Abstract
The Yamuna river is the largest tributary of the Ganges river system. It originates in the Himalayas and flows through a varied geological terrain encompassing a large basin area. Metals Fe, Mn, Pb, Zn, Cu in different chemical fractions of suspended sediments such as exchangeable, carbonates, Fe−Mn oxides, organics and residual fractions were studied. Phosphorus associated with different chemical forms are discussed. The metals are mostly associated with residual fractions in the sediments followed by organics, Fe−Mn oxides, exhangeable and carbonates. Intensive use of chemical fertilizers and pesticides in agriculture in the basin affects the high inorganic phosphorus content in sediments.
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References
Auruda, K. D.: 1983, ‘Physiographic and Anthropogenic Controls of Global and regional Ionic Runoff’, in: Webb, B. W. (ed.), Dissolved Loads of Rivers and Surface Water Quantity/Quality Relationship, Proc. Symp Hamburg, IAHS Publ. No. 141: 31–39.
BalachandA. N. and NairS. M.: 1994, ‘Fractionation of Phosphorus in the Sediment of a Tropical Estuary’, Env. Geol. 23, 284–294.
BernerR. A. and RaoJ. L.: 1994, Phosphorus in Sediments of the Amazon River and Estuary: Implications for Global Flux of Phosphorus to the Sea, Geochim. et Cosmochim. Acta 58(10), 1333–2339.
BostromB., AndersenJ. M., FleischerS. and JanssonM.: 1988, Exchange of Phosphorus Across the Sediment-Water Interface, Hydrobiologia 170, 229–244.
CBPCWP: 1982, The Yamuna Sub-Basin, Central Board of the Prevention and Control of Water Pollution, New Delhi, 114 pp.
DeurerR., ForstnerU. and SchmollG.: 1978, ‘Selective Chemical Extraction of Carbonate Associated Trace Metals in Recent Lacustrine Sediments’, Geochim. et Cosmochim. Acta 42, 425–427.
EnglerR. P., BrannonJ. M., RoseJ. and BighamF.: 1977, ‘A Practical Selective Extraction Procedure for Sediment Characterisation’, in: ChenT. F. (ed.), Chemistry of Marine Sediments. Ann Arbor Sci. Publ, Ann Arbor, Michigan, pp. 163–171.
ErelY and MorganJ. J.: 1991, ‘The Effect of Surface Reactions on the Relative Abundances of Trace Metals in deep-Ocean Water’, Geochim. et Cosmochim. Acta 55, 1807–1813.
Flanagan, F. J.: 1976, ‘Dispersion and Analysis of Eight new USGS Rock Standards, U. S. Geol. Surv. Prof. Pap, 840 pp.
ForstnerU. and WittmannG. T. W.: 1981, Metal Pollution in the Aquatic Environment (2nd edn), Springer-Verlag, Berlin, 486 pp.
FroelichP. N., BenderM. L. and LuedtkeN. A.: 1982, ‘The Marine P Cycles’, J. Sci. 282, 47–51.
GarrelsR. L., MackenzieF. T. and HuntC.: 1975, Chemical Cycles and the Global Environment, William Kauffmann Inc. New York, 206 pp.
GibbsR. J.: 1973, ‘Mechanism of Trace Metal Transport in Rivers’, Science 180, 71–73.
GibbsR. J.: 1977, ‘Transport Phases of Transition Metals in the Amazon and Yukon Rivers’, Geol. Soc. Amer. Bull. 88, 829–843.
HieltjesA. H. M. and LijklemsL.: 1980, ‘Fractionation of Inorganic Phosphorus in Calcareous Sediments’, J. Env. Qual. 9, 405–407.
HosomiM. Okada, and SudoR.: 1982, ‘Release of P from Lake sediments’, Env. Intl. 170, 19–34.
JhaP. K. SubramanianV., SitasawadR. and vanGriekenR.: 1990, ‘Heavy Metals in Sediments of the Yamuna River (A Tributary of the Ganges). India. Sci. Tot. Env. 95, 7–27.
KromM. D. and BernerR. A.: 1981, ‘The Diagenesis of P in a Near Shore Marine Sediment’, Geochim. et Cosmochim. Acta 45, 207–216.
MayerY. and WilliamsJ. D. H.: 1981, ‘Modified Procedure for Determining the Forms of P in Freshwater Sediments’, Tech. Bull.. No. 119, NWRI, Canada, Ontario, 8 pp.
McGlatheryK. J., MarinoR. and HowarthR. W.: 1994, ‘Variable Rates of Phosphate Uptake by Shallow Marine Carbonate Sediments: Mechanisms and Ecological Significance’, Biogeochemistry 25, 127–146.
PettersonK., BostromB. and JacobsenO. S. 1988, Phosphorus in Sediments-Speciation and Analysis, in: PerssonG. and JannssonM. (eds.) Phosphorus in Fresh Water Ecosystems. Developments in Hydrology, Kluwer Academic Publishers, Dordrecht, pp. 91–101.
ProbstJ. L.: 1986, Dissolved and Suspended Matter Transported by the Girou River France. Hydrological Sciences’, J. des Sciences Hydrologiques, 31, 61–79.
RuttenbergK. C.: 1992, ‘Development of a Sequential Extraction Method for Different Forms of P in Marine Sediments’, Limnol. Ocean. 37(7), 1460–1482.
Salomons, W. and Mook, W. G.: 19978, ‘Processes Affecting Trace Metals in Lake Ijssel’, Abs. 10th Int. Cong. on Sedimentology, Jerusalem, pp. 569–570.
ShibuM. P., BalachandA. N. and NambisanP. N. K.: 1990. ‘Trace Metal Speciation in a Tropical Eastuary — significance of Environmental Factors’, Sci. Tot. Env. 97/98, 267–287.
StoneM. and EnglishM. C.: 1993, ‘Geochemical Composition, Phosphorus Speciation and Mass Transport of Fine Grained Sediment to Two Lake Erie Tributaries’, Hydrobiologia 253, 17–29.
SundbyB., GobeiC., SilverbergN. and MucciA.: 1992, ‘The Phosphorus Cycle in Coastal Marine Sediments’, Limnol. Oceano. 37, 1129–1145.
TessierA., CampbellP. G. C. and BissonM.: 1979, ‘Sequential Extraction Procedure for the Speciation of Particulate Trace Metals’, Anal Chem. 51, 844–851.
WarrenL. J.: 1981, ‘Combination of Sediments by Lead, Zinc and Cadmium—a Review’, Env. Poll. Ser. B 2, 410–436.
WarrenL. A. and SimmermannA. P.: 1994, ‘Suspended Particulate Oxides and Organic Matter Interactions in Trace Metal Sorption Reaction in a Small Urban River’, Biogeochemistry 23, 21–34.
YamadaH. and KayamaM.: 1987, ‘Distribution and Dissolution of Several Forms of Phosphorus in Coastal Marine Sediments’, Oceanologica Acta 10, 311–321.
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Chakrapani, G.J., Subramanian, V. Fractionation of heavy metals and phosphorus in suspended sediments of the Yamuna river, India. Environ Monit Assess 43, 117–124 (1996). https://doi.org/10.1007/BF00398602
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DOI: https://doi.org/10.1007/BF00398602