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Comparison of different synthesis methods for nasicon ceramics

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Abstract

Various methods for the synthesis of Na2Zr2P2SiO12 ceramics have been investigated. The methods differ by the order of mixing and the use of acetylacetone to decrease the reactivity of zirconium. The homogeneity of the powders prior to calcination has been checked by 31P NMR. Their reactivity towards crystallization is not drastically different. The sintering behaviour is much better in powders in which the zirconium reactivity has been decreased. The effect of the processing on the resulting ionic conductivity of the ceramics has been studied.

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Authors and Affiliations

  1. Chimie des Matériaux, Faculté des sciences de Tunis, 1060, Tunis, Tunisie

    N. Gasmi, N. Gharbi & H. Zarrouk

  2. Chimie de la Matière Condensée, Université P. et M. Curie, 4 Place Jussieu, 75252, Paris 05, France

    P. Barboux, R. Morineau & J. Livage

Authors
  1. N. Gasmi
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  2. N. Gharbi
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  3. H. Zarrouk
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  4. P. Barboux
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  5. R. Morineau
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  6. J. Livage
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Gasmi, N., Gharbi, N., Zarrouk, H. et al. Comparison of different synthesis methods for nasicon ceramics. J Sol-Gel Sci Technol 4, 231–237 (1995). https://doi.org/10.1007/BF00488378

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  • DOI: https://doi.org/10.1007/BF00488378

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