Abstract
Spirocyclic glycolic esters of orthosilicic acid have been obtained by catalytic disproportionation of the corresponding polyesters formed during transesterification of tetraethoxysilane by glycols. The PMR spectra of these compounds were studied and their dipole moments were measured.
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M. G. Voronkov and L. A, Zhagata, ZhOKh, 37, 2764, 1967.
F. Taurke, Ber., 38, 1661, 1905.
A. Rosenheim and O. Sorge, Ber., 53, 932, 1920.
Yu. N. Vol'nov and B. N. Dolgov, ZhOKh, 10, 556, 1940.
L. Holzapfel, Koll. Z., 100, 380, 1942.
D. F. Peppard, W. G. Brown, and W. C. Jonston, J. Amer. Chem. Soc., 68, 73, 1946.
R. Schwarz and W. Kuchen, Z. anorg. allg. Chem., 226, 185, 1953.
H. W. Kohlschütter and G. Jackel, Z. anorg. Chem., 271, 185, 1953.
F. S. Kipping and J. T. Abrams, J. Chem. Soc., 81, 1944.
W. Hahn, Makromol. Chem., 11, 51, 1953.
R. Müller and L. Heinrich, Ber., 94, 2225, 1961.
Siemens-Schuckertwerke A. -G., British patent no. 798163, 1958; C. A., 53, 5205, 1959.
E. Schwarz and W. Kuchen, Z. anorg. allg. Chem., 279, 84, 1955.
H. Staudinger and W. Hahn, West German patent no. 929189, 1955; RZhKh, 72803, 1956.
M. Jaćowić, Z. anorg. Chem., 228, 324, 1956.
M. G. Voronkov, V. P. Davydova, and B. N. Dolgov, Izv. AN SSSR, OKhN, 698, 1958.
V. P. Davydova, M. G. Voronkov, and B. N. Dolgov, Chemistry and Practical Use of Organosilicon Compounds [in Russian], 1, 204, 1958.
V. P. Davydova, Candidate's dissertation [in Russian], Leningrad, 1958.
M. G. Voronkov, Heterolite Reactions of Cleavage of the Siloxane Bond [in Russian], Moscow, 1961.
R. C. Mehrotra and B. C. Pant, J. Indian Chem. Soc., 41, 563, 1964.
R. M. Ismail, Z. Naturforsch., 19b, 873, 1964.
J. J. Zuckerman, J. Chem. Soc., 873, 1961.
R. C. Mehrotra, Pure Appl. Chem., 13, 111, 1966.
Yu. N. Vol'nov and A. Mishelevich, ZhOKh, 13, 213, 1943.
S. D. Radosavljević, M. D. Dragojević, and M. S. Jaćović, Bull. Soc. Chim. Belgrade, 21, 51, 1956.
M. G. Voronkov, Yu. P. Romadan, USSR patent no. 196840, 1967; Byull. izobr., 12, 35, 1967.
NMR Spectra Catalog, Varian Associates, Palo Alto, California, no. 86, 1962.
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For part IX, see [1].
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Voronkov, M.G., Romadan, Y.P., Pestunovich, V.A. et al. Studies in the field of alkoxysilanes. Chem Heterocycl Compd 4, 702–704 (1968). https://doi.org/10.1007/BF00486934
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DOI: https://doi.org/10.1007/BF00486934