Abstract
The present knowledge of crystal-melt interfacial energies is examined critically, consideration being given to the full range of metallic, inorganic and organic materials, both pure and impure. The methods currently available for measuring crystal-melt energies are discussed, and the significance of the experimental values in elucidating processes of crystal nucleation and growth is pointed out. The application of solid-liquid energy values to the measurement of other interphase boundary energies is indicated.
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References
M. J. Stowell,Phil. Mag. 22 (1970) 1.
D. Turnbull,J. Chem. Phys. 18 (1950) 198.
J. W. Cahn, W. B. Hillig andG. W. Sears,Acta Metallurgica 12 (1964) 1421.
S. C. Hardy andS. R. Coriell,J. Crystal Growth 5 (1969) 329.
G. R. Kotler andL. A. Tarshis,ibid 3,4 (1968) 603.
G. F. Bolling andW. A. Tiller,J. Appl. Phys. 31 (1960) 1345.
D. R. H. Jones,J. Crystal Growth 16 (1972) 187.
W. A. Miller andG. A. Chadwick,Acta Metallurgica 15 (1967) 607.
R. C. Tolman,J. Chem. Phys. 17 (1949) 333.
J. G. Kirkwood andF. P. Buff,ibid 17 (1949) 338.
F. P. Buff andJ. G. Kirkwood,ibid 18 (1950) 991.
C. J. Coombes, Ph.D. Thesis, London University (1969).
C. R. M. Wronski,Brit. J. Appl. Phys. 18 (1967) 1731.
J. R. Sambles,Proc. R. Soc. A 324 (1971) 339.
C. J. Coombes,J. Phys. F. 2 (1972) 441.
W. Drost-Hansen, private communication.
F. Meissner,Z. Anorg. u. Allgem. Chem. 110 (1920) 169.
R. C. Sill andA. S. Skapski,J. Chem. Phys. 24 (1956) 644.
A. S. Skapski, R. Billups andA. Rooney,ibid 26 (1957) 1350.
A. S. Skapski, R. Billups andD. Casavant,ibid 31 (1959) 1431.
E. S. Miksch,Rev. Sci. Instrum. 36 (1965) 797.
D. R. H. Jones, Ph.D. Thesis, Cambridge University (1970).
W. M. Ketcham andP. V. Hobbs,Phil. Mag. 19 (1969) 1161.
M. E. R. Walford, unpublished work, referred to byJ. F. Nye andS. Mae,J. Glaciol. 11 (1972) 81.
G. Kanig,Kolloid Z. 173 (1960) 97.
P. Kubelka andR. Prokscha,ibid 109 (1944) 79.
B. R. Puri, L. R. Sharma andM. L. Lakhanpal,J. Chem. Phys. 58 (1954) 289.
B. R. Puri, D. D. Singh andY. P. Myer,Trans. Faraday Soc. 53 (1957) 530.
J. L. Shereshefvsky,J. Amer. Chem. Soc. 50 (1928) 2966.
M. Folman andJ. L. Shereshefvsky,J. Phys. Chem. 59 (1955) 607.
W. J. O'Brien,Surf. Sci. 19 (1970) 387.
A. R. Ubbelohde, “Melting and Crystal Structure” (Clarendon Press, Oxford, 1965) p. 29.
G. E. Nash andM. E. Glicksman,Phil. Mag. 24 (1971) 577.
D. R. H. Jones andG. A. Chadwick,ibid 22 (1970) 291.
Idem, J. Crystal Growth 11 (1971) 260.
D. R. H. Jones,Phil. Mag. 27 (1973) 569.
Idem, Rev. Sci. Instrum. 41 (1970) 1509.
L. R. Morris, unpublished work [mentioned in 33].
D. P. Woodruff andA. J. Forty,Phil. Mag. 15 (1967) 935.
T. R. Anthony andH. E. Cline,J. Appl. Phys. 43 (1972) 2473.
E. W. J. Miller andJ. Beech,Metallography 5 (1972) 298.
H. E. Cline andT. R. Anthony,Acta Metallurgica 19 (1971) 491.
D. R. H. Jones andG. A. Chadwick,Phil. Mag. 24 (1971) 1327.
D. R. H. Jones,J. Crystal Growth, in press.
S. Suzuki andD. Kuroiwa,J. Glaciol. 11 (1972) 265.
C. A. Knight,Phil. Mag. 23 (1971) 153.
M. E. Glicksman andC. L. Vold,Acta Metallurgica 17 (1969) 1.
Idem, Scripta Met. 5 (1971) 493.
