Abstract
Comparative oxidation tests with a fine- and a coarse-grain 25Cr-20Ni steel, and cast steel of similar composition in synthetic air between 900 and 1300°C reveal a strong influence of grain growth in the base metal on the oxidation behavior. Metal grain growth destroys the protective Cr2O3-rich scale, and promotes the formation of a scale rich in iron oxides. The result is a higher scaling rate, and a higher Cr depletion at the metal-scale interface of the fine-grain material which undergoes grain growth during oxidation.
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Ledjeff, K., Rahmel, A. & Schorr, M. Influence of metal grain growth on the oxidation behavior of a 25Cr-20Ni steel. Oxid Met 15, 485–493 (1981). https://doi.org/10.1007/BF00603539
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DOI: https://doi.org/10.1007/BF00603539