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Antisymmetric exchange in the trinuclear clusters of copper (II)

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Abstract

The magnetic susceptibility of Cu3(C6H5N2O)3(OH)SO4 · 10.5 H2O crystals was measured in the temperature interval 4.2–11 K and magnetic field range 0–50 kOe. The theoretical analysis of the effects of antisymmetric exchange was performed. An adequate interpretation of the experimental results may be done in terms of an antisymmetric exchange which is about 12 cm−1 in the crystals discussed. The rhombic distortions of the trigonal cluster were shown to reduce the antisymmetric exchange.

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the Moldavian SSR, Kishinev

    B. S. Tsukerblat, B. Ya. Kuyavskaya, M. I. Belinskii & A. V. Ablov

  2. The N.S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moskow

    V. M. Novotortsev & V. T. Kalinnikov

Authors
  1. B. S. Tsukerblat
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  2. B. Ya. Kuyavskaya
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  3. M. I. Belinskii
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  4. A. V. Ablov
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  5. V. M. Novotortsev
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  6. V. T. Kalinnikov
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Tsukerblat, B.S., Kuyavskaya, B.Y., Belinskii, M.I. et al. Antisymmetric exchange in the trinuclear clusters of copper (II). Theoret. Chim. Acta 38, 131–138 (1975). https://doi.org/10.1007/BF00581470

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  • DOI: https://doi.org/10.1007/BF00581470

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