R. A. Masamura, M. E. Glicksman andC. L. Vold,ibid 6 (1972) 943.
D. Turnbull andJ. C. Fisher,J. Chem. Phys. 17 (1949) 71.
J. H. Holloman andD. Turnbull,Prog. Met. Phys. 4 (1953) 333.
K. A. Jackson,Ind. Eng. Chem. 57 (1965) 29.
D. Turnbull,J. Chem. Phys. 20 (1952) 411.
I. E. Kuhns andB. J. Mason,Proc. R. Soc. A 302 (1968) 437.
G. R. Wood andA. G. Walton,J. Appl. Phys. 41 (1970) 3027.
G. L. F. Powell,J. Aust. Inst. Metals 10 (1965) 223.
D. W. Gommersall, S. Y. Shirashi andR. G. Ward,ibid 10 (1965) 220.
B. Vonnegut,J. Colloid. Sci. 3 (1948) 563.
D. Turnbull andR. E. Cech,J. Appl. Phys. 21 (1950) 804.
D. R. H. Jones andG. A. Chadwick,Phil. Mag. 24 (1971) 995.
J. E. Hilliard andJ. W. Cahn,Acta Metallurgica 6 (1958) 772.
W. Jacobi,Z. Naturforsch A 10 (1955) 322.
B. J. Mason, “The Physics of Clouds” (University Press, Oxford, 1957) p. 128.
L. Dufour andR. Defay, “Thermodynamics of Clouds” (Academic Press, New York, 1963) p. 231.
G. R. Wood andA. G. Walton, unpublished work.
S. C. Hardy, S. R. Coriell andR. F. Sekerka,J. Crystal Growth 11 (1971) 53.
S. C. Hardy andS. R. Coriell,ibid 7 (1970) 147.
Idem, ibid 3,4 (1968) 569.
D. P. Woodruff, private communication.
D. E. Temkin,Dokl. Akad. Nauk. SSSR 132 (1960) 1307.
G. R. Kotler andL. A. Tarshis, Publication Preprint, Ford Scientific Laboratory, Dearborn, Michigan, USA (1968).
M. E. Glicksman andR. J. Schaefer,J. Crystal Growth 1 (1968) 297.
R. Trivedi,Acta Metallurgica 18 (1970) 287.
G. R. Kotler, private communication.
R. Fernandez andA. J. Barduhn,Desalination 3 (1967) 330.
H. E. Cline andT. R. Anthony,Acta Metallurgica 19 (1971) 175.
U. M. Franklin andW. A. Miller,Canad. Met. Q. 8 (1969) 145.
W. A. Miller andG. A. Chadwick,Proc. R. Soc. A 312 (1969) 257.
Idem, in “The Solidification of Metals” (The Iron and Steel Institute, London, 1968) p. 49.
H. Sang, W. A. Miller andG. A. Chadwick, to be published.
G. A. Chadwick, in “Interfaces” (edited by R. C. Gifkins) (Butterworths, London, 1969) p. 101.
J. Basterfield, W. A. Miller andG. C. Weatherly,Canad. Met. Q. 8 (1969) 131.
A. S. Skapski,Acta Metallurgica 4 (1956) 576.
F. K. Gorskii andA. S. Mikulich, in “Crystallization Processes” (edited by N. N. Sirota, F. K. Gorskii and V. M. Varikash) English Translation (Consultants Bureau, New York, 1964) p. 3.
M. Blackman, S. J. Peppiatt andJ. R. Sambles,Nature Lond. 239 (1972) 61.
I. A. Kotzé andD. Kuhlmann-Wilsdorf,Appl. Phys. Letters 9 (1966) 96.
R. H. Ewing,Phil. Mag. 25 (1972) 779.
Idem, J. Crystal Growth 11 (1971) 221.
D. E. Temkin, in “Crystallization Processes” (edited by N. N. Sirota, F. K. Gorskii, and V. M. Varikash) English Translation (Consultants Bureau, New York, 1964) p. 15.
D. Turnbull, in “Liquids: Structure, Properties, Solid Interactions” (edited by T. J. Hughel) (Elsevier, Amsterdam, London and New York, 1965) p.6.
D. G. Thomas andL. A. K. Staveley,J. Chem. Soc. 1952 (1952) 4569.
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Jones, D.R.H. The free energies of solid-liquid interfaces. J Mater Sci 9, 1–17 (1974). https://doi.org/10.1007/BF00554751
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DOI: https://doi.org/10.1007/BF00554751