau diatremes. Contrib Mineral Petrol 69:119–131

    Google Scholar 

  • Smith D, Roden MF (1981) Geothermometry and kinetics in a two-spinel peridotite nodule, Colorado Plateau. (in press) Am Mineral

  • Staudigel H, Schreyer W (1977) The upper thermal stability of clinochlore Mg5Al(AlSi3O10) (OH)8, at 10–35 kb \(P_{H_2 O}\). Contrib Mineral Petrol 61:187–198

    Google Scholar 

  • Switzer GS (1977) Composition of garnet xenocrysts from three kimberlite pipes in Arizona and New Mexico. Smithson. Earth Sci 19:1–21

    Google Scholar 

  • Walker D, Longhi J, Lasaga AC, Stolper EM, Grove TL, Hays JF (1977) Slowly cooled microgabbros 15555 and 15065. Proc Lunar Sci Conf 8:1521–1547

    Google Scholar 

  • Watson KD, Morton DM (1969) Eclogite inclusions in kimberlite pipes at Garnet Ridge, northeastern Arizona. Am Mineral 54:267–285

    Google Scholar 

  • White RW (1966) Ultramafic inclusions in basaltic rocks from Hawaii. Contrib Mineral Petrol 12:245–314

    Google Scholar 

  • Witkind IJ, Thaden RE (1963) Geology and uranium-vanadium deposits of the Monument Valley area, Apache and Navajo Counties, Arizona. US Geol Surv Bull 1103:171 p

    Google Scholar 

  • Wood BJ (1974) The solubility of alumina in orthopyroxene coexisting with garnet. Contrib Mineral Petrol 46:1–15

    Google Scholar 

  • Wood BJ, Nicholls J (1978) The thermodynamic properties of reciprocal solid solutions. Contrib Mineral Petrol 66:389–400

    Google Scholar 

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Hunter, W.C., Smith, D. Garnet peridotite from Colorado Plateau ultramafic diatremes: Hydrates, carbonates, and comparative geothermometry. Contr. Mineral. and Petrol. 76, 312–320 (1981). https://doi.org/10.1007/BF00375458

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