Summary
An approximate method, an empirical one, a semi theoretical one, and the procedure due to Lindsay and Bromley are examined for prediction of thermal conductivity of polar-nonpolar gas mixtures. With a modification of the approximate method we find, by analyzing experimental and calculated results of twelve different systems, that prediction of thermal conductivity is possible with an uncertainty of about 2%. This is important because experimental data on such gas systems are rare. The methods also permit computation of thermal conductivity at moderately high temperatures and for multicomponent mixtures.
Similar content being viewed by others
References
Chapman, S. and T. G. Cowling, The Mathematical Theory of Non-Uniform Gases, Cambridge University Press, London 1952.
Hirschfelder, J. O., J. Chem. Phys. 26 (1957) 282.
Mason, E. A. and L. Monchick, J. Chem. Phys. 36 (1962) 1622.
Saxena, S. C., M. P. Saksena, and R. S. Gambhir, Brit. J. Appl. Phys. 15 (1964) 843.
Hirschfelder, J. O., Sixth International Combustion Symposium, p. 351, Reinhold, New York 1957.
Monchick, L., A. N. G. Pereira, and E. A. Mason, J. Chem. Phys. 42 (1965) 3241.
Saxena, S. C., M. P. Saksena, R. S. Gambhir, and J. M. Gandhi, Physica 31 (1965) 333.
Mason, E. A. and S. C. Saxena, Phys. Fluids 1 (1958) 361.
Saxena, S. C. and J. M. Gandhi, Rev. Modern Phys. 35 (1963) 1022.
Gambhir, R. S. and S. C. Saxena, Mol. Phys. 11 (1966) 233.
Gandhi, J. M. and S. C. Saxena, Mol. Phys. 12 (1967) 57.
Mathur, S., P. K. Tondon, and S. C. Saxena, Mol. Phys., 12 (1967) 569.
Srivastava, B. N. and S. C. Saxena, Proc. Phys. Soc. (London) 70B (1957) 369.
Srivastava, B. N. and S. C. Saxena, J. Chem. Phys. 27 (1957) 583.
Saxena, S. C., Indian J. Phys. 31 (1957) 597; J. Chem. Phys. 25 (1956) 360.
Mason, E. A. and H. von Ubisch, Phys. Fluids 3 (1960) 355.
Lindsay, A. L. and L. A. Bromley, Ind. Eng. Chem. 42 (1950) 1508.
Rothman, A. J. and L. A. Bromley, Ind. Eng. Chem. 47 (1955) 899.
Mathur, S. and S. C. Saxena, Appl. Sci. Res. 17 (1967) 155.
Gupta, G. P. and S. C. Saxena, Defence Sci. J. (India) 16 (1966) 165.
Cowling, T. G., P. Gray, and P. G. Wright, Proc. Roy. Soc. (London) A 276 (1963) 69.
Gruss, H. and H. Schmick, Wiss. Veröffentl. Siemens-Konzern 7 (1928) 202.
Timrot, D. L. and N. B. Vargaftik, Trans. of the Fourth World Power Conference III, p. 1642, ASME, New York 1950.
Vines, R. G. and L. A. Bennett, J. Chem. Phys. 23 (1955) 1587.
Westenberg, A. A. and N. de Haas, Phys. Fluids 6 (1963) 617.
Gray, P. and P. G. Wright, Proc. Roy. Soc. (London) A 263 (1961) 161.
Kornfeld, G. and K. Hilferding, Z. Physik. Chem. Bodenstein Vol. (1931) 792.
Cheung, H., L. A. Bromley, and C. R. Wilke, University of California Radiation Laboratory, report No. 8230 Rev. (1959); see also AIChE J. 8 (1962) 221.
Gambhir, R. S. and S. C. Saxena, Trans. Faraday Soc. 60 (1964) 38.
Saksena, M. P. and S. C. Saxena, Appl. Sci. Res. 17 (1967) 326.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Tondon, P.K., Saxena, S.C. Calculation of thermal conductivity of polar-nonpolar gas mixtures. Appl. Sci. Res. 19, 163–170 (1968). https://doi.org/10.1007/BF00383919
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00383919