Abstract
The phase separation behaviour of an 18.56 mol % Na2O-SiO2 glass prepared via the standard glass preparation technique and the metallic-organic derived (MOD) method have been studied and contrasted. Our results suggest that at this composition the miscibility temperature is significantly elevated when a MOD preparation procedure is used. The origin of this effect appears to be related to the enhanced water content in the glass prepared by the MOD procedure.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
P. F. James, J. Mater. Sci 10 (1975) 1802.
W. B. Hillig, “Symposium on Nucleation and Crystallization in Glasses and Melts,” edited by Reser (American Ceramic Society, Columbus, Ohio, 1962) p. 77.
R. R. Shaw and D. R. Uhlmann, J. Non-Cryst. Solids 1 (1969) 474.
L. L. Hench and H. F. Schaake, “Introduction to Glass Science,” edited by Pye, Stevens, and LaCourse (Plenum Press, New York, 1972) p. 583.
D. F. Howell, J. H. Summons and W. Haller, Ceram. Bull. 54 (1975) 707.
W. Haller, D. B. Blackburn and J. H. Simmons, J. Amer. Ceram. Soc. 57 (1974) 120.
N. J. Kreidl and M. S. Maklad, ibid 52 (1969) 508.
S. P. Mukherjee, J. Zarzycki and J. P. Traverse, J. Mater. Sci. 11 (1976) 341.
L. Levene and I. Thomas, U.S. Patent 3640093. (1972).
G. F. Neilson, Phys. Chem. Glasses 10 (1969) 54.
Idem, Discuss. Faraday Soc. 50 (1970) 145.
N. S. Andreev, D. A. Goganov and E. A. Porai-Koshits, “Structure of Glass”, Vol. 3, edited by E. A. Porai-Koshits (Translated by E. B. Uvarov Consultants Bureau, New York, 1966) p. 47.
H. Scholze, Glass Ind. 47 (1966) 546.
R. V. Adams, Phys. Chem. Glasses 2 (1961) 39.
H. Scholze, Glastechn. Ber. 32 (1959) 81.
J. H. Hildebrand and R. L. Scott, “Regular Solutions” (Prentice Hall Inc., Englewood Cliffs, N.J., 1962).
B. E. Warren and A. G. Pinars, J. Amer. Ceram. Soc. 23 (1940) 301.
H. Rawson, “Inorganic Glass-Forming Systems,” (Academic Press, London and New York, 1967) p. 115.
A. Dietzel, Z. Electrochem. 48 (1942) 9.
R. J. Charles, Phys. Chem. Glasses 10 (1969) 169.
H. Ramberg, Amer. Mineral 39 (1954) 256.
M. J. Buerger, ibid. 33 (1948) 744.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Weinberg, M.C., Neilson, G.F. Phase separation behaviour of a metal-organic derived sodium silicate glass. J Mater Sci 13, 1206–1216 (1978). https://doi.org/10.1007/BF00544726
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00544726